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Thermocatalytic Decomposition of Sesame Waste Biomass over Ni-Co-Doped MCM-41: Kinetics and Physicochemical Properties of the Bio-Oil

Author

Listed:
  • Jan Nisar

    (National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan)

  • Raqeeb Ullah

    (National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan)

  • Ghulam Ali

    (National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan)

  • Afzal Shah

    (Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan)

  • Muhammad Imran Din

    (School of Chemistry, University of the Punjab, New Campus, Lahore 54590, Pakistan)

  • Zaib Hussain

    (School of Chemistry, University of the Punjab, New Campus, Lahore 54590, Pakistan)

  • Roohul Amin

    (Department of Chemistry, GC Peshawar, University of Peshawar, Peshawar 25120, Pakistan)

Abstract

The increase in industrialization and development has tremendously diminished fossil fuel resources. Moreover, the excessive use of fossil fuels has resulted in the release of various toxic gases and an increase in global warming. Hence, necessitating the need to search for a renewable energy source. In this study, sesame waste biomass (SWB), which is abundantly available in Pakistan, has been used as feedstock for obtaining bio-oil using the pyrolysis technique. Pyrolysis was carried out using thermogravimetry and a pyrolysis chamber. Firstly, thermogravimetric analysis was performed on biomass with/without a laboratory synthesized catalyst Ni/Co/MCM-41 in nitrogen at different temperature programmed rates of 5, 10, 15, and 20 °C/min. A four-stage weight loss was observed that pointed toward the vaporization of water, and degradation of hemicelluloses, cellulose, and lignin. The kinetics parameters were determined using the Kissinger equation. The activation energy for the decomposition reaction of hemicelluloses, cellulose, and lignin, without catalyst, was observed as 133.02, 141.33, and 191.22 kJ/mol, respectively, however, with catalyst it was found as 91.45, 99.76, and 149.65 kJ/mol, respectively. In the catalyzed reaction the results showed the lowest activation energy, which is an indication of the fact that the catalyst is successful in reducing the activation energy to a sufficient level. As the TG/DTG showed active degradation between 200 and 400 °C, therefore, the waste sesame biomass over Ni-Co/MCM-41 was pyrolyzed within the same temperature range in the pyrolysis chamber. Temperature and time were optimized for maximum oil yield. A maximum oil yield of 38% was achieved at 330 °C and 20 min. The oil obtained was studied using GCMS. The physicochemical characteristics of the oil were assessed, and it was found that if the oil was upgraded properly, it could serve as a fuel for commercial use.

Suggested Citation

  • Jan Nisar & Raqeeb Ullah & Ghulam Ali & Afzal Shah & Muhammad Imran Din & Zaib Hussain & Roohul Amin, 2023. "Thermocatalytic Decomposition of Sesame Waste Biomass over Ni-Co-Doped MCM-41: Kinetics and Physicochemical Properties of the Bio-Oil," Energies, MDPI, vol. 16(9), pages 1-15, April.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:9:p:3731-:d:1133984
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    References listed on IDEAS

    as
    1. Ghulam Ali & Marrij Afraz & Faisal Muhammad & Jan Nisar & Afzal Shah & Shamsa Munir & Syed Tasleem Hussain, 2022. "Production of Fuel Range Hydrocarbons from Pyrolysis of Lignin over Zeolite Y, Hydrogen," Energies, MDPI, vol. 16(1), pages 1-14, December.
    2. Gupta, Shubhi & Gupta, Goutam Kishore & Mondal, Monoj Kumar, 2019. "Slow pyrolysis of chemically treated walnut shell for valuable products: Effect of process parameters and in-depth product analysis," Energy, Elsevier, vol. 181(C), pages 665-676.
    3. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    4. Nafees Ur Rehman & Jan Nisar & Ghulam Ali & Ali Ahmad & Afzal Shah & Zahoor H. Farooqi & Faisal Muhammad, 2023. "Production of Bio-Oil from Thermo-Catalytic Decomposition of Pomegranate Peels over a Sulfonated Tea Waste Heterogeneous Catalyst: A Kinetic Investigation," Energies, MDPI, vol. 16(4), pages 1-17, February.
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