IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-46619-8.html
   My bibliography  Save this article

Highly efficient multi-resonance thermally activated delayed fluorescence material toward a BT.2020 deep-blue emitter

Author

Listed:
  • Junki Ochi

    (Kyoto University)

  • Yuki Yamasaki

    (Kwansei Gakuin University)

  • Kojiro Tanaka

    (Kyoto University)

  • Yasuhiro Kondo

    (Ltd.)

  • Kohei Isayama

    (Ltd.)

  • Susumu Oda

    (Toyo University)

  • Masakazu Kondo

    (Ltd.)

  • Takuji Hatakeyama

    (Kyoto University)

Abstract

An ultrapure deep-blue multi-resonance-induced thermally activated delayed fluorescence material (DOB2-DABNA-A) is designed and synthesized. Benefiting from a fully resonating extended helical π-conjugated system, this compound has a small ΔEST value of 3.6 meV and sufficient spin–orbit coupling to exhibit a high-rate constant for reverse intersystem crossing (kRISC = 1.1 × 106 s–1). Furthermore, an organic light-emitting diode employing DOB2-DABNA-A as an emitter is fabricated; it exhibits ultrapure deep-blue emission at 452 nm with a small full width at half maximum of 24 nm, corresponding to Commission Internationale de l’Éclairage (CIE) coordinates of (0.145, 0.049). The high kRISC value reduces the efficiency roll-off, resulting in a high external quantum efficiency (EQE) of 21.6% at 1000 cd m–2.

Suggested Citation

  • Junki Ochi & Yuki Yamasaki & Kojiro Tanaka & Yasuhiro Kondo & Kohei Isayama & Susumu Oda & Masakazu Kondo & Takuji Hatakeyama, 2024. "Highly efficient multi-resonance thermally activated delayed fluorescence material toward a BT.2020 deep-blue emitter," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46619-8
    DOI: 10.1038/s41467-024-46619-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-46619-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-46619-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Hironori Kaji & Hajime Suzuki & Tatsuya Fukushima & Katsuyuki Shizu & Katsuaki Suzuki & Shosei Kubo & Takeshi Komino & Hajime Oiwa & Furitsu Suzuki & Atsushi Wakamiya & Yasujiro Murata & Chihaya Adach, 2015. "Purely organic electroluminescent material realizing 100% conversion from electricity to light," Nature Communications, Nature, vol. 6(1), pages 1-8, December.
    2. Naoya Aizawa & Yu Harabuchi & Satoshi Maeda & Yong-Jin Pu, 2020. "Kinetic prediction of reverse intersystem crossing in organic donor–acceptor molecules," Nature Communications, Nature, vol. 11(1), pages 1-6, December.
    3. Anton Pershin & David Hall & Vincent Lemaur & Juan-Carlos Sancho-Garcia & Luca Muccioli & Eli Zysman-Colman & David Beljonne & Yoann Olivier, 2019. "Highly emissive excitons with reduced exchange energy in thermally activated delayed fluorescent molecules," Nature Communications, Nature, vol. 10(1), pages 1-5, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jianyu Zhang & Yujie Tu & Hanchen Shen & Jacky W. Y. Lam & Jianwei Sun & Haoke Zhang & Ben Zhong Tang, 2023. "Regulating the proximity effect of heterocycle-containing AIEgens," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Junyuan Liu & Yunhui Zhu & Taiju Tsuboi & Chao Deng & Weiwei Lou & Dan Wang & Tiangeng Liu & Qisheng Zhang, 2022. "Toward a BT.2020 green emitter through a combined multiple resonance effect and multi-lock strategy," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Alexander J. Gillett & Claire Tonnelé & Giacomo Londi & Gaetano Ricci & Manon Catherin & Darcy M. L. Unson & David Casanova & Frédéric Castet & Yoann Olivier & Weimin M. Chen & Elena Zaborova & Emrys , 2021. "Spontaneous exciton dissociation enables spin state interconversion in delayed fluorescence organic semiconductors," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    4. Hyung Suk Kim & Sang Hoon Lee & Seunghyup Yoo & Chihaya Adachi, 2024. "Understanding of complex spin up-conversion processes in charge-transfer-type organic molecules," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    5. Ying-Chun Cheng & Xun Tang & Kai Wang & Xin Xiong & Xiao-Chun Fan & Shulin Luo & Rajat Walia & Yue Xie & Tao Zhang & Dandan Zhang & Jia Yu & Xian-Kai Chen & Chihaya Adachi & Xiao-Hong Zhang, 2024. "Efficient, narrow-band, and stable electroluminescence from organoboron-nitrogen-carbonyl emitter," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    6. Katsuyuki Shizu & Hironori Kaji, 2024. "Quantitative prediction of rate constants and its application to organic emitters," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    7. A. Lennart Schleper & Kenichi Goushi & Christoph Bannwarth & Bastian Haehnle & Philipp J. Welscher & Chihaya Adachi & Alexander J. C. Kuehne, 2021. "Hot exciplexes in U-shaped TADF molecules with emission from locally excited states," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    8. Weidong Qiu & Denghui Liu & Mengke Li & Xinyi Cai & Zijian Chen & Yanmei He & Baoyan Liang & Xiaomei Peng & Zhenyang Qiao & Jiting Chen & Wei Li & Junrong Pu & Wentao Xie & Zhiheng Wang & Deli Li & Yi, 2023. "Confining donor conformation distributions for efficient thermally activated delayed fluorescence with fast spin-flipping," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46619-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.