Holistic Assessment of Decarbonization Pathways of Energy-Intensive Industries Based on Exergy Analysis

The decarbonization of the industrial sector plays a crucial role in a successful energy transition. This transformation is very costly and complex, as many of the existing production processes and plants will have to be partially or completely replaced to reduce carbon dioxide (CO 2 ) emissions. This raises questions about how significant reductions in CO 2 emissions resulting from decarbonization will affect the use of resources to produce a certain product and the overall value of sustainability. This article considers the relationship between CO 2 reduction and the impact on the resource efficiency of an industrial production process. For this purpose, a methodology was developed that holistically assesses the decarbonization pathway of an industrial sector. This holistic assessment takes into account the energy carriers, raw materials, and auxiliary and construction materials used for the operation and building of the significant plant components and summarizes them as a total use of resources. For this purpose, the use of resources is represented by the thermodynamic quantity exergy, which takes into account both the energy and material components of a production process. The energy and material streams in a production process are balanced by applying exergetic analysis. This methodology is used for current state-of-the-art and future decarbonized production processes in order to quantify the effects of the decarbonization process. By comparing the calculated resource efficiencies, the thermodynamic impact on the sustainability of decarbonization paths can be set in relation to the amount of CO 2 saved. For validation, the developed methodology is applied to a conventional and a decarbonized ammonia production process. The conventional production route represents the production of ammonia by methane steam reforming, and the decarbonized production route is represented by synthesis gas production via water electrolysis and an air separation unit. The resource efficiency of the conventional ammonia production route, taking into account the energy sources, raw materials, construction materials, and auxiliary materials used, is 59%, producing a total of 1539 kg of CO 2 emissions per ton of ammonia. The decarbonized process has a resource efficiency of 45%, while no CO 2 emissions are produced in this manufacturing process. This means that the decarbonization of the production process reduces resource efficiency by 14%. In relation to the reduced amount of CO 2 , specific resource efficiency decreases by 9.09%/t CO2 . The decline in resource efficiency is mainly due to the high level of heat and energy recovery in the conventional process and the very electricity-intensive hydrogen production in the decarbonized production process.