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A fast-charging/discharging and long-term stable artificial electrode enabled by space charge storage mechanism

Author

Listed:
  • Linyi Zhao

    (Qingdao University)

  • Tiansheng Wang

    (Qingdao University)

  • Fengkai Zuo

    (Qingdao University)

  • Zhengyu Ju

    (The University of Texas at Austin)

  • Yuhao Li

    (Qingdao University)

  • Qiang Li

    (Qingdao University)

  • Yue Zhu

    (The University of Texas at Austin
    Ocean University of China)

  • Hongsen Li

    (Qingdao University)

  • Guihua Yu

    (The University of Texas at Austin)

Abstract

Lithium‐ion batteries with fast-charging/discharging properties are urgently needed for the mass adoption of electric vehicles. Here, we show that fast charging/discharging, long-term stable and high energy charge-storage properties can be realized in an artificial electrode made from a mixed electronic/ionic conductor material (Fe/LixM, where M = O, F, S, N) enabled by a space charge principle. Particularly, the Fe/Li2O electrode is able to be charged/discharged to 126 mAh g−1 in 6 s at a high current density of up to 50 A g−1, and it also shows stable cycling performance for 30,000 cycles at a current density of 10 A g−1, with a mass-loading of ~2.5 mg cm−2 of the electrode materials. This study demonstrates the critical role of the space charge storage mechanism in advancing electrochemical energy storage and provides an unconventional perspective for designing high-performance anode materials for lithium-ion batteries.

Suggested Citation

  • Linyi Zhao & Tiansheng Wang & Fengkai Zuo & Zhengyu Ju & Yuhao Li & Qiang Li & Yue Zhu & Hongsen Li & Guihua Yu, 2024. "A fast-charging/discharging and long-term stable artificial electrode enabled by space charge storage mechanism," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48215-2
    DOI: 10.1038/s41467-024-48215-2
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    References listed on IDEAS

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