IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v5y2012i2p420-437d16265.html
   My bibliography  Save this article

The Driving Forces of Guest Substitution in Gas Hydrates—A Laser Raman Study on CH 4 -CO 2 Exchange in the Presence of Impurities

Author

Listed:
  • Bettina Beeskow-Strauch

    (Helmholtz Centre Potsdam, German Research Centre for Geosciences (GFZ), Telegrafenberg, 14473 Potsdam, Germany)

  • Judith Maria Schicks

    (Helmholtz Centre Potsdam, German Research Centre for Geosciences (GFZ), Telegrafenberg, 14473 Potsdam, Germany)

Abstract

The recovery of CH 4 gas from natural hydrate formations by injection of industrially emitted CO 2 is considered to be a promising solution to simultaneously access an unconventional fossil fuel reserve and counteract atmospheric CO 2 increase. CO 2 obtained from industrial processes may contain traces of impurities such as SO 2 or NO x and natural gas hydrates may contain higher hydrocarbons such as C 2 H 6 and C 3 H 8 . These additions have an influence on the properties of the resulting hydrate phase and the conversion process of CH 4 -rich hydrates to CO 2 -rich hydrates. Here we show results of a microscopic and laser Raman in situ study investigating the effects of SO 2 -polluted CO 2 and mixed CH 4 -C 2 H 6 hydrate on the exchange process. Our study shows that the key driving force of the exchange processes is the establishment of the chemical equilibrium between hydrate phase and the surrounding phases. The exchange rate is also influenced by the guest-to-cavity ratio as well as the thermodynamic stability in terms of p - T conditions of the original and resulting hydrate phase. The most effective molecule exchange is related to structural changes (sI-sII) which indicates that hydrate decomposition and reformation processes are the occurring processes.

