IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-38216-y.html
   My bibliography  Save this article

Enabling metallic behaviour in two-dimensional superlattice of semiconductor colloidal quantum dots

Author

Listed:
  • Ricky Dwi Septianto

    (RIKEN Center for Emergent Matter Science (CEMS)
    Tokyo Institute of Technology)

  • Retno Miranti

    (RIKEN Center for Emergent Matter Science (CEMS))

  • Tomoka Kikitsu

    (RIKEN Center for Emergent Matter Science (CEMS))

  • Takaaki Hikima

    (RIKEN SPring-8 Center)

  • Daisuke Hashizume

    (RIKEN Center for Emergent Matter Science (CEMS))

  • Nobuhiro Matsushita

    (Tokyo Institute of Technology)

  • Yoshihiro Iwasa

    (RIKEN Center for Emergent Matter Science (CEMS)
    The University of Tokyo)

  • Satria Zulkarnaen Bisri

    (RIKEN Center for Emergent Matter Science (CEMS)
    Tokyo Institute of Technology
    Tokyo University of Agriculture and Technology)

Abstract

Semiconducting colloidal quantum dots and their assemblies exhibit superior optical properties owing to the quantum confinement effect. Thus, they are attracting tremendous interest from fundamental research to commercial applications. However, the electrical conducting properties remain detrimental predominantly due to the orientational disorder of quantum dots in the assembly. Here we report high conductivity and the consequent metallic behaviour of semiconducting colloidal quantum dots of lead sulphide. Precise facet orientation control to forming highly-ordered quasi-2-dimensional epitaxially-connected quantum dot superlattices is vital for high conductivity. The intrinsically high mobility over 10 cm2 V−1 s−1 and temperature-independent behaviour proved the high potential of semiconductor quantum dots for electrical conducting properties. Furthermore, the continuously tunable subband filling will enable quantum dot superlattices to be a future platform for emerging physical properties investigations, such as strongly correlated and topological states, as demonstrated in the moiré superlattices of twisted bilayer graphene.

