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A pressure-amplifying framework material with negative gas adsorption transitions

Author

Listed:
  • Simon Krause

    (Technische Universität Dresden)

  • Volodymyr Bon

    (Technische Universität Dresden)

  • Irena Senkovska

    (Technische Universität Dresden)

  • Ulrich Stoeck

    (Technische Universität Dresden
    † Present address: Institute for Complex Materials, Leibniz Institute for Solid State and Materials Research (IFW) Dresden, Helmholtzstraße 20, D-01069 Dresden, Germany.)

  • Dirk Wallacher

    (Helmholtz-Zentrum Berlin für Materialien und Energie)

  • Daniel M. Többens

    (Department Structure and Dynamics of Energy Materials)

  • Stefan Zander

    (Department Structure and Dynamics of Energy Materials)

  • Renjith S. Pillai

    (Institut Charles Gerhardt Montpellier UMR 5253 CNRS UM ENSCM, Université Montpellier, Place E. Bataillon, 34095)

  • Guillaume Maurin

    (Institut Charles Gerhardt Montpellier UMR 5253 CNRS UM ENSCM, Université Montpellier, Place E. Bataillon, 34095)

  • François-Xavier Coudert

    (Chimie ParisTech, PSL Research University, CNRS, Institut de Recherche de Chimie Paris)

  • Stefan Kaskel

    (Technische Universität Dresden)

Abstract

For adsorption processes, gas uptake usually increases with increasing pressure; however, here the phenomenon of negative gas adsorption is demonstrated in a metal–organic framework, which undergoes a sudden hysteretic structural deformation and pore contraction, releasing guest molecules.

Suggested Citation

  • Simon Krause & Volodymyr Bon & Irena Senkovska & Ulrich Stoeck & Dirk Wallacher & Daniel M. Többens & Stefan Zander & Renjith S. Pillai & Guillaume Maurin & François-Xavier Coudert & Stefan Kaskel, 2016. "A pressure-amplifying framework material with negative gas adsorption transitions," Nature, Nature, vol. 532(7599), pages 348-352, April.
    • Handle: RePEc:nat:nature:v:532:y:2016:i:7599:d:10.1038_nature17430
    DOI: 10.1038/nature17430
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    Cited by:

    1. Davide Caprini & Francesco Battista & Paweł Zajdel & Giovanni Di Muccio & Carlo Guardiani & Benjamin Trump & Marcus Carter & Andrey A. Yakovenko & Eder Amayuelas & Luis Bartolomé & Simone Meloni & Yar, 2024. "Bubbles enable volumetric negative compressibility in metastable elastocapillary systems," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Yangyang Xu & Tu Sun & Tengwu Zeng & Xiangyu Zhang & Xuan Yao & Shan Liu & Zhaolin Shi & Wen Wen & Yingbo Zhao & Shan Jiang & Yanhang Ma & Yue-Biao Zhang, 2023. "Symmetry-breaking dynamics in a tautomeric 3D covalent organic framework," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Francesco Walenszus & Volodymyr Bon & Jack D. Evans & Simon Krause & Jürgen Getzschmann & Stefan Kaskel & Muslim Dvoyashkin, 2023. "On the role of history-dependent adsorbate distribution and metastable states in switchable mesoporous metal-organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    4. Lei Wei & Tu Sun & Zhaolin Shi & Zezhao Xu & Wen Wen & Shan Jiang & Yingbo Zhao & Yanhang Ma & Yue-Biao Zhang, 2022. "Guest-adaptive molecular sensing in a dynamic 3D covalent organic framework," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    5. Yu Liang & Xiaoxin Yang & Xiaoyu Wang & Zong-Jie Guan & Hang Xing & Yu Fang, 2023. "A cage-on-MOF strategy to coordinatively functionalize mesoporous MOFs for manipulating selectivity in adsorption and catalysis," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    6. Simon Krause & Jack D. Evans & Volodymyr Bon & Stefano Crespi & Wojciech Danowski & Wesley R. Browne & Sebastian Ehrling & Francesco Walenszus & Dirk Wallacher & Nico Grimm & Daniel M. Többens & Manfr, 2022. "Cooperative light-induced breathing of soft porous crystals via azobenzene buckling," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Rong Yang & Yu Wang & Jian-Wei Cao & Zi-Ming Ye & Tony Pham & Katherine A. Forrest & Rajamani Krishna & Hongwei Chen & Libo Li & Bo-Kai Ling & Tao Zhang & Tong Gao & Xue Jiang & Xiang-Ou Xu & Qian-Hao, 2024. "Hydrogen bond unlocking-driven pore structure control for shifting multi-component gas separation function," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    8. Jin-Peng Xue & Yang Hu & Bo Zhao & Zhi-Kun Liu & Jing Xie & Zi-Shuo Yao & Jun Tao, 2022. "A spin-crossover framework endowed with pore-adjustable behavior by slow structural dynamics," Nature Communications, Nature, vol. 13(1), pages 1-10, December.

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