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CO-tolerant RuNi/TiO2 catalyst for the storage and purification of crude hydrogen

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  • Zhaohua Wang

    (Peking University)

  • Chunyang Dong

    (Peking University
    Université de Lille, CNRS, Centrale Lille, ENSCL, Université d’Artois, UMR)

  • Xuan Tang

    (East China University of Science & Technology)

  • Xuetao Qin

    (Peking University)

  • Xingwu Liu

    (Peking University
    National Energy Center for Coal to Liquids, Synfuels CHINA Co., Ltd)

  • Mi Peng

    (Peking University)

  • Yao Xu

    (Peking University)

  • Chuqiao Song

    (Peking University)

  • Jie Zhang

    (Peking University)

  • Xuan Liang

    (Peking University)

  • Sheng Dai

    (East China University of Science & Technology)

  • Ding Ma

    (Peking University)

Abstract

Hydrogen storage by means of catalytic hydrogenation of suitable organic substrates helps to elevate the volumetric density of hydrogen energy. In this regard, utilizing cheaper industrial crude hydrogen to fulfill the goal of hydrogen storage would show economic attraction. However, because CO impurities in crude hydrogen can easily deactivate metal active sites even in trace amounts such a process has not yet been realized. Here, we develop a robust RuNi/TiO2 catalyst that enables the efficient hydrogenation of toluene to methyl-cyclohexane under simulated crude hydrogen feeds with 1000–5000 ppm CO impurity at around 180 °C under atmospheric pressure. We show that the co-localization of Ru and Ni species during reduction facilitated the formation of tightly coupled metallic Ru-Ni clusters. During the catalytic hydrogenation process, due to the distinct bonding properties, Ru and Ni served as the active sites for CO methanation and toluene hydrogenation respectively. Our work provides fresh insight into the effective utilization and purification of crude hydrogen for the future hydrogen economy.

Suggested Citation

  • Zhaohua Wang & Chunyang Dong & Xuan Tang & Xuetao Qin & Xingwu Liu & Mi Peng & Yao Xu & Chuqiao Song & Jie Zhang & Xuan Liang & Sheng Dai & Ding Ma, 2022. "CO-tolerant RuNi/TiO2 catalyst for the storage and purification of crude hydrogen," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32100-x
    DOI: 10.1038/s41467-022-32100-x
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    References listed on IDEAS

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    1. Luning Chen & Pragya Verma & Kaipeng Hou & Zhiyuan Qi & Shuchen Zhang & Yi-Sheng Liu & Jinghua Guo & Vitalie Stavila & Mark D. Allendorf & Lansun Zheng & Miquel Salmeron & David Prendergast & Gabor A., 2022. "Reversible dehydrogenation and rehydrogenation of cyclohexane and methylcyclohexane by single-site platinum catalyst," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Jun Zhou & Zhe Gao & Guolei Xiang & Tianyu Zhai & Zikai Liu & Weixin Zhao & Xin Liang & Leyu Wang, 2022. "Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Sharma, Sunita & Ghoshal, Sib Krishna, 2015. "Hydrogen the future transportation fuel: From production to applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1151-1158.
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