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Nanoscale chemical imaging of a working catalyst by scanning transmission X-ray microscopy

Author

Listed:
  • Emiel de Smit

    (Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Sorbonnelaan 16, 3584 CA Utrecht, The Netherlands)

  • Ingmar Swart

    (Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Sorbonnelaan 16, 3584 CA Utrecht, The Netherlands)

  • J. Fredrik Creemer

    (DIMES-ECTM, Delft University of Technology, PO Box 5053, 2600 GB Delft, The Netherlands)

  • Gerard H. Hoveling

    (DEMO, Delft University of Technology, PO Box 5031, 2600 GA Delft, The Netherlands)

  • Mary K. Gilles

    (Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA)

  • Tolek Tyliszczak

    (Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA)

  • Patricia J. Kooyman

    (DelftChemTech and National Centre for High Resolution Electron Microscopy, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands)

  • Henny W. Zandbergen

    (Kavli Institute of NanoScience, National Centre for High Resolution Electron Microscopy, Delft University of Technology, PO Box 5046, 2600 GA Delft, The Netherlands)

  • Cynthia Morin

    (Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Sorbonnelaan 16, 3584 CA Utrecht, The Netherlands)

  • Bert M. Weckhuysen

    (Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Sorbonnelaan 16, 3584 CA Utrecht, The Netherlands)

  • Frank M. F. de Groot

    (Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Sorbonnelaan 16, 3584 CA Utrecht, The Netherlands)

Abstract

Nanoscale observations of surface catalysis Most industrial processes make use of heterogeneous catalysts, which typically consist of nanometre-sized particles of metal or metal oxide dispersed on a solid support material. Any attempt to unravel how such complex systems function requires detailed information on the morphology and chemical composition of the catalysts during operation. Microspectroscopy methods have now advanced to a stage where this challenge can be tackled. Using a specially designed nanoreactor and scanning transmission X-ray microscopy, de Smit et al. have achieved direct imaging of an iron-based Fisher–Tropsch catalyst with nanometre-resolution and reveal how changes in the catalyst correlate with its activity. The same approach could help understand — and improve — other heterogeneous catalysts and important chemical processes occurring at surfaces.

Suggested Citation

  • Emiel de Smit & Ingmar Swart & J. Fredrik Creemer & Gerard H. Hoveling & Mary K. Gilles & Tolek Tyliszczak & Patricia J. Kooyman & Henny W. Zandbergen & Cynthia Morin & Bert M. Weckhuysen & Frank M. F, 2008. "Nanoscale chemical imaging of a working catalyst by scanning transmission X-ray microscopy," Nature, Nature, vol. 456(7219), pages 222-225, November.
    • Handle: RePEc:nat:nature:v:456:y:2008:i:7219:d:10.1038_nature07516
    DOI: 10.1038/nature07516
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    Cited by:

    1. Lukas Grote & Martin Seyrich & Ralph Döhrmann & Sani Y. Harouna-Mayer & Federica Mancini & Emilis Kaziukenas & Irene Fernandez-Cuesta & Cecilia A. Zito & Olga Vasylieva & Felix Wittwer & Michal Odstrč, 2022. "Imaging Cu2O nanocube hollowing in solution by quantitative in situ X-ray ptychography," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Toshihiko Ogura, 2011. "Three-Dimensional X-ray Observation of Atmospheric Biological Samples by Linear-Array Scanning-Electron Generation X-ray Microscope System," PLOS ONE, Public Library of Science, vol. 6(6), pages 1-9, June.
    3. Toshihiko Ogura, 2019. "Direct observation of unstained biological samples in water using newly developed impedance scanning electron microscopy," PLOS ONE, Public Library of Science, vol. 14(8), pages 1-17, August.

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