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Numerical 3D Model of a Novel Photoelectrolysis Tandem Cell with Solid Electrolyte for Green Hydrogen Production

Author

Listed:
  • Giosuè Giacoppo

    (CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy)

  • Stefano Trocino

    (CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy)

  • Carmelo Lo Vecchio

    (CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy)

  • Vincenzo Baglio

    (CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy)

  • María I. Díez-García

    (Departament de Química Física i Institut Universitari d’Electroquímica, Universitat d’Alacant, Apartat 99, E-03080 Alicante, Spain)

  • Antonino Salvatore Aricò

    (CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy)

  • Orazio Barbera

    (CNR-ITAE, Via Salita S. Lucia Sopra Contesse 5, 98126 Messina, Italy)

Abstract

The only strategy for reducing fossil fuel-based energy sources is to increase the use of sustainable ones. Among renewable energy sources, solar energy can significantly contribute to a sustainable energy future, but its discontinuous nature requires a large storage capacity. Due to its ability to be produced from primary energy sources and transformed, without greenhouse gas emissions, into mechanical, thermal, and electrical energy, emitting only water as a by-product, hydrogen is an effective carrier and means of energy storage. Technologies for hydrogen production from methane, methanol, hydrocarbons, and water electrolysis using non-renewable electrical power generate CO 2 . Conversely, employing photoelectrochemistry to harvest hydrogen is a sustainable technique for sunlight-direct energy storage. Research on photoelectrolysis is addressed to materials, prototypes, and simulation studies. From the latter point of view, models have mainly been implemented for aqueous-electrolyte cells, with only one semiconductor-based electrode and a metal-based counter electrode. In this study, a novel cell architecture was numerically modelled. A numerical model of a tandem cell with anode and cathode based on metal oxide semiconductors and a polymeric membrane as an electrolyte was implemented and investigated. Numerical results of 11% solar to hydrogen conversion demonstrate the feasibility of the proposed novel concept.

Suggested Citation

  • Giosuè Giacoppo & Stefano Trocino & Carmelo Lo Vecchio & Vincenzo Baglio & María I. Díez-García & Antonino Salvatore Aricò & Orazio Barbera, 2023. "Numerical 3D Model of a Novel Photoelectrolysis Tandem Cell with Solid Electrolyte for Green Hydrogen Production," Energies, MDPI, vol. 16(4), pages 1-12, February.
  • Handle: RePEc:gam:jeners:v:16:y:2023:i:4:p:1953-:d:1070208
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    References listed on IDEAS

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    1. Burton, N.A. & Padilla, R.V. & Rose, A. & Habibullah, H., 2021. "Increasing the efficiency of hydrogen production from solar powered water electrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
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    Cited by:

    1. Arkadiusz Małek & Agnieszka Dudziak & Jacek Caban & Monika Stoma, 2024. "Strategic Model for Yellow Hydrogen Production Using the Metalog Family of Probability Distributions," Energies, MDPI, vol. 17(10), pages 1-24, May.
    2. Yi Guo & Qi Wang & Maofei Geng & Xueyuan Peng & Jianmei Feng, 2023. "Effects of Liquid Density on the Gas-Liquid Interaction of the Ionic Liquid Compressor for Hydrogen Storage," Energies, MDPI, vol. 16(7), pages 1-20, April.
    3. Barbera, O. & Lo Vecchio, C. & Trocino, S. & Carbone, A. & Aricò, A.S. & Baglio, V. & Giacoppo, G., 2024. "Solar to hydrogen conversion by a 25 cm2-photoelectrochemical cell with upscaled components," Renewable Energy, Elsevier, vol. 224(C).

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