IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-48268-3.html
   My bibliography  Save this article

Realizing thermoelectric cooling and power generation in N-type PbS0.6Se0.4 via lattice plainification and interstitial doping

Author

Listed:
  • Lei Wang

    (Beihang University)

  • Yi Wen

    (Beihang University)

  • Shulin Bai

    (Beihang University
    Tianmushan Laboratory)

  • Cheng Chang

    (Beihang University)

  • Yichen Li

    (Beihang University)

  • Shan Liu

    (Beihang University)

  • Dongrui Liu

    (Beihang University)

  • Siqi Wang

    (Beihang University)

  • Zhe Zhao

    (Beihang University)

  • Shaoping Zhan

    (Beihang University)

  • Qian Cao

    (Huabei Cooling Device Co. LTD.)

  • Xiang Gao

    (Center for High Pressure Science and Technology Advanced Research (HPSTAR))

  • Hongyao Xie

    (Beihang University)

  • Li-Dong Zhao

    (Beihang University
    Tianmushan Laboratory)

Abstract

Thermoelectrics have great potential for use in waste heat recovery to improve energy utilization. Moreover, serving as a solid-state heat pump, they have found practical application in cooling electronic products. Nevertheless, the scarcity of commercial Bi2Te3 raw materials has impeded the sustainable and widespread application of thermoelectric technology. In this study, we developed a low-cost and earth-abundant PbS compound with impressive thermoelectric performance. The optimized n-type PbS material achieved a record-high room temperature ZT of 0.64 in this system. Additionally, the first thermoelectric cooling device based on n-type PbS was fabricated, which exhibits a remarkable cooling temperature difference of ~36.9 K at room temperature. Meanwhile, the power generation efficiency of a single-leg device employing our n-type PbS material reaches ~8%, showing significant potential in harvesting waste heat into valuable electrical power. This study demonstrates the feasibility of sustainable n-type PbS as a viable alternative to commercial Bi2Te3, thereby extending the application of thermoelectrics.

