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A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates

Author

Listed:
  • Zhi Wang

    (Shandong University)

  • Yan-Jie Zhu

    (Shandong University)

  • Bao-Liang Han

    (Shandong University)

  • Yi-Zhi Li

    (Shandong University)

  • Chen-Ho Tung

    (Shandong University)

  • Di Sun

    (Shandong University)

Abstract

Metalloligands provide a potent strategy for manipulating the surface metal arrangements of metal nanoclusters, but their synthesis and subsequent installation onto metal nanoclusters remains a significant challenge. Herein, two atomically precise silver nanoclusters {Ag14[(TC4A)6(V9O16)](CyS)3} (Ag14) and {Ag43S[(TC4A)2(V4O9)]3(CyS)9(PhCOO)3Cl3(SO4)4(DMF)3·6DMF} (Ag43) are synthesized by controlling reaction temperature (H4TC4A = p-tert-butylthiacalix[4]arene). Interestingly, the 3D scaffold-like [(TC4A)6(V9O16)]11- metalloligand in Ag14 and 1D arcuate [(TC4A)2(V4O9)]6- metalloligand in Ag43 exhibit a dual role that is the internal polyoxovanadates as anion template and the surface TC4A4- as the passivating agent. Furthermore, the thermal-induced structure transformation between Ag14 and Ag43 is achieved based on the temperature-dependent assembly process. Ag14 shows superior photothermal conversion performance than Ag43 in solid state indicating its potential for remote laser ignition. Here, we show the potential of two thiacalix[4]arene modified polyoxovanadates metalloligands in the assembly of metal nanoclusters and provide a cornerstone for the remote laser ignition applications of silver nanoclusters.

Suggested Citation

  • Zhi Wang & Yan-Jie Zhu & Bao-Liang Han & Yi-Zhi Li & Chen-Ho Tung & Di Sun, 2023. "A route to metalloligands consolidated silver nanoclusters by grafting thiacalix[4]arene onto polyoxovanadates," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-41050-x
    DOI: 10.1038/s41467-023-41050-x
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    References listed on IDEAS

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    1. Ji Qi & Chao Chen & Xiaoyan Zhang & Xianglong Hu & Shenglu Ji & Ryan T. K. Kwok & Jacky W. Y. Lam & Dan Ding & Ben Zhong Tang, 2018. "Light-driven transformable optical agent with adaptive functions for boosting cancer surgery outcomes," Nature Communications, Nature, vol. 9(1), pages 1-12, December.
    2. Yitao Cao & Tongyu Liu & Tiankai Chen & Bihan Zhang & De-en Jiang & Jianping Xie, 2021. "Revealing the etching process of water-soluble Au25 nanoclusters at the molecular level," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
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