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Epitaxial growth of metal-organic framework nanosheets into single-crystalline orthogonal arrays

Author

Listed:
  • Yingying Zou

    (East China Normal University)

  • Chao Liu

    (East China Normal University)

  • Chaoqi Zhang

    (East China Normal University)

  • Ling Yuan

    (East China Normal University)

  • Jiaxin Li

    (East China Normal University)

  • Tong Bao

    (East China Normal University)

  • Guangfeng Wei

    (Tongji University)

  • Jin Zou

    (The University of Queensland)

  • Chengzhong Yu

    (East China Normal University
    The University of Queensland)

Abstract

Construction of two-dimensional nanosheets into three-dimensional regular structures facilitates the mass transfer and exploits the maximum potential of two-dimensional building blocks in applications such as catalysis. Here, we report the synthesis of metal-organic frameworks with an orthogonal nanosheet array. The assembly involves the epitaxial growth of single crystalline metal-organic framework nanosheets with a naturally non-preferred facet exposure as the shell on a cubic metal-organic framework as the core. The nanosheets, despite of two typical shapes and crystallographic orientations, also form a single crystalline orthogonally arrayed framework. The density and size of nanosheets in the core-shell-structured composite metal-organic frameworks can be well adjusted. Moreover, metal-organic frameworks with a single composition and hollow orthogonal nanosheet array morphology can be obtained. Benefiting from the unusual facet exposure and macroporous structure, the designed structure exhibits improved electrocatalytic oxygen evolution activity compared to conventional nanosheets.

Suggested Citation

  • Yingying Zou & Chao Liu & Chaoqi Zhang & Ling Yuan & Jiaxin Li & Tong Bao & Guangfeng Wei & Jin Zou & Chengzhong Yu, 2023. "Epitaxial growth of metal-organic framework nanosheets into single-crystalline orthogonal arrays," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-41517-x
    DOI: 10.1038/s41467-023-41517-x
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    References listed on IDEAS

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    1. Dongdong Xu & Yanhang Ma & Zhifeng Jing & Lu Han & Bhupendra Singh & Ji Feng & Xuefeng Shen & Fenglei Cao & Peter Oleynikov & Huai Sun & Osamu Terasaki & Shunai Che, 2014. "π–π interaction of aromatic groups in amphiphilic molecules directing for single-crystalline mesostructured zeolite nanosheets," Nature Communications, Nature, vol. 5(1), pages 1-9, September.
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    3. Ohmin Kwon & Jin Yeong Kim & Sungbin Park & Jae Hwa Lee & Junsu Ha & Hyunsoo Park & Hoi Ri Moon & Jihan Kim, 2019. "Computer-aided discovery of connected metal-organic frameworks," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
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