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Experimental, computational analysis of Butein and Lanceoletin for natural dye-sensitized solar cells and stabilizing efficiency by IoT

Author

Listed:
  • M. Bradha

    (Rathinam Technical Campus)

  • Nagaraj Balakrishnan

    (Rathinam Technical Campus)

  • A. Suvitha

    (CMR Institute of Technology)

  • T. Arumanayagam

    (Pachaiyappa’s College)

  • M. Rekha

    (Sri Manakula Vinayagar Engineering College)

  • P. Vivek

    (Sri Sankara Arts and Science College)

  • P. Ajay

    (Anna University)

  • V. Sangeetha

    (Measi Matriculation Higher Secondary School)

  • Ananth Steephen

    (KPR Institute of Engineering and Technology)

Abstract

The thoughtful implementation of Internet of Things (IoT) expertise to sustainable progress in environment friendly renewable energy sector is significant for future energy conversion, storage and usage. The exploration of IoT proficiency in restoring the fresh condition of natural dye-sensitized solar cells once again by refilling the photo-sensitizer from its dye-degraded condition is conceived. This concept will eliminate one of the key limitations of dye-sensitized solar cells in real-world application. Potential environment friendly organic dyes were separated from the Butea Monosperma petals and employed for proficient titanium dioxide (TiO2) photo-anodes. Butein and Lanceoletin are prominent colorants existent in the organic source (Butea Monosperma petals) and enhanced molecular structures premeditated. The colorant-sensitized TiO2 NPs underwent the structural, photosensitive, spectral and IV (current–voltage) readings. Comparative DFT (density functional theoretical) and experimental studies on the spectroscopic, electronic and nonlinear opto-response characteristics of Butein and Lanceoletin were performed. The change in HOMO–LUMO energy which governs kinetic steadiness, chemical reactivity, chemical softness, hardness and MEP (molecular electrostatic potential) of molecules has been intended at B3LYP@6-311G (d, p). Environment friendly, price-effective NDSSCs were made by using organic photo-anodes. Graphic abstract

Suggested Citation

  • M. Bradha & Nagaraj Balakrishnan & A. Suvitha & T. Arumanayagam & M. Rekha & P. Vivek & P. Ajay & V. Sangeetha & Ananth Steephen, 2022. "Experimental, computational analysis of Butein and Lanceoletin for natural dye-sensitized solar cells and stabilizing efficiency by IoT," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 24(6), pages 8807-8822, June.
    • Handle: RePEc:spr:endesu:v:24:y:2022:i:6:d:10.1007_s10668-021-01810-5
    DOI: 10.1007/s10668-021-01810-5
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    References listed on IDEAS

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    1. Shraddha Khamparia & Dipika Kaur Jaspal, 2017. "Evaluation of decoloration potential of Xanthium Strumarium seed hull for adsorption of Direct red 81 in aqueous solution," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 19(5), pages 1933-1951, October.
    2. Pankaj Chawla & S. K. Sharma & A. P. Toor, 2020. "Techno-economic evaluation of anatase and p25 TiO2 for treatment basic yellow 28 dye solution through heterogeneous photocatalysis," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 22(1), pages 231-249, January.
    3. R. Keyikoglu & O. T. Can, 2021. "The role of dye molecular weight on the decolorization performance of the electrocoagulation," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(3), pages 3917-3928, March.
    4. Shivaji Karad & Ritula Thakur, 2021. "Efficient monitoring and control of wind energy conversion systems using Internet of things (IoT): a comprehensive review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(10), pages 14197-14214, October.
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