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A Carbon-Cloth Anode Electroplated with Iron Nanostructure for Microbial Fuel Cell Operated with Real Wastewater

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  • Enas Taha Sayed

    (Center for Advanced Materials Research, University of Sharjah, Sharjah 27272, UAE
    Chemical Engineering Department, Faculty of Engineering, Minia University, Al Minya 61111, Egypt)

  • Hussain Alawadhi

    (Center for Advanced Materials Research, University of Sharjah, Sharjah 27272, UAE
    Department of Applied Physics and Astronomy, University of Sharjah, PO Box, Sharjah 27272, UAE)

  • Khaled Elsaid

    (Chemical Engineering Program, Texas A&M University, College Station, TX 77843-3122, USA)

  • A. G. Olabi

    (Center for Advanced Materials Research, University of Sharjah, Sharjah 27272, UAE
    Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah 27272, UAE
    Mechanical Engineering and Design, School of Engineering and Applied Science, Aston University, Aston Triangle, Birmingham B4 7DA, UK)

  • Maryam Adel Almakrani

    (Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah 27272, UAE)

  • Shaikha Tamim Bin Tamim

    (Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah 27272, UAE)

  • Ghada H. M. Alafranji

    (Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah 27272, UAE)

  • Mohammad Ali Abdelkareem

    (Center for Advanced Materials Research, University of Sharjah, Sharjah 27272, UAE
    Chemical Engineering Department, Faculty of Engineering, Minia University, Al Minya 61111, Egypt
    Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah 27272, UAE)

Abstract

Microbial fuel cell (MFC) is an emerging method for extracting energy from wastewater. The power generated from such systems is low due to the sluggish electron transfer from the inside of the biocatalyst to the anode surface. One strategy for enhancing the electron transfer rate is anode modification. In this study, iron nanostructure was synthesized on a carbon cloth (CC) via a simple electroplating technique, and later investigated as a bio-anode in an MFC operated with real wastewater. The performance of an MFC with a nano-layer of iron was compared to that using bare CC. The results demonstrated that the open-circuit voltage increased from 600 mV in the case of bare CC to 800 mV in the case of the iron modified CC, showing a 33% increase in OCV. This increase in OCV can be credited to the decrease in the anode potential from 0.16 V vs. Ag/AgCl in the case of bare CC, to −0.01 V vs. Ag/AgCl in the case of the modified CC. The power output in the case of the modified electrode was 80 mW/m 2 —two times that of the MFC using the bare CC. Furthermore, the steady-state current in the case of the iron modified carbon cloth was two times that of the bare CC electrode. The improved performance was correlated to the enhanced electron transfer between the microorganisms and the iron-plated surface, along with the increase of the anode surface- as confirmed from the electrochemical impedance spectroscopy and the surface morphology, respectively.

Suggested Citation

  • Enas Taha Sayed & Hussain Alawadhi & Khaled Elsaid & A. G. Olabi & Maryam Adel Almakrani & Shaikha Tamim Bin Tamim & Ghada H. M. Alafranji & Mohammad Ali Abdelkareem, 2020. "A Carbon-Cloth Anode Electroplated with Iron Nanostructure for Microbial Fuel Cell Operated with Real Wastewater," Sustainability, MDPI, vol. 12(16), pages 1-11, August.
    • Handle: RePEc:gam:jsusta:v:12:y:2020:i:16:p:6538-:d:398314
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    References listed on IDEAS