Suggested Citation

  • Bettina Beeskow-Strauch & Judith Maria Schicks, 2012. "The Driving Forces of Guest Substitution in Gas Hydrates—A Laser Raman Study on CH 4 -CO 2 Exchange in the Presence of Impurities," Energies, MDPI, vol. 5(2), pages 1-18, February.
    • Handle: RePEc:gam:jeners:v:5:y:2012:i:2:p:420-437:d:16265
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/5/2/420/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/5/2/420/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Hailong Lu & Yu-taek Seo & Jong-won Lee & Igor Moudrakovski & John A. Ripmeester & N. Ross Chapman & Richard B. Coffin & Graeme Gardner & John Pohlman, 2007. "Complex gas hydrate from the Cascadia margin," Nature, Nature, vol. 445(7125), pages 303-306, January.
    2. Aydin, Gokhan & Karakurt, Izzet & Aydiner, Kerim, 2010. "Evaluation of geologic storage options of CO2: Applicability, cost, storage capacity and safety," Energy Policy, Elsevier, vol. 38(9), pages 5072-5080, September.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gajanan, K. & Ranjith, P.G. & Yang, S.Q. & Xu, T., 2024. "Advances in research and developments on natural gas hydrate extraction with gas exchange," Renewable and Sustainable Energy Reviews, Elsevier, vol. 190(PB).
    2. Ouyang, Qian & Pandey, Jyoti Shanker & von Solms, Nicolas, 2022. "Insights into multistep depressurization of CH4/CO2 mixed hydrates in unconsolidated sediments," Energy, Elsevier, vol. 260(C).
    3. Lee, Yohan & Kim, Yunju & Lee, Jaehyoung & Lee, Huen & Seo, Yongwon, 2015. "CH4 recovery and CO2 sequestration using flue gas in natural gas hydrates as revealed by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 150(C), pages 120-127.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ningning Zhao & Tianfu Xu & Kairan Wang & Hailong Tian & Fugang Wang, 2018. "Experimental study of physical‐chemical properties modification of coal after CO2 sequestration in deep unmineable coal seams," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(3), pages 510-528, June.
    2. Lee, Joonseop & Lee, Dongyoung & Seo, Yongwon, 2021. "Experimental investigation of the exact role of large-molecule guest substances (LMGSs) in determining phase equilibria and structures of natural gas hydrates," Energy, Elsevier, vol. 215(PB).
    3. Qian Wu & Qianguo Lin & Qiang Yang & Yang Li, 2022. "An optimization‐based CCUS source‐sink matching model for dynamic planning of CCUS clusters," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 12(4), pages 433-453, August.
    4. Ludovic Nicolas Legoix & Livio Ruffine & Christian Deusner & Matthias Haeckel, 2018. "Experimental Study of Mixed Gas Hydrates from Gas Feed Containing CH 4 , CO 2 and N 2 : Phase Equilibrium in the Presence of Excess Water and Gas Exchange," Energies, MDPI, vol. 11(8), pages 1-12, July.
    5. Aydin, Gokhan, 2014. "Modeling of energy consumption based on economic and demographic factors: The case of Turkey with projections," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 382-389.
    6. Li, Wei & Younger, Paul L. & Cheng, Yuanping & Zhang, Baoyong & Zhou, Hongxing & Liu, Qingquan & Dai, Tao & Kong, Shengli & Jin, Kan & Yang, Quanlin, 2015. "Addressing the CO2 emissions of the world's largest coal producer and consumer: Lessons from the Haishiwan Coalfield, China," Energy, Elsevier, vol. 80(C), pages 400-413.
    7. Sun, You-Hong & Zhang, Guo-Biao & Carroll, John J. & Li, Sheng-Li & Jiang, Shu-Hui & Guo, Wei, 2018. "Experimental investigation into gas recovery from CH4-C2H6-C3H8 hydrates by CO2 replacement," Applied Energy, Elsevier, vol. 229(C), pages 625-636.
    8. Jung-Tae Kim & Ah-Ram Kim & Gye-Chun Cho & Chul-Whan Kang & Joo Yong Lee, 2019. "The Effects of Coupling Stiffness and Slippage of Interface Between the Wellbore and Unconsolidated Sediment on the Stability Analysis of the Wellbore Under Gas Hydrate Production," Energies, MDPI, vol. 12(21), pages 1-23, November.
    9. Choi, Wonjung & Mok, Junghoon & Lee, Yohan & Lee, Jaehyoung & Seo, Yongwon, 2021. "Optimal driving force for the dissociation of CH4 hydrates in hydrate-bearing sediments using depressurization," Energy, Elsevier, vol. 223(C).
    10. Sergey Misyura & Pavel Strizhak & Anton Meleshkin & Vladimir Morozov & Olga Gaidukova & Nikita Shlegel & Maria Shkola, 2023. "A Review of Gas Capture and Liquid Separation Technologies by CO 2 Gas Hydrate," Energies, MDPI, vol. 16(8), pages 1-20, April.
    11. Lee, Yohan & Choi, Wonjung & Seo, Young-ju & Lee, Joo Yong & Lee, Jaehyoung & Seo, Yongwon, 2018. "Structural transition induced by cage-dependent guest exchange in CH4 + C3H8 hydrates with CO2 injection for energy recovery and CO2 sequestration," Applied Energy, Elsevier, vol. 228(C), pages 229-239.
    12. Xu, Jiuping & Tang, Min & Liu, Tingting & Fan, Lurong, 2024. "Technological paradigm-based development strategy towards natural gas hydrate technology," Energy, Elsevier, vol. 289(C).
    13. Karakurt, Izzet & Aydin, Gokhan & Aydiner, Kerim, 2012. "Sources and mitigation of methane emissions by sectors: A critical review," Renewable Energy, Elsevier, vol. 39(1), pages 40-48.
    14. Locatelli, Giorgio & Mancini, Mauro, 2010. "Small-medium sized nuclear coal and gas power plant: A probabilistic analysis of their financial performances and influence of CO2 cost," Energy Policy, Elsevier, vol. 38(10), pages 6360-6374, October.
    15. Mok, Junghoon & Choi, Wonjung & Lee, Jonghyuk & Seo, Yongwon, 2022. "Effects of pressure and temperature conditions on thermodynamic and kinetic guest exchange behaviors of CH4 − CO2 + N2 replacement for energy recovery and greenhouse gas storage," Energy, Elsevier, vol. 239(PB).
    16. Li, Xiao-Sen & Xu, Chun-Gang & Zhang, Yu & Ruan, Xu-Ke & Li, Gang & Wang, Yi, 2016. "Investigation into gas production from natural gas hydrate: A review," Applied Energy, Elsevier, vol. 172(C), pages 286-322.
    17. Zhang, Shanling & Ma, Yingrui & Xu, Zhenhua & Zhang, Yongtian & Liu, Xiang & Zhong, Xiuping & Tu, Guigang & Chen, Chen, 2024. "Numerical simulation study of natural gas hydrate extraction by depressurization combined with CO2 replacement," Energy, Elsevier, vol. 303(C).
    18. Seo, Young-ju & Park, Seongmin & Kang, Hyery & Ahn, Yun-Ho & Lim, Dongwook & Kim, Se-Joon & Lee, Jaehyoung & Lee, Joo Yong & Ahn, Taewoong & Seo, Yongwon & Lee, Huen, 2016. "Isostructural and cage-specific replacement occurring in sII hydrate with external CO2/N2 gas and its implications for natural gas production and CO2 storage," Applied Energy, Elsevier, vol. 178(C), pages 579-586.
    19. Ghorbani, Afshin & Rahimpour, Hamid Reza & Ghasemi, Younes & Zoughi, Somayeh & Rahimpour, Mohammad Reza, 2014. "A Review of Carbon Capture and Sequestration in Iran: Microalgal Biofixation Potential in Iran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 73-100.
    20. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:5:y:2012:i:2:p:420-437:d:16265. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.