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Suppressed decomposition of organometal halide perovskites by impermeable electron-extraction layers in inverted solar cells

Author

Listed:
  • K.O. Brinkmann

    (Institute of Electronic Devices, University of Wuppertal)

  • J. Zhao

    (Institute of Electronic Devices, University of Wuppertal
    College of Materials Science and Engineering, Nanchang University)

  • N. Pourdavoud

    (Institute of Electronic Devices, University of Wuppertal)

  • T. Becker

    (Institute of Electronic Devices, University of Wuppertal)

  • T. Hu

    (Institute of Electronic Devices, University of Wuppertal
    College of Chemistry/Institute of Polymers, Nanchang University)

  • S. Olthof

    (University of Cologne)

  • K. Meerholz

    (University of Cologne)

  • L. Hoffmann

    (Institute of Electronic Devices, University of Wuppertal)

  • T. Gahlmann

    (Institute of Electronic Devices, University of Wuppertal)

  • R. Heiderhoff

    (Institute of Electronic Devices, University of Wuppertal)

  • M. F. Oszajca

    (Nanograde AG)

  • N. A. Luechinger

    (Nanograde AG)

  • D. Rogalla

    (Ruhr-Universität Bochum, RUBION, Universitätsstr. 150)

  • Y. Chen

    (College of Chemistry/Institute of Polymers, Nanchang University)

  • B. Cheng

    (College of Materials Science and Engineering, Nanchang University)

  • T Riedl

    (Institute of Electronic Devices, University of Wuppertal)

Abstract

The area of thin-film photovoltaics has been overwhelmed by organometal halide perovskites. Unfortunately, serious stability concerns arise with perovskite solar cells. For example, methyl-ammonium lead iodide is known to decompose in the presence of water and, more severely, even under inert conditions at elevated temperatures. Here, we demonstrate inverted perovskite solar cells, in which the decomposition of the perovskite is significantly mitigated even at elevated temperatures. Specifically, we introduce a bilayered electron-extraction interlayer consisting of aluminium-doped zinc oxide and tin oxide. We evidence tin oxide grown by atomic layer deposition does form an outstandingly dense gas permeation barrier that effectively hinders the ingress of moisture towards the perovskite and—more importantly—it prevents the egress of decomposition products of the perovskite. Thereby, the overall decomposition of the perovskite is significantly suppressed, leading to an outstanding device stability.

Suggested Citation

  • K.O. Brinkmann & J. Zhao & N. Pourdavoud & T. Becker & T. Hu & S. Olthof & K. Meerholz & L. Hoffmann & T. Gahlmann & R. Heiderhoff & M. F. Oszajca & N. A. Luechinger & D. Rogalla & Y. Chen & B. Cheng , 2017. "Suppressed decomposition of organometal halide perovskites by impermeable electron-extraction layers in inverted solar cells," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    • Handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_ncomms13938
    DOI: 10.1038/ncomms13938
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    Cited by:

    1. Sajid, Sajid & Huang, Hao & Ji, Jun & Jiang, Haoran & Duan, Mingjun & Liu, Xin & Liu, Benyu & Li, Meicheng, 2021. "Quest for robust electron transporting materials towards efficient, hysteresis-free and stable perovskite solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    2. Xiang, Huimin & Liu, Pengyun & Ran, Ran & Wang, Wei & Zhou, Wei & Shao, Zongping, 2022. "Two-dimensional Dion-Jacobson halide perovskites as new-generation light absorbers for perovskite solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    3. Thibault Lemercier & Lara Perrin & Emilie Planès & Solenn Berson & Lionel Flandin, 2020. "A Comparison of the Structure and Properties of Opaque and Semi-Transparent NIP/PIN-Type Scalable Perovskite Solar Cells," Energies, MDPI, vol. 13(15), pages 1-18, July.
    4. Jarla Thiesbrummel & Sahil Shah & Emilio Gutierrez-Partida & Fengshuo Zu & Francisco Peña-Camargo & Stefan Zeiske & Jonas Diekmann & Fangyuan Ye & Karol P. Peters & Kai O. Brinkmann & Pietro Capriogli, 2024. "Ion-induced field screening as a dominant factor in perovskite solar cell operational stability," Nature Energy, Nature, vol. 9(6), pages 664-676, June.
    5. Zhi Chen & Jie Wang & Hongbo Wu & Jianming Yang & Yikai Wang & Jing Zhang & Qinye Bao & Ming Wang & Zaifei Ma & Wolfgang Tress & Zheng Tang, 2022. "A Transparent Electrode Based on Solution-Processed ZnO for Organic Optoelectronic Devices," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

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