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An unexpected dual-emissive luminogen with tunable aggregation-induced emission and enhanced chiroptical property

Author

Listed:
  • Xinyu Zhang

    (University of Science and Technology of China)

  • Huiqing Liu

    (University of Science and Technology of China)

  • Guilin Zhuang

    (Zhejiang University of Technology)

  • Shangfeng Yang

    (University of Science and Technology of China)

  • Pingwu Du

    (University of Science and Technology of China)

Abstract

In the literature, organic materials with both aggregation-induced emission (AIE) and aggregation-caused quenching (ACQ) effects that can emit with multiple bands both in the solution and aggregated state are rarely reported. Herein we report a novel chiral dual-emissive bismacrocycle with tunable aggregation-induced emission colors. A facile four-step synthesis strategy is developed to construct this rigid bismacrocycle, (1,4)[8]cycloparaphenylenophane (SCPP[8]), which possesses a 1,2,4,5-tetraphenylbenzene core locked by two intersecting polyphenylene-based macrocycles. The luminescent behavior of SCPP[8] shows the unique characteristics of both ACQ effect and AIE effect, inducing remarkable redshift emission with near white-light emission. SCPP[8] is configurationally stable and possesses a novel shape-persistent bismacrocycle scaffold with a high strain energy. In addition, SCPP[8] displays enhanced circularly polarized luminescence properties due to AIE effect.

Suggested Citation

  • Xinyu Zhang & Huiqing Liu & Guilin Zhuang & Shangfeng Yang & Pingwu Du, 2022. "An unexpected dual-emissive luminogen with tunable aggregation-induced emission and enhanced chiroptical property," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31281-9
    DOI: 10.1038/s41467-022-31281-9
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    References listed on IDEAS

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    1. Zikai He & Weijun Zhao & Jacky W. Y. Lam & Qian Peng & Huili Ma & Guodong Liang & Zhigang Shuai & Ben Zhong Tang, 2017. "White light emission from a single organic molecule with dual phosphorescence at room temperature," Nature Communications, Nature, vol. 8(1), pages 1-8, December.
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    Cited by:

    1. Yun-Lan Li & Hai-Ling Wang & Zhong-Hong Zhu & Yu-Feng Wang & Fu-Pei Liang & Hua-Hong Zou, 2024. "Aggregation induced emission dynamic chiral europium(III) complexes with excellent circularly polarized luminescence and smart sensors," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    2. Xinyu Zhang & Cheng Chen & Wen Zhang & Nan Yin & Bing Yuan & Guilin Zhuang & Xiao-Ye Wang & Pingwu Du, 2024. "Anomalous anti-Kasha excited-state luminescence from symmetry-breaking heterogeneous carbon bisnanohoops," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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