IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v10y2019i1d10.1038_s41467-019-09924-1.html
   My bibliography  Save this article

Fast lithium growth and short circuit induced by localized-temperature hotspots in lithium batteries

Author

Listed:
  • Yangying Zhu

    (Stanford University)

  • Jin Xie

    (Stanford University
    ShanghaiTech University)

  • Allen Pei

    (Stanford University)

  • Bofei Liu

    (Stanford University)

  • Yecun Wu

    (Stanford University
    Stanford University)

  • Dingchang Lin

    (Stanford University)

  • Jun Li

    (Stanford University
    Stanford University)

  • Hansen Wang

    (Stanford University)

  • Hao Chen

    (Stanford University)

  • Jinwei Xu

    (Stanford University)

  • Ankun Yang

    (Stanford University)

  • Chun-Lan Wu

    (Stanford University)

  • Hongxia Wang

    (Stanford University)

  • Wei Chen

    (Stanford University)

  • Yi Cui

    (Stanford University
    Stanford Institute for Materials and Energy Sciences)

Abstract

Fast-charging and high-energy-density batteries pose significant safety concerns due to high rates of heat generation. Understanding how localized high temperatures affect the battery is critical but remains challenging, mainly due to the difficulty of probing battery internal temperature with high spatial resolution. Here we introduce a method to induce and sense localized high temperature inside a lithium battery using micro-Raman spectroscopy. We discover that temperature hotspots can induce significant lithium metal growth as compared to the surrounding lower temperature area due to the locally enhanced surface exchange current density. More importantly, localized high temperature can be one of the factors to cause battery internal shorting, which further elevates the temperature and increases the risk of thermal runaway. This work provides important insights on the effects of heterogeneous temperatures within batteries and aids the development of safer batteries, thermal management schemes, and diagnostic tools.

Suggested Citation

  • Yangying Zhu & Jin Xie & Allen Pei & Bofei Liu & Yecun Wu & Dingchang Lin & Jun Li & Hansen Wang & Hao Chen & Jinwei Xu & Ankun Yang & Chun-Lan Wu & Hongxia Wang & Wei Chen & Yi Cui, 2019. "Fast lithium growth and short circuit induced by localized-temperature hotspots in lithium batteries," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-019-09924-1
    DOI: 10.1038/s41467-019-09924-1
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-019-09924-1
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-019-09924-1?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Guangxu & Wei, Xuezhe & Tang, Xuan & Zhu, Jiangong & Chen, Siqi & Dai, Haifeng, 2021. "Internal short circuit mechanisms, experimental approaches and detection methods of lithium-ion batteries for electric vehicles: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    2. Li, Da & Zhang, Lei & Zhang, Zhaosheng & Liu, Peng & Deng, Junjun & Wang, Qiushi & Wang, Zhenpo, 2023. "Battery safety issue detection in real-world electric vehicles by integrated modeling and voltage abnormality," Energy, Elsevier, vol. 284(C).
    3. Xu, Bin & Lee, Jinwoo & Kwon, Daeil & Kong, Lingxi & Pecht, Michael, 2021. "Mitigation strategies for Li-ion battery thermal runaway: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    4. Fan, Zhaohui & Fu, Yijie & Liang, Hong & Gao, Renjing & Liu, Shutian, 2023. "A module-level charging optimization method of lithium-ion battery considering temperature gradient effect of liquid cooling and charging time," Energy, Elsevier, vol. 265(C).
    5. Lin, Xiang-Wei & Li, Yu-Bai & Wu, Wei-Tao & Zhou, Zhi-Fu & Chen, Bin, 2024. "Advances on two-phase heat transfer for lithium-ion battery thermal management," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    6. Qiao, Dongdong & Wang, Xueyuan & Lai, Xin & Zheng, Yuejiu & Wei, Xuezhe & Dai, Haifeng, 2022. "Online quantitative diagnosis of internal short circuit for lithium-ion batteries using incremental capacity method," Energy, Elsevier, vol. 243(C).
    7. Christensen, Paul A. & Anderson, Paul A. & Harper, Gavin D.J. & Lambert, Simon M. & Mrozik, Wojciech & Rajaeifar, Mohammad Ali & Wise, Malcolm S. & Heidrich, Oliver, 2021. "Risk management over the life cycle of lithium-ion batteries in electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    8. Khurshid, Adnan & Chen, Yufeng & Rauf, Abdur & Khan, Khalid, 2023. "Critical metals in uncertainty: How Russia-Ukraine conflict drives their prices?," Resources Policy, Elsevier, vol. 85(PB).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-019-09924-1. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.