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Large-area integration of two-dimensional materials and their heterostructures by wafer bonding

Author

Listed:
  • Arne Quellmalz

    (KTH Royal Institute of Technology)

  • Xiaojing Wang

    (KTH Royal Institute of Technology)

  • Simon Sawallich

    (Protemics GmbH
    RWTH Aachen University)

  • Burkay Uzlu

    (RWTH Aachen University
    Advanced Microelectronic Center Aachen (AMICA))

  • Martin Otto

    (Advanced Microelectronic Center Aachen (AMICA))

  • Stefan Wagner

    (Advanced Microelectronic Center Aachen (AMICA))

  • Zhenxing Wang

    (Advanced Microelectronic Center Aachen (AMICA))

  • Maximilian Prechtl

    (Universität der Bundeswehr München)

  • Oliver Hartwig

    (Universität der Bundeswehr München)

  • Siwei Luo

    (Universität der Bundeswehr München)

  • Georg S. Duesberg

    (Universität der Bundeswehr München)

  • Max C. Lemme

    (RWTH Aachen University
    Advanced Microelectronic Center Aachen (AMICA))

  • Kristinn B. Gylfason

    (KTH Royal Institute of Technology)

  • Niclas Roxhed

    (KTH Royal Institute of Technology)

  • Göran Stemme

    (KTH Royal Institute of Technology)

  • Frank Niklaus

    (KTH Royal Institute of Technology)

Abstract

Integrating two-dimensional (2D) materials into semiconductor manufacturing lines is essential to exploit their material properties in a wide range of application areas. However, current approaches are not compatible with high-volume manufacturing on wafer level. Here, we report a generic methodology for large-area integration of 2D materials by adhesive wafer bonding. Our approach avoids manual handling and uses equipment, processes, and materials that are readily available in large-scale semiconductor manufacturing lines. We demonstrate the transfer of CVD graphene from copper foils (100-mm diameter) and molybdenum disulfide (MoS2) from SiO2/Si chips (centimeter-sized) to silicon wafers (100-mm diameter). Furthermore, we stack graphene with CVD hexagonal boron nitride and MoS2 layers to heterostructures, and fabricate encapsulated field-effect graphene devices, with high carrier mobilities of up to $$4520\;{\mathrm{cm}}^2{\mathrm{V}}^{ - 1}{\mathrm{s}}^{ - 1}$$ 4520 cm 2 V − 1 s − 1 . Thus, our approach is suited for backend of the line integration of 2D materials on top of integrated circuits, with potential to accelerate progress in electronics, photonics, and sensing.

Suggested Citation

  • Arne Quellmalz & Xiaojing Wang & Simon Sawallich & Burkay Uzlu & Martin Otto & Stefan Wagner & Zhenxing Wang & Maximilian Prechtl & Oliver Hartwig & Siwei Luo & Georg S. Duesberg & Max C. Lemme & Kris, 2021. "Large-area integration of two-dimensional materials and their heterostructures by wafer bonding," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-21136-0
    DOI: 10.1038/s41467-021-21136-0
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    Cited by:

    1. Josef Schätz & Navin Nayi & Jonas Weber & Christoph Metzke & Sebastian Lukas & Jürgen Walter & Tim Schaffus & Fabian Streb & Eros Reato & Agata Piacentini & Annika Grundmann & Holger Kalisch & Michael, 2024. "Button shear testing for adhesion measurements of 2D materials," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Yangshuang Bian & Mingliang Zhu & Chengyu Wang & Kai Liu & Wenkang Shi & Zhiheng Zhu & Mingcong Qin & Fan Zhang & Zhiyuan Zhao & Hanlin Wang & Yunqi Liu & Yunlong Guo, 2024. "A detachable interface for stable low-voltage stretchable transistor arrays and high-resolution X-ray imaging," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    3. Xin Gao & Liming Zheng & Fang Luo & Jun Qian & Jingyue Wang & Mingzhi Yan & Wendong Wang & Qinci Wu & Junchuan Tang & Yisen Cao & Congwei Tan & Jilin Tang & Mengjian Zhu & Yani Wang & Yanglizhi Li & L, 2022. "Integrated wafer-scale ultra-flat graphene by gradient surface energy modulation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Max C. Lemme & Deji Akinwande & Cedric Huyghebaert & Christoph Stampfer, 2022. "2D materials for future heterogeneous electronics," Nature Communications, Nature, vol. 13(1), pages 1-5, December.

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