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Improving interface quality for 1-cm2 all-perovskite tandem solar cells

Author

Listed:
  • Rui He

    (Sichuan University)

  • Wanhai Wang

    (Xiamen University
    Nanjing University of Science and Technology)

  • Zongjin Yi

    (Sichuan University)

  • Felix Lang

    (University of Potsdam)

  • Cong Chen

    (Sichuan University)

  • Jincheng Luo

    (Sichuan University)

  • Jingwei Zhu

    (Sichuan University)

  • Jarla Thiesbrummel

    (University of Potsdam
    University of Oxford)

  • Sahil Shah

    (University of Potsdam)

  • Kun Wei

    (Xiamen University)

  • Yi Luo

    (Sichuan University)

  • Changlei Wang

    (Soochow University)

  • Huagui Lai

    (Empa, Swiss Federal Laboratories for Materials Science and Technology)

  • Hao Huang

    (Guangxi University)

  • Jie Zhou

    (Nanjing University of Science and Technology)

  • Bingsuo Zou

    (Guangxi University)

  • Xinxing Yin

    (Jiaxing University)

  • Shengqiang Ren

    (Sichuan University)

  • Xia Hao

    (Sichuan University)

  • Lili Wu

    (Sichuan University)

  • Jingquan Zhang

    (Sichuan University)

  • Jinbao Zhang

    (Xiamen University)

  • Martin Stolterfoht

    (University of Potsdam)

  • Fan Fu

    (Empa, Swiss Federal Laboratories for Materials Science and Technology)

  • Weihua Tang

    (Xiamen University
    Nanjing University of Science and Technology)

  • Dewei Zhao

    (Sichuan University)

Abstract

All-perovskite tandem solar cells provide high power conversion efficiency at a low cost1–4. Rapid efficiency improvement in small-area ( 1.75 eV) perovskite top subcells8, which at present have large voltage and fill factor losses, particularly for large-area (>1 cm2) tandem solar cells. Here we develop a self-assembled monolayer of (4-(7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid as a hole-selective layer for wide-bandgap perovskite solar cells, which facilitates subsequent growth of high-quality wide-bandgap perovskite over a large area with suppressed interfacial non-radiative recombination, enabling efficient hole extraction. By integrating (4-(7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid in devices, we demonstrate a high open-circuit voltage (VOC) of 1.31 V in a 1.77-eV perovskite solar cell, corresponding to a very low VOC deficit of 0.46 V (with respect to the bandgap). With these wide-bandgap perovskite subcells, we report 27.0% (26.4% certified stabilized) monolithic all-perovskite tandem solar cells with an aperture area of 1.044 cm2. The certified tandem cell shows an outstanding combination of a high VOC of 2.12 V and a fill factor of 82.6%. Our demonstration of the large-area tandem solar cells with high certified efficiency is a key step towards scaling up all-perovskite tandem photovoltaic technology.

Suggested Citation

  • Rui He & Wanhai Wang & Zongjin Yi & Felix Lang & Cong Chen & Jincheng Luo & Jingwei Zhu & Jarla Thiesbrummel & Sahil Shah & Kun Wei & Yi Luo & Changlei Wang & Huagui Lai & Hao Huang & Jie Zhou & Bings, 2023. "Improving interface quality for 1-cm2 all-perovskite tandem solar cells," Nature, Nature, vol. 618(7963), pages 80-86, June.
  • Handle: RePEc:nat:nature:v:618:y:2023:i:7963:d:10.1038_s41586-023-05992-y
    DOI: 10.1038/s41586-023-05992-y
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    Citations

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    Cited by:

    1. Jin Zhou & Shiqiang Fu & Shun Zhou & Lishuai Huang & Cheng Wang & Hongling Guan & Dexin Pu & Hongsen Cui & Chen Wang & Ti Wang & Weiwei Meng & Guojia Fang & Weijun Ke, 2024. "Mixed tin-lead perovskites with balanced crystallization and oxidation barrier for all-perovskite tandem solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Wei Gao & Ruijie Ma & Top Archie Dela Peña & Cenqi Yan & Hongxiang Li & Mingjie Li & Jiaying Wu & Pei Cheng & Cheng Zhong & Zhanhua Wei & Alex K.-Y. Jen & Gang Li, 2024. "Efficient all-small-molecule organic solar cells processed with non-halogen solvent," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    3. Artem Musiienko & Fengjiu Yang & Thomas William Gries & Chiara Frasca & Dennis Friedrich & Amran Al-Ashouri & Elifnaz Sağlamkaya & Felix Lang & Danny Kojda & Yi-Teng Huang & Valerio Stacchini & Robert, 2024. "Resolving electron and hole transport properties in semiconductor materials by constant light-induced magneto transport," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Yao Zhang & Chunyan Li & Haiyan Zhao & Zhongxun Yu & Xiaoan Tang & Jixiang Zhang & Zhenhua Chen & Jianrong Zeng & Peng Zhang & Liyuan Han & Han Chen, 2024. "Synchronized crystallization in tin-lead perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Shuchen Tan & Chongwen Li & Cheng Peng & Wenjian Yan & Hongkai Bu & Haokun Jiang & Fang Yue & Linbao Zhang & Hongtao Gao & Zhongmin Zhou, 2024. "Sustainable thermal regulation improves stability and efficiency in all-perovskite tandem solar cells," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    6. Shuxian Du & Hao Huang & Zhineng Lan & Peng Cui & Liang Li & Min Wang & Shujie Qu & Luyao Yan & Changxu Sun & Yingying Yang & Xinxin Wang & Meicheng Li, 2024. "Inhibiting perovskite decomposition by a creeper-inspired strategy enables efficient and stable perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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