Suggested Citation

  • Ricky Dwi Septianto & Retno Miranti & Tomoka Kikitsu & Takaaki Hikima & Daisuke Hashizume & Nobuhiro Matsushita & Yoshihiro Iwasa & Satria Zulkarnaen Bisri, 2023. "Enabling metallic behaviour in two-dimensional superlattice of semiconductor colloidal quantum dots," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38216-y
    DOI: 10.1038/s41467-023-38216-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-38216-y
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-38216-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Yuan Cao & Valla Fatemi & Shiang Fang & Kenji Watanabe & Takashi Taniguchi & Efthimios Kaxiras & Pablo Jarillo-Herrero, 2018. "Unconventional superconductivity in magic-angle graphene superlattices," Nature, Nature, vol. 556(7699), pages 43-50, April.
    2. Nuri Yazdani & Samuel Andermatt & Maksym Yarema & Vasco Farto & Mohammad Hossein Bani-Hashemian & Sebastian Volk & Weyde M. M. Lin & Olesya Yarema & Mathieu Luisier & Vanessa Wood, 2020. "Charge transport in semiconductors assembled from nanocrystal quantum dots," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    3. W. Beugeling & E. Kalesaki & C. Delerue & Y.-M. Niquet & D. Vanmaekelbergh & C. Morais Smith, 2015. "Topological states in multi-orbital HgTe honeycomb lattices," Nature Communications, Nature, vol. 6(1), pages 1-7, May.
    4. F. X. Redl & K.-S. Cho & C. B. Murray & S. O'Brien, 2003. "Three-dimensional binary superlattices of magnetic nanocrystals and semiconductor quantum dots," Nature, Nature, vol. 423(6943), pages 968-971, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kenji Shibata & Masaki Yoshida & Kazuhiko Hirakawa & Tomohiro Otsuka & Satria Zulkarnaen Bisri & Yoshihiro Iwasa, 2023. "Single PbS colloidal quantum dot transistors," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. Hualiang Lv & Yuxing Yao & Mingyue Yuan & Guanyu Chen & Yuchao Wang & Longjun Rao & Shucong Li & Ufuoma I. Kara & Robert L. Dupont & Cheng Zhang & Boyuan Chen & Bo Liu & Xiaodi Zhou & Renbing Wu & Sol, 2024. "Functional nanoporous graphene superlattice," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. He Wang & Yanzhao Liu & Ming Gong & Hua Jiang & Xiaoyue Gao & Wenlong Ma & Jiawei Luo & Haoran Ji & Jun Ge & Shuang Jia & Peng Gao & Ziqiang Wang & X. C. Xie & Jian Wang, 2023. "Emergent superconductivity in topological-kagome-magnet/metal heterostructures," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. J. Díez-Mérida & A. Díez-Carlón & S. Y. Yang & Y.-M. Xie & X.-J. Gao & J. Senior & K. Watanabe & T. Taniguchi & X. Lu & A. P. Higginbotham & K. T. Law & Dmitri K. Efetov, 2023. "Symmetry-broken Josephson junctions and superconducting diodes in magic-angle twisted bilayer graphene," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    3. Li Chen & Cong Lin & Diwei Shi & Xuanyu Huang & Quanshui Zheng & Jinhui Nie & Ming Ma, 2023. "Fully automatic transfer and measurement system for structural superlubric materials," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    4. Xinyu Wang & Jinghua Jiang & Juan Chen & Zhawure Asilehan & Wentao Tang & Chenhui Peng & Rui Zhang, 2024. "Moiré effect enables versatile design of topological defects in nematic liquid crystals," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    5. Alejandro Ruiz & Brandon Gunn & Yi Lu & Kalyan Sasmal & Camilla M. Moir & Rourav Basak & Hai Huang & Jun-Sik Lee & Fanny Rodolakis & Timothy J. Boyle & Morgan Walker & Yu He & Santiago Blanco-Canosa &, 2022. "Stabilization of three-dimensional charge order through interplanar orbital hybridization in PrxY1−xBa2Cu3O6+δ," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    6. Sami Dzsaber & Diego A. Zocco & Alix McCollam & Franziska Weickert & Ross McDonald & Mathieu Taupin & Gaku Eguchi & Xinlin Yan & Andrey Prokofiev & Lucas M. K. Tang & Bryan Vlaar & Laurel E. Winter & , 2022. "Control of electronic topology in a strongly correlated electron system," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    7. Sahar Pakdel & Asbjørn Rasmussen & Alireza Taghizadeh & Mads Kruse & Thomas Olsen & Kristian S. Thygesen, 2024. "High-throughput computational stacking reveals emergent properties in natural van der Waals bilayers," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Kaijie Yang & Zian Xu & Yanjie Feng & Frank Schindler & Yuanfeng Xu & Zhen Bi & B. Andrei Bernevig & Peizhe Tang & Chao-Xing Liu, 2024. "Topological minibands and interaction driven quantum anomalous Hall state in topological insulator based moiré heterostructures," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    9. Keshav Singh & Aaron Chew & Jonah Herzog-Arbeitman & B. Andrei Bernevig & Oskar Vafek, 2024. "Topological heavy fermions in magnetic field," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    10. Peng Wang & Qidong Fu & Ruihan Peng & Yaroslav V. Kartashov & Lluis Torner & Vladimir V. Konotop & Fangwei Ye, 2022. "Two-dimensional Thouless pumping of light in photonic moiré lattices," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    11. Avior Almoalem & Irena Feldman & Ilay Mangel & Michael Shlafman & Yuval E. Yaish & Mark H. Fischer & Michael Moshe & Jonathan Ruhman & Amit Kanigel, 2024. "The observation of π-shifts in the Little-Parks effect in 4Hb-TaS2," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    12. Märta A. Tschudin & David A. Broadway & Patrick Siegwolf & Carolin Schrader & Evan J. Telford & Boris Gross & Jordan Cox & Adrien E. E. Dubois & Daniel G. Chica & Ricardo Rama-Eiroa & Elton J. G. Sant, 2024. "Imaging nanomagnetism and magnetic phase transitions in atomically thin CrSBr," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    13. Yuri Saida & Thomas Gauthier & Hiroo Suzuki & Satoshi Ohmura & Ryo Shikata & Yui Iwasaki & Godai Noyama & Misaki Kishibuchi & Yuichiro Tanaka & Wataru Yajima & Nicolas Godin & Gaël Privault & Tomoharu, 2024. "Photoinduced dynamics during electronic transfer from narrow to wide bandgap layers in one-dimensional heterostructured materials," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    14. Anushree Datta & M. J. Calderón & A. Camjayi & E. Bascones, 2023. "Heavy quasiparticles and cascades without symmetry breaking in twisted bilayer graphene," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    15. Xiaozhou Zan & Xiangdong Guo & Aolin Deng & Zhiheng Huang & Le Liu & Fanfan Wu & Yalong Yuan & Jiaojiao Zhao & Yalin Peng & Lu Li & Yangkun Zhang & Xiuzhen Li & Jundong Zhu & Jingwei Dong & Dongxia Sh, 2024. "Electron/infrared-phonon coupling in ABC trilayer graphene," Nature Communications, Nature, vol. 15(1), pages 1-6, December.
    16. Suk Hyun Sung & Yin Min Goh & Hyobin Yoo & Rebecca Engelke & Hongchao Xie & Kuan Zhang & Zidong Li & Andrew Ye & Parag B. Deotare & Ellad B. Tadmor & Andrew J. Mannix & Jiwoong Park & Liuyan Zhao & Ph, 2022. "Torsional periodic lattice distortions and diffraction of twisted 2D materials," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    17. Robin Huber & Max-Niklas Steffen & Martin Drienovsky & Andreas Sandner & Kenji Watanabe & Takashi Taniguchi & Daniela Pfannkuche & Dieter Weiss & Jonathan Eroms, 2022. "Band conductivity oscillations in a gate-tunable graphene superlattice," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    18. Shouheng Chen & Zihan Liang & Jinshui Miao & Xiang-Long Yu & Shuo Wang & Yule Zhang & Han Wang & Yun Wang & Chun Cheng & Gen Long & Taihong Wang & Lin Wang & Han Zhang & Xiaolong Chen, 2024. "Infrared optoelectronics in twisted black phosphorus," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    19. C. D. Dashwood & A. H. Walker & M. P. Kwasigroch & L. S. I. Veiga & Q. Faure & J. G. Vale & D. G. Porter & P. Manuel & D. D. Khalyavin & F. Orlandi & C. V. Colin & O. Fabelo & F. Krüger & R. S. Perry , 2023. "Strain control of a bandwidth-driven spin reorientation in Ca3Ru2O7," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    20. Jubin Nathawat & Ishiaka Mansaray & Kohei Sakanashi & Naoto Wada & Michael D. Randle & Shenchu Yin & Keke He & Nargess Arabchigavkani & Ripudaman Dixit & Bilal Barut & Miao Zhao & Harihara Ramamoorthy, 2023. "Signatures of hot carriers and hot phonons in the re-entrant metallic and semiconducting states of Moiré-gapped graphene," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38216-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.