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Crystal OH mediating pathway for hydrogen peroxide production via two-electron water oxidation in non-carbonate electrolytes

Author

Listed:
  • Ruilin Wang

    (Sun Yat-sen University)

  • Hao Luo

    (Sun Yat-sen University)

  • Chengyu Duan

    (Sun Yat-sen University)

  • Huimin Liu

    (Sun Yat-sen University)

  • Mengdi Sun

    (Sun Yat-sen University)

  • Quan Zhou

    (Sun Yat-sen University)

  • Zheshun Ou

    (Sun Yat-sen University)

  • Yinglong Lu

    (Sun Yat-sen University)

  • Guanghui Luo

    (Sun Yat-sen University)

  • Jimmy C. Yu

    (The Chinese University of Hong Kong)

  • Zhuofeng Hu

    (Sun Yat-sen University)

Abstract

Water oxidation presents a promising avenue for hydrogen peroxide (H2O2) production. However, the reliance on alkaline bicarbonate electrolytes as an intermediate has limitations, such as H2O2 decomposition and a narrow pH effectiveness range (7–9), restricting its utility across wider pH ranges. This study unveils a crystal OH mediating pathway that stabilizes SO4OH* as a crucial intermediate. Basic copper carbonate (Cu2(OH)2CO3) tablets, commonly found on cultural relics, exhibit the capability to generate H2O2 in neutral or acidic non-bicarbonate electrolytes. By leveraging this crystal OH mediating strategy, considerable H2O2 production in Na2SO4 electrolytes is achievable. Notably, the H2O2 production rate can reach 64.35 μmol h−1 at 3.4 V vs. RHE in a 50 mL 0.5 M Na2SO4 electrolyte. This research underscores the importance of crystal part in catalyst in catalyzing the 2e− water oxidation reaction, offering valuable insights for future investigations.

Suggested Citation

  • Ruilin Wang & Hao Luo & Chengyu Duan & Huimin Liu & Mengdi Sun & Quan Zhou & Zheshun Ou & Yinglong Lu & Guanghui Luo & Jimmy C. Yu & Zhuofeng Hu, 2024. "Crystal OH mediating pathway for hydrogen peroxide production via two-electron water oxidation in non-carbonate electrolytes," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-54593-4
    DOI: 10.1038/s41467-024-54593-4
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    References listed on IDEAS

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    1. Kun Jiang & Seoin Back & Austin J. Akey & Chuan Xia & Yongfeng Hu & Wentao Liang & Diane Schaak & Eli Stavitski & Jens K. Nørskov & Samira Siahrostami & Haotian Wang, 2019. "Highly selective oxygen reduction to hydrogen peroxide on transition metal single atom coordination," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    2. Lejing Li & Zhuofeng Hu & Yongqiang Kang & Shiyu Cao & Liangpang Xu & Luo Yu & Lizhi Zhang & Jimmy C. Yu, 2023. "Electrochemical generation of hydrogen peroxide from a zinc gallium oxide anode with dual active sites," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Qizhan Zhang & Minghua Zhou & Gengbo Ren & Yawei Li & Yanchun Li & Xuedong Du, 2020. "Highly efficient electrosynthesis of hydrogen peroxide on a superhydrophobic three-phase interface by natural air diffusion," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
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