Suggested Citation

  • Lei Wang & Yi Wen & Shulin Bai & Cheng Chang & Yichen Li & Shan Liu & Dongrui Liu & Siqi Wang & Zhe Zhao & Shaoping Zhan & Qian Cao & Xiang Gao & Hongyao Xie & Li-Dong Zhao, 2024. "Realizing thermoelectric cooling and power generation in N-type PbS0.6Se0.4 via lattice plainification and interstitial doping," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48268-3
    DOI: 10.1038/s41467-024-48268-3
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-48268-3
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-48268-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Kanishka Biswas & Jiaqing He & Ivan D. Blum & Chun-I Wu & Timothy P. Hogan & David N. Seidman & Vinayak P. Dravid & Mercouri G. Kanatzidis, 2012. "High-performance bulk thermoelectrics with all-scale hierarchical architectures," Nature, Nature, vol. 489(7416), pages 414-418, September.
    2. Shaoping Zhan & Tao Hong & Bingchao Qin & Yingcai Zhu & Xiang Feng & Lizhong Su & Haonan Shi & Hao Liang & Qianfan Zhang & Xiang Gao & Zhen-Hua Ge & Lei Zheng & Dongyang Wang & Li-Dong Zhao, 2022. "Realizing high-ranged thermoelectric performance in PbSnS2 crystals," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bingchao Qin & Dongyang Wang & Tao Hong & Yuping Wang & Dongrui Liu & Ziyuan Wang & Xiang Gao & Zhen-Hua Ge & Li-Dong Zhao, 2023. "High thermoelectric efficiency realized in SnSe crystals via structural modulation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Nie, Xianhua & Xue, Juan & Zhao, Li & Deng, Shuai & Xiong, Hanping, 2024. "New insight of thermodynamic cycle in thermoelectric power generation analyses: Literature review and perspectives," Energy, Elsevier, vol. 292(C).
    3. Longquan Wang & Wenhao Zhang & Song Yi Back & Naoyuki Kawamoto & Duy Hieu Nguyen & Takao Mori, 2024. "High-performance Mg3Sb2-based thermoelectrics with reduced structural disorder and microstructure evolution," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Romo-De-La-Cruz, Cesar-Octavio & Chen, Yun & Liang, Liang & Paredes-Navia, Sergio A. & Wong-Ng, Winnie K. & Song, Xueyan, 2023. "Entering new era of thermoelectric oxide ceramics with high power factor through designing grain boundaries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    5. Yihua Zhang & Guyang Peng & Shuankui Li & Haijun Wu & Kaidong Chen & Jiandong Wang & Zhihao Zhao & Tu Lyu & Yuan Yu & Chaohua Zhang & Yang Zhang & Chuansheng Ma & Shengwu Guo & Xiangdong Ding & Jun Su, 2024. "Phase interface engineering enables state-of-the-art half-Heusler thermoelectrics," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    6. Bushra Jabar & Fu Li & Zhuanghao Zheng & Adil Mansoor & Yongbin Zhu & Chongbin Liang & Dongwei Ao & Yuexing Chen & Guangxing Liang & Ping Fan & Weishu Liu, 2021. "Homo-composition and hetero-structure nanocomposite Pnma Bi2SeS2 - Pnnm Bi2SeS2 with high thermoelectric performance," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    7. Zihang Liu & Weihong Gao & Hironori Oshima & Kazuo Nagase & Chul-Ho Lee & Takao Mori, 2022. "Maximizing the performance of n-type Mg3Bi2 based materials for room-temperature power generation and thermoelectric cooling," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    8. Yingcai Zhu & Dongyang Wang & Tao Hong & Lei Hu & Toshiaki Ina & Shaoping Zhan & Bingchao Qin & Haonan Shi & Lizhong Su & Xiang Gao & Li-Dong Zhao, 2022. "Multiple valence bands convergence and strong phonon scattering lead to high thermoelectric performance in p-type PbSe," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    9. Yilin Jiang & Jinfeng Dong & Hua-Lu Zhuang & Jincheng Yu & Bin Su & Hezhang Li & Jun Pei & Fu-Hua Sun & Min Zhou & Haihua Hu & Jing-Wei Li & Zhanran Han & Bo-Ping Zhang & Takao Mori & Jing-Feng Li, 2022. "Evolution of defect structures leading to high ZT in GeTe-based thermoelectric materials," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    10. Smith, Eric & Hosseini, Seyed Ehsan, 2019. "Human Body Micro-power plant," Energy, Elsevier, vol. 183(C), pages 16-24.
    11. Sun, Henan & Ge, Ya & Liu, Wei & Liu, Zhichun, 2019. "Geometric optimization of two-stage thermoelectric generator using genetic algorithms and thermodynamic analysis," Energy, Elsevier, vol. 171(C), pages 37-48.
    12. Montecucco, Andrea & Knox, Andrew R., 2014. "Accurate simulation of thermoelectric power generating systems," Applied Energy, Elsevier, vol. 118(C), pages 166-172.
    13. Contento, Gaetano & Lorenzi, Bruno & Rizzo, Antonella & Narducci, Dario, 2020. "Simultaneous materials and layout optimization of non-imaging optically concentrated solar thermoelectric generators," Energy, Elsevier, vol. 194(C).
    14. Marfoua, Brahim & Lim, Young Soo & Hong, Jisang, 2020. "High thermoelectric performance of two-dimensional α-GeTe bilayer," Energy, Elsevier, vol. 211(C).
    15. Li, Yong & Yang, Jie & Song, Jian, 2016. "Structural model, size effect and nano-energy system design for more sustainable energy of solid state automotive battery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 685-697.
    16. Decheng An & Senhao Zhang & Xin Zhai & Wutao Yang & Riga Wu & Huaide Zhang & Wenhao Fan & Wenxian Wang & Shaoping Chen & Oana Cojocaru-Mirédin & Xian-Ming Zhang & Matthias Wuttig & Yuan Yu, 2024. "Metavalently bonded tellurides: the essence of improved thermoelectric performance in elemental Te," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    17. Zhifang Zhou & Yi Huang & Bin Wei & Yueyang Yang & Dehong Yu & Yunpeng Zheng & Dongsheng He & Wenyu Zhang & Mingchu Zou & Jin-Le Lan & Jiaqing He & Ce-Wen Nan & Yuan-Hua Lin, 2023. "Compositing effects for high thermoelectric performance of Cu2Se-based materials," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    18. Bhuvanesh Srinivasan & David Berthebaud & Takao Mori, 2020. "Is LiI a Potential Dopant Candidate to Enhance the Thermoelectric Performance in Sb-Free GeTe Systems? A Prelusive Study," Energies, MDPI, vol. 13(3), pages 1-7, February.
    19. Zhu, Wei & Deng, Yuan & Wang, Yao & Shen, Shengfei & Gulfam, Raza, 2016. "High-performance photovoltaic-thermoelectric hybrid power generation system with optimized thermal management," Energy, Elsevier, vol. 100(C), pages 91-101.
    20. Li, Yong & Yang, Jie & Song, Jian, 2016. "Nano-energy system coupling model and failure characterization of lithium ion battery electrode in electric energy vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1250-1261.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48268-3. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.