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Electrostatic Self-Assembly of Fe 3 O 4 Nanoparticles on Graphene Oxides for High Capacity Lithium-Ion Battery Anodes

Author

Listed:
  • Taegyune Yoon

    (Department of Chemical Engineering, Dong-A University, Busan 604-714, Korea)

  • Jaegyeong Kim

    (Department of Chemical Engineering, Dong-A University, Busan 604-714, Korea)

  • Jinku Kim

    (Department of Bio and Chemical Engineering, Hongik University, Sejong 339-701, Korea)

  • Jung Kyoo Lee

    (Department of Chemical Engineering, Dong-A University, Busan 604-714, Korea)

Abstract

Magnetite, Fe 3 O 4 , is a promising anode material for lithium ion batteries due to its high theoretical capacity (924 mA h g −1 ), high density, low cost and low toxicity. However, its application as high capacity anodes is still hampered by poor cycling performance. To stabilize the cycling performance of Fe 3 O 4 nanoparticles, composites comprising Fe 3 O 4 nanoparticles and graphene sheets (GS) were fabricated. The Fe 3 O 4 /GS composite disks of mm dimensions were prepared by electrostatic self-assembly between negatively charged graphene oxide (GO) sheets and positively charged Fe 3 O 4 -APTMS [Fe 3 O 4 grafted with (3-aminopropyl)trimethoxysilane (APTMS)] in an acidic solution (pH = 2) followed by in situ chemical reduction. Thus prepared Fe 3 O 4 /GS composite showed an excellent rate capability as well as much enhanced cycling stability compared with Fe 3 O 4 electrode. The superior electrochemical responses of Fe 3 O 4 /GS composite disks assure the advantages of: (1) electrostatic self-assembly between high storage-capacity materials with GO; and (2) incorporation of GS in the Fe 3 O 4 /GS composite for high capacity lithium-ion battery application.

Suggested Citation

  • Taegyune Yoon & Jaegyeong Kim & Jinku Kim & Jung Kyoo Lee, 2013. "Electrostatic Self-Assembly of Fe 3 O 4 Nanoparticles on Graphene Oxides for High Capacity Lithium-Ion Battery Anodes," Energies, MDPI, vol. 6(9), pages 1-11, September.
    • Handle: RePEc:gam:jeners:v:6:y:2013:i:9:p:4830-4840:d:28765
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    1. P. Poizot & S. Laruelle & S. Grugeon & L. Dupont & J-M. Tarascon, 2000. "Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries," Nature, Nature, vol. 407(6803), pages 496-499, September.
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