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The direct arylation of allylic sp3 C–H bonds via organic and photoredox catalysis

Author

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  • James D. Cuthbertson

    (Merck Center for Catalysis at Princeton University)

  • David W. C. MacMillan

    (Merck Center for Catalysis at Princeton University)

Abstract

Photoredox and organic catalysis are combined to achieve broadly effective direct arylation of allylic carbon–hydrogen bonds under mild conditions; this carbon–carbon bond forming reaction readily accommodates a wide range of alkene and electron-deficient arene coupling partners.

Suggested Citation

  • James D. Cuthbertson & David W. C. MacMillan, 2015. "The direct arylation of allylic sp3 C–H bonds via organic and photoredox catalysis," Nature, Nature, vol. 519(7541), pages 74-77, March.
    • Handle: RePEc:nat:nature:v:519:y:2015:i:7541:d:10.1038_nature14255
    DOI: 10.1038/nature14255
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    Cited by:

    1. Xiaochen Wang & Rongxin Yang & Binbing Zhu & Yuxiu Liu & Hongjian Song & Jianyang Dong & Qingmin Wang, 2023. "Direct allylic acylation via cross-coupling involving cooperative N‑heterocyclic carbene, hydrogen atom transfer, and photoredox catalysis," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Yujun Li & Shaopeng Guo & Qing-Han Li & Ke Zheng, 2023. "Metal-free photoinduced C(sp3)–H/C(sp3)–H cross-coupling to access α‑tertiary amino acid derivatives," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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