IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-36319-0.html
   My bibliography  Save this article

Manipulating the ordered oxygen complexes to achieve high strength and ductility in medium-entropy alloys

Author

Listed:
  • Meiyuan Jiao

    (University of Science and Technology Beijing)

  • Zhifeng Lei

    (Hunan University)

  • Yuan Wu

    (University of Science and Technology Beijing)

  • Jinlong Du

    (Peking University)

  • Xiao-Ye Zhou

    (Shenzhen University)

  • Wenyue Li

    (University of Science and Technology Beijing)

  • Xiaoyuan Yuan

    (University of Science and Technology Beijing)

  • Xiaochun Liu

    (Changsha University of Science & Technology)

  • Xiangyu Zhu

    (The University of Texas at Dallas)

  • Shudao Wang

    (University of Science and Technology Beijing)

  • Huihui Zhu

    (University of Science and Technology Beijing)

  • Peipei Cao

    (University of Science and Technology Beijing)

  • Xiongjun Liu

    (University of Science and Technology Beijing)

  • Xiaobin Zhang

    (University of Science and Technology Beijing)

  • Hui Wang

    (University of Science and Technology Beijing)

  • Suihe Jiang

    (University of Science and Technology Beijing)

  • Zhaoping Lu

    (University of Science and Technology Beijing)

Abstract

Oxygen solute strengthening is an effective strategy to harden alloys, yet, it often deteriorates the ductility. Ordered oxygen complexes (OOCs), a state between random interstitials and oxides, can simultaneously enhance strength and ductility in high-entropy alloys. However, whether this particular strengthening mechanism holds in other alloys and how these OOCs are tailored remain unclear. Herein, we demonstrate that OOCs can be obtained in bcc (body-centered-cubic) Ti-Zr-Nb medium-entropy alloys via adjusting the content of Nb and oxygen. Decreasing the phase stability enhances the degree of (Ti, Zr)-rich chemical short-range orderings, and then favors formation of OOCs after doping oxygen. Moreover, the number density of OOCs increases with oxygen contents in a given alloy, but adding excessive oxygen (>3.0 at.%) causes grain boundary segregation. Consequently, the tensile yield strength is enhanced by ~75% and ductility is substantially improved by ~164% with addition of 3.0 at.% O in the Ti-30Zr-14Nb MEA.

Suggested Citation

  • Meiyuan Jiao & Zhifeng Lei & Yuan Wu & Jinlong Du & Xiao-Ye Zhou & Wenyue Li & Xiaoyuan Yuan & Xiaochun Liu & Xiangyu Zhu & Shudao Wang & Huihui Zhu & Peipei Cao & Xiongjun Liu & Xiaobin Zhang & Hui W, 2023. "Manipulating the ordered oxygen complexes to achieve high strength and ductility in medium-entropy alloys," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36319-0
    DOI: 10.1038/s41467-023-36319-0
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-36319-0
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-36319-0?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhifeng Lei & Xiongjun Liu & Yuan Wu & Hui Wang & Suihe Jiang & Shudao Wang & Xidong Hui & Yidong Wu & Baptiste Gault & Paraskevas Kontis & Dierk Raabe & Lin Gu & Qinghua Zhang & Houwen Chen & Hongtao, 2018. "Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes," Nature, Nature, vol. 563(7732), pages 546-550, November.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Linze Li & Bin Ouyang & Zhengyan Lun & Haoyan Huo & Dongchang Chen & Yuan Yue & Colin Ophus & Wei Tong & Guoying Chen & Gerbrand Ceder & Chongmin Wang, 2023. "Atomic-scale probing of short-range order and its impact on electrochemical properties in cation-disordered oxide cathodes," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Tong Li & Tianwei Liu & Shiteng Zhao & Yan Chen & Junhua Luan & Zengbao Jiao & Robert O. Ritchie & Lanhong Dai, 2023. "Ultra-strong tungsten refractory high-entropy alloy via stepwise controllable coherent nanoprecipitations," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    3. O. El Atwani & H. T. Vo & M. A. Tunes & C. Lee & A. Alvarado & N. Krienke & J. D. Poplawsky & A. A. Kohnert & J. Gigax & W.-Y. Chen & M. Li & Y. Q. Wang & J. S. Wróbel & D. Nguyen-Manh & J. K. S. Bald, 2023. "A quinary WTaCrVHf nanocrystalline refractory high-entropy alloy withholding extreme irradiation environments," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Yeqiang Bu & Yuan Wu & Zhifeng Lei & Xiaoyuan Yuan & Leqing Liu & Peng Wang & Xiongjun Liu & Honghui Wu & Jiabin Liu & Hongtao Wang & R. O. Ritchie & Zhaoping Lu & Wei Yang, 2024. "Elastic strain-induced amorphization in high-entropy alloys," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    5. Jing Wang & Ping Jiang & Fuping Yuan & Xiaolei Wu, 2022. "Chemical medium-range order in a medium-entropy alloy," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
    6. Hyojin Park & Farahnaz Haftlang & Yoon–Uk Heo & Jae Bok Seol & Zhijun Wang & Hyoung Seop Kim, 2024. "Periodic spinodal decomposition in double–strengthened medium–entropy alloy," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Chang Liu & Wenjun Lu & Wenzhen Xia & Chaowei Du & Ziyuan Rao & James P. Best & Steffen Brinckmann & Jian Lu & Baptiste Gault & Gerhard Dehm & Ge Wu & Zhiming Li & Dierk Raabe, 2022. "Massive interstitial solid solution alloys achieve near-theoretical strength," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    8. Yan Chong & Ruopeng Zhang & Mohammad S. Hooshmand & Shiteng Zhao & Daryl C. Chrzan & Mark Asta & J. W. Morris & Andrew M. Minor, 2021. "Elimination of oxygen sensitivity in α-titanium by substitutional alloying with Al," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    9. Xizheng Wang & Yunhao Zhao & Gang Chen & Xinpeng Zhao & Chuan Liu & Soumya Sridar & Luis Fernando Ladinos Pizano & Shuke Li & Alexandra H. Brozena & Miao Guo & Hanlei Zhang & Yuankang Wang & Wei Xiong, 2022. "Ultrahigh-temperature melt printing of multi-principal element alloys," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    10. Bo Xiao & Junhua Luan & Shijun Zhao & Lijun Zhang & Shiyao Chen & Yilu Zhao & Lianyong Xu & C. T. Liu & Ji-Jung Kai & Tao Yang, 2022. "Achieving thermally stable nanoparticles in chemically complex alloys via controllable sluggish lattice diffusion," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    11. Bin Ouyang & Yan Zeng, 2024. "The rise of high-entropy battery materials," Nature Communications, Nature, vol. 15(1), pages 1-5, December.
    12. Ge Wu & Chang Liu & Yong-Qiang Yan & Sida Liu & Xinyu Ma & Shengying Yue & Zhi-Wei Shan, 2024. "Elemental partitioning-mediated crystalline-to-amorphous phase transformation under quasi-static deformation," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36319-0. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.