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Production of Fuel Range Hydrocarbons from Pyrolysis of Lignin over Zeolite Y, Hydrogen

Author

Listed:
  • Ghulam Ali

    (National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan)

  • Marrij Afraz

    (National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan)

  • Faisal Muhammad

    (National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan)

  • Jan Nisar

    (National Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan)

  • Afzal Shah

    (Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan)

  • Shamsa Munir

    (School of Applied Sciences and Humanities, National University of Technology (NUTECH), Islamabad 44000, Pakistan)

  • Syed Tasleem Hussain

    (Department of Chemistry, Kohat University of Science and Technology (KUST), Kohat 26000, Pakistan)

Abstract

In the current study, plain and lignin loaded with Zeolite Y, hydrogen was decomposed in a pyrolysis chamber. The reaction parameters were optimized and 390 ° C, 3% catalyst with a reaction time of 40 min were observed as the most suitable conditions for better oil yield. The bio-oil collected from the catalyzed and non-catalyzed pyrolytic reactions was analyzed by gas chromatography mass spectrometry (GCMS). Catalytic pyrolysis resulted in the production of bio-oil consisting of 15 components ranging from C 3 to C 18 with a high percentage of fuel range benzene derivatives. Non-catalytic pyrolysis produced bio-oil that consists of 58 components ranging from C 3 to C 24 ; however, the number and quantity of fuel range hydrocarbons were lower than in the catalyzed products. The pyrolysis reaction was studied kinetically for both samples using thermogravimetry at heating rates of 5, 10, 15 and 20 ° C/min in the temperature range 20–600 ° C. The activation energies and pre-exponential factors were calculated using the Kissinger equation for both non-catalytic and catalytic decomposition and found to be 157.96 kJ/mol, 141.33 kJ/mol, 2.66 × 10 13 min −1 and 2.17 × 10 10 min −1 , respectively. It was concluded that Zeolite Y, hydrogen worked well as a catalyst to decrease activation energy and enhance the quality of the bio-oil generated.

Suggested Citation

  • Ghulam Ali & Marrij Afraz & Faisal Muhammad & Jan Nisar & Afzal Shah & Shamsa Munir & Syed Tasleem Hussain, 2022. "Production of Fuel Range Hydrocarbons from Pyrolysis of Lignin over Zeolite Y, Hydrogen," Energies, MDPI, vol. 16(1), pages 1-14, December.
    • Handle: RePEc:gam:jeners:v:16:y:2022:i:1:p:215-:d:1014356
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    References listed on IDEAS

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    1. Jan Nisar & Ali Ahmad & Ghulam Ali & Nafees Ur Rehman & Afzal Shah & Iltaf Shah, 2022. "Enhanced Bio-Oil Yield from Thermal Decomposition of Peanut Shells Using Termite Hill as the Catalyst," Energies, MDPI, vol. 15(5), pages 1-13, March.
    2. Muhammad Amir Raza & Muhammad Mohsin Aman & Altaf Hussain Rajpar & Mohamed Bashir Ali Bashir & Touqeer Ahmed Jumani, 2022. "Towards Achieving 100% Renewable Energy Supply for Sustainable Climate Change in Pakistan," Sustainability, MDPI, vol. 14(24), pages 1-23, December.
    3. Bogdan Włodarczyk & Daniela Firoiu & George H. Ionescu & Florin Ghiocel & Marek Szturo & Lesław Markowski, 2021. "Assessing the Sustainable Development and Renewable Energy Sources Relationship in EU Countries," Energies, MDPI, vol. 14(8), pages 1-16, April.
    4. Potrč, Sanja & Čuček, Lidija & Martin, Mariano & Kravanja, Zdravko, 2021. "Sustainable renewable energy supply networks optimization – The gradual transition to a renewable energy system within the European Union by 2050," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
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    Cited by:

    1. Nafees Ur Rehman & Jan Nisar & Ghulam Ali & Ali Ahmad & Afzal Shah & Zahoor H. Farooqi & Faisal Muhammad, 2023. "Production of Bio-Oil from Thermo-Catalytic Decomposition of Pomegranate Peels over a Sulfonated Tea Waste Heterogeneous Catalyst: A Kinetic Investigation," Energies, MDPI, vol. 16(4), pages 1-17, February.
    2. Jan Nisar & Raqeeb Ullah & Ghulam Ali & Afzal Shah & Muhammad Imran Din & Zaib Hussain & Roohul Amin, 2023. "Thermocatalytic Decomposition of Sesame Waste Biomass over Ni-Co-Doped MCM-41: Kinetics and Physicochemical Properties of the Bio-Oil," Energies, MDPI, vol. 16(9), pages 1-15, April.

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