IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-29370-w.html
   My bibliography  Save this article

Nuclearity enlargement from [PW9O34@Ag51] to [(PW9O34)2@Ag72] and 2D and 3D network formation driven by bipyridines

Author

Listed:
  • Zhi Wang

    (Shandong University)

  • Yan-Jie Zhu

    (Shandong University)

  • Ying-Zhou Li

    (Qilu University of Technology (Shandong Academy of Science))

  • Gui-Lin Zhuang

    (Zhejiang University of Technology)

  • Ke-Peng Song

    (Shandong University)

  • Zhi-Yong Gao

    (Henan Normal University)

  • Jian-Min Dou

    (Liaocheng University)

  • Mohamedally Kurmoo

    (Institut de Chimie de Strasbourg)

  • Chen-Ho Tung

    (Shandong University)

  • Di Sun

    (Shandong University)

Abstract

The structural transformations of metal nanoclusters are typically quite complex processes involving the formation and breakage of several bonds, and thus are challenging to study. Herein, we report a case where two lacunary Keggin polyoxometallate templated silver single-pods [PW9O34@Ag51] (SD/Ag51b) fuse to a double-pod [(PW9O34)2@Ag72] by reacting with 4,4’-bipyridine (bipy) or 1,4-bis(4-pyridinylmethyl)piperazine (pi-bipy). Their crystal structures reveal the formation of a 2D 44-sql layer (SD/Ag72a) with bipy and a 3D pcu framework (SD/Ag72c) with pi-bipy. The PW9O349− retains its structure during the cluster fusion and cluster-based network formation. Although the two processes, stripping of an Ag-ligands interface followed by fusion, and polymerization, are difficult to envisage, electrospray ionization mass spectrometry provides enough evidences for such a proposal to be made. Through this example, we expect the structural transformation to become a powerful method for synthesizing silver nanoclusters and their infinite networks, and to evolve from trial-and-error to rational.

Suggested Citation

  • Zhi Wang & Yan-Jie Zhu & Ying-Zhou Li & Gui-Lin Zhuang & Ke-Peng Song & Zhi-Yong Gao & Jian-Min Dou & Mohamedally Kurmoo & Chen-Ho Tung & Di Sun, 2022. "Nuclearity enlargement from [PW9O34@Ag51] to [(PW9O34)2@Ag72] and 2D and 3D network formation driven by bipyridines," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29370-w
    DOI: 10.1038/s41467-022-29370-w
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-29370-w
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-022-29370-w?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhi Wang & Hai-Feng Su & Chen-Ho Tung & Di Sun & Lan-Sun Zheng, 2018. "Deciphering synergetic core-shell transformation from [Mo6O22@Ag44] to [Mo8O28@Ag50]," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    2. Qiaofeng Yao & Yan Feng & Victor Fung & Yong Yu & De-en Jiang & Jun Yang & Jianping Xie, 2017. "Precise control of alloying sites of bimetallic nanoclusters via surface motif exchange reaction," Nature Communications, Nature, vol. 8(1), pages 1-11, December.
    3. Daishi Fujita & Yoshihiro Ueda & Sota Sato & Nobuhiro Mizuno & Takashi Kumasaka & Makoto Fujita, 2016. "Self-assembly of tetravalent Goldberg polyhedra from 144 small components," Nature, Nature, vol. 540(7634), pages 563-566, December.
    4. Qiaofeng Yao & Xun Yuan & Victor Fung & Yong Yu & David Tai Leong & De-en Jiang & Jianping Xie, 2017. "Understanding seed-mediated growth of gold nanoclusters at molecular level," Nature Communications, Nature, vol. 8(1), pages 1-11, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhihe Liu & Hua Tan & Bo Li & Zehua Hu & De-en Jiang & Qiaofeng Yao & Lei Wang & Jianping Xie, 2023. "Ligand effect on switching the rate-determining step of water oxidation in atomically precise metal nanoclusters," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Liang Qiao & Nia Pollard & Ravithree D. Senanayake & Zhi Yang & Minjung Kim & Arzeena S. Ali & Minh Tam Hoang & Nan Yao & Yimo Han & Rigoberto Hernandez & Andre Z. Clayborne & Matthew R. Jones, 2023. "Atomically precise nanoclusters predominantly seed gold nanoparticle syntheses," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Zhe Lian & Jing He & Lin Liu & Yanqing Fan & Xuebo Chen & Hua Jiang, 2023. "[2,2] Paracyclophanes-based double helicates for constructing artificial light-harvesting systems and white LED device," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Xiao-Li Pei & Pei Zhao & Hitoshi Ube & Zhen Lei & Masahiro Ehara & Mitsuhiko Shionoya, 2024. "Single-gold etching at the hypercarbon atom of C-centred hexagold(I) clusters protected by chiral N-heterocyclic carbenes," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    5. Tsukasa Abe & Keisuke Takeuchi & Masahiro Higashi & Hirofumi Sato & Shuichi Hiraoka, 2024. "Rational design of metal–organic cages to increase the number of components via dihedral angle control," Nature Communications, Nature, vol. 15(1), pages 1-17, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29370-w. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.