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Molecularly-porous ultrathin membranes for highly selective organic solvent nanofiltration

Author

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  • Tiefan Huang

    (Nanostructured Polymeric Membranes Laboratory, Advanced Membranes and Porous Materials Center, Biological and Environmental Science and Engineering Division (BESE), King Abdullah University of Science and Technology (KAUST)
    Hunan University of Science and Technology)

  • Basem A. Moosa

    (Smart Hybrid Materials (SHMs) Laboratory, Advanced Membranes and Porous Materials Center, Physical Sciences and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST))

  • Phuong Hoang

    (Smart Hybrid Materials (SHMs) Laboratory, Advanced Membranes and Porous Materials Center, Physical Sciences and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST))

  • Jiangtao Liu

    (Nanostructured Polymeric Membranes Laboratory, Advanced Membranes and Porous Materials Center, Biological and Environmental Science and Engineering Division (BESE), King Abdullah University of Science and Technology (KAUST))

  • Stefan Chisca

    (Nanostructured Polymeric Membranes Laboratory, Advanced Membranes and Porous Materials Center, Biological and Environmental Science and Engineering Division (BESE), King Abdullah University of Science and Technology (KAUST))

  • Gengwu Zhang

    (Smart Hybrid Materials (SHMs) Laboratory, Advanced Membranes and Porous Materials Center, Physical Sciences and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST))

  • Mram AlYami

    (Smart Hybrid Materials (SHMs) Laboratory, Advanced Membranes and Porous Materials Center, Physical Sciences and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST))

  • Niveen M. Khashab

    (Smart Hybrid Materials (SHMs) Laboratory, Advanced Membranes and Porous Materials Center, Physical Sciences and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST))

  • Suzana P. Nunes

    (Nanostructured Polymeric Membranes Laboratory, Advanced Membranes and Porous Materials Center, Biological and Environmental Science and Engineering Division (BESE), King Abdullah University of Science and Technology (KAUST))

Abstract

Engineering membranes for molecular separation in organic solvents is still a big challenge. When the selectivity increases, the permeability tends to drastically decrease, increasing the energy demands for the separation process. Ideally, organic solvent nanofiltration membranes should be thin to enhance the permeant transport, have a well-tailored nanoporosity and high stability in harsh solvents. Here, we introduce a trianglamine macrocycle as a molecular building block for cross-linked membranes, prepared by facile interfacial polymerization, for high-performance selective separations. The membranes were prepared via a two-in-one strategy, enabled by the amine macrocycle, by simultaneously reducing the thickness of the thin-film layers (

Suggested Citation

  • Tiefan Huang & Basem A. Moosa & Phuong Hoang & Jiangtao Liu & Stefan Chisca & Gengwu Zhang & Mram AlYami & Niveen M. Khashab & Suzana P. Nunes, 2020. "Molecularly-porous ultrathin membranes for highly selective organic solvent nanofiltration," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-19404-6
    DOI: 10.1038/s41467-020-19404-6
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    Cited by:

    1. Shanshan Hong & Maria Vincenzo & Alberto Tiraferri & Erica Bertozzi & Radosław Górecki & Bambar Davaasuren & Xiang Li & Suzana P. Nunes, 2024. "Precision ion separation via self-assembled channels," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    2. Shuangqiao Han & Junyong Zhu & Adam A. Uliana & Dongyang Li & Yatao Zhang & Lin Zhang & Yong Wang & Tao He & Menachem Elimelech, 2022. "Microporous organic nanotube assisted design of high performance nanofiltration membranes," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Jinrong Wang & Weibin Lin & Zhuo Chen & Valeriia O. Nikolaeva & Lukman O. Alimi & Niveen M. Khashab, 2024. "Smart touchless human–machine interaction based on crystalline porous cages," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Banan Alhazmi & Gergo Ignacz & Maria Vincenzo & Mohamed Nejib Hedhili & Gyorgy Szekely & Suzana P. Nunes, 2024. "Ultraselective Macrocycle Membranes for Pharmaceutical Ingredients Separation in Organic Solvents," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    5. Huawen Peng & Kaicheng Yu & Xufei Liu & Jiapeng Li & Xiangguo Hu & Qiang Zhao, 2023. "Quaternization-spiro design of chlorine-resistant and high-permeance lithium separation membranes," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Si-Hua Liu & Jun-Hao Zhou & Chunrui Wu & Peng Zhang & Xingzhong Cao & Jian-Ke Sun, 2024. "Sub-8 nm networked cage nanofilm with tunable nanofluidic channels for adaptive sieving," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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