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Completely aqueous processable stimulus responsive organic room temperature phosphorescence materials with tunable afterglow color

Author

Listed:
  • Dan Li

    (Tianjin University)

  • Yujie Yang

    (Tianjin University)

  • Jie Yang

    (Tianjin University)

  • Manman Fang

    (Tianjin University)

  • Ben Zhong Tang

    (Tianjin University
    The Chinese University of Hong Kong)

  • Zhen Li

    (Tianjin University
    Tianjin University
    Wuhan University
    Tianjin University, International Campus of Tianjin University)

Abstract

Many luminescent stimuli responsive materials are based on fluorescence emission, while stimuli-responsive room temperature phosphorescent materials are less explored. Here, we show a kind of stimulus-responsive room temperature phosphorescence materials by the covalent linkage of phosphorescent chromophore of arylboronic acid and polymer matrix of poly(vinylalcohol). Attributed to the rigid environment offered from hydrogen bond and B-O covalent bond between arylboronic acid and poly(vinylalcohol), the yielded polymer film exhibits ultralong room temperature phosphorescence with lifetime of 2.43 s and phosphorescence quantum yield of 7.51%. Interestingly, the RTP property of this film is sensitive to the water and heat stimuli, because water could destroy the hydrogen bonds between adjacent poly(vinylalcohol) polymers, then changing the rigidity of this system. Furthermore, by introducing another two fluorescent dyes to this system, the color of afterglow with stimulus response effect could be adjusted from blue to green to orange through triplet-to-singlet Förster-resonance energy-transfer. Finally, due to the water/heat-sensitive, multicolor and completely aqueous processable feature for these three afterglow hybrids, they are successfully applied in multifunctional ink for anti-counterfeit, screen printing and fingerprint record.

Suggested Citation

  • Dan Li & Yujie Yang & Jie Yang & Manman Fang & Ben Zhong Tang & Zhen Li, 2022. "Completely aqueous processable stimulus responsive organic room temperature phosphorescence materials with tunable afterglow color," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28011-6
    DOI: 10.1038/s41467-022-28011-6
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    References listed on IDEAS

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    1. Shiki Yagai & Satoru Okamura & Yujiro Nakano & Mitsuaki Yamauchi & Keiki Kishikawa & Takashi Karatsu & Akihide Kitamura & Akira Ueno & Daiki Kuzuhara & Hiroko Yamada & Tomohiro Seki & Hajime Ito, 2014. "Design amphiphilic dipolar π-systems for stimuli-responsive luminescent materials using metastable states," Nature Communications, Nature, vol. 5(1), pages 1-10, December.
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    Cited by:

    1. Xiaoyu Chen & Renlong Zhu & Baicheng Zhang & Xiaolong Zhang & Aoyuan Cheng & Hongping Liu & Ruiying Gao & Xuepeng Zhang & Biao Chen & Shuji Ye & Jun Jiang & Guoqing Zhang, 2024. "Rapid room-temperature phosphorescence chiral recognition of natural amino acids," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Juan Wei & Mingye Zhu & Tingchen Du & Jangang Li & Peiling Dai & Chenyuan Liu & Jiayu Duan & Shujuan Liu & Xingcheng Zhou & Sudi Zhang & Luo Guo & Hao Wang & Yun Ma & Wei Huang & Qiang Zhao, 2023. "Full-color persistent room temperature phosphorescent elastomers with robust optical properties," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    3. Xue Chen & Mengfen Che & Weidong Xu & Zhongbin Wu & Yung Doug Suh & Suli Wu & Xiaowang Liu & Wei Huang, 2024. "Matrix-induced defects and molecular doping in the afterglow of SiO2 microparticles," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Liang Gao & Jiayue Huang & Lunjun Qu & Xiaohong Chen & Ying Zhu & Chen Li & Quanchi Tian & Yanli Zhao & Chaolong Yang, 2023. "Stepwise taming of triplet excitons via multiple confinements in intrinsic polymers for long-lived room-temperature phosphorescence," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Xiaolu Zhou & Xue Bai & Fangjian Shang & Heng-Yi Zhang & Li-Hua Wang & Xiufang Xu & Yu Liu, 2024. "Supramolecular assembly activated single-molecule phosphorescence resonance energy transfer for near-infrared targeted cell imaging," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    6. Zizhao Huang & Zhenyi He & Bingbing Ding & He Tian & Xiang Ma, 2022. "Photoprogrammable circularly polarized phosphorescence switching of chiral helical polyacetylene thin films," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    7. Xiao Zhang & Mingjian Zeng & Yewen Zhang & Chenyu Zhang & Zhisheng Gao & Fei He & Xudong Xue & Huanhuan Li & Ping Li & Gaozhan Xie & Hui Li & Xin Zhang & Ningning Guo & He Cheng & Ansheng Luo & Wei Zh, 2023. "Multicolor hyperafterglow from isolated fluorescence chromophores," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Guang Lu & Jing Tan & Hongxiang Wang & Yi Man & Shuo Chen & Jing Zhang & Chunbo Duan & Chunmiao Han & Hui Xu, 2024. "Delayed room temperature phosphorescence enabled by phosphines," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    9. Rui Tian & Shuo Gao & Kaitao Li & Chao Lu, 2023. "Design of mechanical-robust phosphorescence materials through covalent click reaction," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    10. Juan Wei & Chenyuan Liu & Jiayu Duan & Aiwen Shao & Jinlu Li & Jiangang Li & Wenjie Gu & Zixian Li & Shujuan Liu & Yun Ma & Wei Huang & Qiang Zhao, 2023. "Conformation-dependent dynamic organic phosphorescence through thermal energy driven molecular rotations," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    11. Qinglong Jia & Xilong Yan & Bowei Wang & Jiayi Li & Wensheng Xu & Zhuoyao Shen & Changchang Bo & Yang Li & Ligong Chen, 2023. "Construction of room temperature phosphorescent materials with ultralong lifetime by in-situ derivation strategy," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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