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Esterification of Fatty Acids with Short-Chain Alcohols over Commercial Acid Clays in a Semi-Continuous Reactor

Author

Listed:
  • Soumaya Bouguerra Neji

    (Laboratory of Applied Chemistry: Heterocycles, Fats and Polymers, Faculté des Sciences de Sfax, Route de Soukra Km 3.5, 3038-Sfax, Tunisia)

  • Mahmoud Trabelsi

    (Laboratory of Applied Chemistry: Heterocycles, Fats and Polymers, Faculté des Sciences de Sfax, Route de Soukra Km 3.5, 3038-Sfax, Tunisia)

  • Mohamed H. Frikha

    (Laboratory of Applied Chemistry: Heterocycles, Fats and Polymers, Faculté des Sciences de Sfax, Route de Soukra Km 3.5, 3038-Sfax, Tunisia)

Abstract

Production of fatty acid esters from stearic, oleic, and palmitic acids and short-chain alcohols (methanol, ethanol, propanol, and butanol) for the production of biodiesel was investigated in this work. A series of montmorillonite-based clays catalysts (KSF, KSF/0, KP10, and K10) were used as acidic catalysts. The influence of the specific surface area and the acidity of the catalysts on the esterification rate were investigated. The best catalytic activities were obtained with KSF/0 catalyst. The esterification reaction has been carried out efficiently in a semi-continuous reactor at 150°C temperature higher than the boiling points of water and alcohol. The reactor used enabled the continuous removal of water and esterification with hydrated alcohol (ethanol 95%) without affecting the original activity of the clay.

Suggested Citation

  • Soumaya Bouguerra Neji & Mahmoud Trabelsi & Mohamed H. Frikha, 2009. "Esterification of Fatty Acids with Short-Chain Alcohols over Commercial Acid Clays in a Semi-Continuous Reactor," Energies, MDPI, vol. 2(4), pages 1-11, November.
    • Handle: RePEc:gam:jeners:v:2:y:2009:i:4:p:1107-1117:d:6247
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    References listed on IDEAS

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    1. Srivastava, Anjana & Prasad, Ram, 2000. "Triglycerides-based diesel fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 4(2), pages 111-133, June.
    2. Hanh, Hoang Duc & Dong, Nguyen The & Okitsu, Kenji & Nishimura, Rokuro & Maeda, Yasuaki, 2009. "Biodiesel production by esterification of oleic acid with short-chain alcohols under ultrasonic irradiation condition," Renewable Energy, Elsevier, vol. 34(3), pages 780-783.
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    Cited by:

    1. Ibrahim, Shaimaa M., 2021. "Preparation, characterization and application of novel surface-modified ZrSnO4 as Sn-based TMOs catalysts for the stearic acid esterification with methanol to biodiesel," Renewable Energy, Elsevier, vol. 173(C), pages 151-163.
    2. Rezende, Michelle J.C. & Pinto, Angelo C., 2016. "Esterification of fatty acids using acid-activated Brazilian smectite natural clay as a catalyst," Renewable Energy, Elsevier, vol. 92(C), pages 171-177.

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