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    6. Wilberforce, Tabbi & El Hassan, Zaki & Durrant, A. & Thompson, J. & Soudan, Bassel & Olabi, A.G., 2019. "Overview of ocean power technology," Energy, Elsevier, vol. 175(C), pages 165-181.
    7. Abdelkareem, Mohammad Ali & Tanveer, Waqas Hassan & Sayed, Enas Taha & Assad, M. El Haj & Allagui, Anis & Cha, S.W., 2019. "On the technical challenges affecting the performance of direct internal reforming biogas solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 361-375.
    8. Fathy, Ahmed & Elaziz, Mohamed Abd & Sayed, Enas Taha & Olabi, A.G. & Rezk, Hegazy, 2019. "Optimal parameter identification of triple-junction photovoltaic panel based on enhanced moth search algorithm," Energy, Elsevier, vol. 188(C).
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    10. Olabi, Abdul Ghani & Mahmoud, Montaser & Soudan, Bassel & Wilberforce, Tabbi & Ramadan, Mohamad, 2020. "Geothermal based hybrid energy systems, toward eco-friendly energy approaches," Renewable Energy, Elsevier, vol. 147(P1), pages 2003-2012.
    11. Rezk, Hegazy & Sayed, Enas Taha & Al-Dhaifallah, Mujahed & Obaid, M. & El-Sayed, Abou Hashema M. & Abdelkareem, Mohammad Ali & Olabi, A.G., 2019. "Fuel cell as an effective energy storage in reverse osmosis desalination plant powered by photovoltaic system," Energy, Elsevier, vol. 175(C), pages 423-433.
    12. Abdelkareem, Mohammad Ali & Allagui, Anis & Sayed, Enas Taha & El Haj Assad, M. & Said, Zafar & Elsaid, Khaled, 2019. "Comparative analysis of liquid versus vapor-feed passive direct methanol fuel cells," Renewable Energy, Elsevier, vol. 131(C), pages 563-584.
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    Cited by:

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    2. Hegazy Rezk & A. G. Olabi & Mohammad Ali Abdelkareem & Hussein M. Maghrabie & Enas Taha Sayed, 2023. "Fuzzy Modelling and Optimization of Yeast-MFC for Simultaneous Wastewater Treatment and Electrical Energy Production," Sustainability, MDPI, vol. 15(3), pages 1-12, January.
    3. Dawid Nosek & Tomasz Mikołajczyk & Agnieszka Cydzik-Kwiatkowska, 2023. "Anode Modification with Fe 2 O 3 Affects the Anode Microbiome and Improves Energy Generation in Microbial Fuel Cells Powered by Wastewater," IJERPH, MDPI, vol. 20(3), pages 1-21, January.
    4. Dawid Nosek & Piotr Jachimowicz & Agnieszka Cydzik-Kwiatkowska, 2020. "Anode Modification as an Alternative Approach to Improve Electricity Generation in Microbial Fuel Cells," Energies, MDPI, vol. 13(24), pages 1-22, December.
    5. Halima Alnaqbi & Oussama El-Kadri & Mohammad Ali Abdelkareem & Sameer Al-Asheh, 2022. "Recent Progress in Metal-Organic Framework-Derived Chalcogenides (MX; X = S, Se) as Electrode Materials for Supercapacitors and Catalysts in Fuel Cells," Energies, MDPI, vol. 15(21), pages 1-25, November.
    6. Rajesh Banu Jeyakumar & Godvin Sharmila Vincent, 2022. "Recent Advances and Perspectives of Nanotechnology in Anaerobic Digestion: A New Paradigm towards Sludge Biodegradability," Sustainability, MDPI, vol. 14(12), pages 1-18, June.
    7. Wilberforce, Tabbi & Abdelkareem, Mohammad Ali & Elsaid, Khaled & Olabi, A.G. & Sayed, Enas Taha, 2022. "Role of carbon-based nanomaterials in improving the performance of microbial fuel cells," Energy, Elsevier, vol. 240(C).
    8. Ahmed Fathy & Hegazy Rezk & Dalia Yousri & Abdullah G. Alharbi & Sulaiman Alshammari & Yahia B. Hassan, 2023. "Maximizing Bio-Hydrogen Production from an Innovative Microbial Electrolysis Cell Using Artificial Intelligence," Sustainability, MDPI, vol. 15(4), pages 1-13, February.
    9. A. G. Olabi & Tabbi Wilberforce & Khaled Elsaid & Tareq Salameh & Enas Taha Sayed & Khaled Saleh Husain & Mohammad Ali Abdelkareem, 2021. "Selection Guidelines for Wind Energy Technologies," Energies, MDPI, vol. 14(11), pages 1-34, June.
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    12. Enas Taha Sayed & Abdul Ghani Olabi & Abdul Hai Alami & Ali Radwan & Ayman Mdallal & Ahmed Rezk & Mohammad Ali Abdelkareem, 2023. "Renewable Energy and Energy Storage Systems," Energies, MDPI, vol. 16(3), pages 1-26, February.

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