IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i8p2862-d793554.html
   My bibliography  Save this article

Effect of High-Rate Cycle Aging and Over-Discharge on NCM811 (LiNi0.8Co0.1Mn0.1O2) Batteries

Author

Listed:
  • Tao Yin

    (College of Mechanical and Electrical Engineering, Qingdao University, Qingdao 260071, China
    Engineering Technology Center of Power Integration and Energy Storage System, Qingdao University, Qingdao 266071, China
    National and Local Joint Engineering Technology Center for Intelligent Power Integration Technology for Electric Vehicles (Qingdao), Qingdao 266071, China)

  • Longzhou Jia

    (College of Mechanical and Electrical Engineering, Qingdao University, Qingdao 260071, China
    Engineering Technology Center of Power Integration and Energy Storage System, Qingdao University, Qingdao 266071, China
    National and Local Joint Engineering Technology Center for Intelligent Power Integration Technology for Electric Vehicles (Qingdao), Qingdao 266071, China)

  • Xichao Li

    (College of Mechanical and Electrical Engineering, Qingdao University, Qingdao 260071, China
    Engineering Technology Center of Power Integration and Energy Storage System, Qingdao University, Qingdao 266071, China
    National and Local Joint Engineering Technology Center for Intelligent Power Integration Technology for Electric Vehicles (Qingdao), Qingdao 266071, China
    Energy Storage Business Department, CRRC Qingdao Sifang Rolling Stock Research Institute Co., Ltd., Qingdao 266031, China)

  • Lili Zheng

    (College of Mechanical and Electrical Engineering, Qingdao University, Qingdao 260071, China
    Engineering Technology Center of Power Integration and Energy Storage System, Qingdao University, Qingdao 266071, China
    National and Local Joint Engineering Technology Center for Intelligent Power Integration Technology for Electric Vehicles (Qingdao), Qingdao 266071, China)

  • Zuoqiang Dai

    (College of Mechanical and Electrical Engineering, Qingdao University, Qingdao 260071, China
    Engineering Technology Center of Power Integration and Energy Storage System, Qingdao University, Qingdao 266071, China
    National and Local Joint Engineering Technology Center for Intelligent Power Integration Technology for Electric Vehicles (Qingdao), Qingdao 266071, China)

Abstract

Inconsistencies in a monomer battery pack can lead to the over-discharge of a single battery. Although deep over-discharge can be avoided by optimizing the battery control system, slight over-discharge still often occurs in the battery pack. The aging behavior of cylindrical NCM811 batteries under high-rate aging and over-discharge was studied. By setting the end-of-discharge of 1 V, the battery capacity rapidly decayed after 130 cycles. Additionally, the temperature sharply increased in the over-discharge stage. The micro short-circuit was found by the discharge voltage curve and impedance spectrum. Batteries with 100%, 79.6% and 50.9% SOH (state of health = Q_now/Q_new × 100%) as a result of high-rate aging and over-discharging were subjected to thermal testing in an adiabatic environment. The battery without high-rate aging and over-discharge did not experience thermal runaway. However, severe thermal runaway occurred in the 79.6% and 50.9% SOH batteries. Regarding the cyclic aging of the 50.9% SOH battery, the fusion temperature of the separator decreased by 22.3 °C, indicating a substantial degradation of the separator and thus reducing battery safety. Moreover, the results of scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) analyses revealed that the particles of the positive material were broken and detached, and that large-area cracks and delamination had formed on the negative material. Furthermore, Ni deposition and the uneven deposition of P and F on the negative surface were observed, which increased the risk of short-circuit in the battery. Positive and negative materials were attached on both sides of the separator, which reduced the effective area of ionic transportation.

Suggested Citation

  • Tao Yin & Longzhou Jia & Xichao Li & Lili Zheng & Zuoqiang Dai, 2022. "Effect of High-Rate Cycle Aging and Over-Discharge on NCM811 (LiNi0.8Co0.1Mn0.1O2) Batteries," Energies, MDPI, vol. 15(8), pages 1-15, April.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:8:p:2862-:d:793554
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/8/2862/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/8/2862/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Sheng Yang & Wenwei Wang & Cheng Lin & Weixiang Shen & Yiding Li, 2019. "Investigation of Internal Short Circuits of Lithium-Ion Batteries under Mechanical Abusive Conditions," Energies, MDPI, vol. 12(10), pages 1-16, May.
    2. Dong Wang & Lili Zheng & Xichao Li & Guangchao Du & Zhichao Zhang & Yan Feng & Longzhou Jia & Zuoqiang Dai, 2020. "Effects of Overdischarge Rate on Thermal Runaway of NCM811 Li-Ion Batteries," Energies, MDPI, vol. 13(15), pages 1-14, July.
    3. Waag, Wladislaw & Käbitz, Stefan & Sauer, Dirk Uwe, 2013. "Experimental investigation of the lithium-ion battery impedance characteristic at various conditions and aging states and its influence on the application," Applied Energy, Elsevier, vol. 102(C), pages 885-897.
    4. Yusuke Abe & Natsuki Hori & Seiji Kumagai, 2019. "Electrochemical Impedance Spectroscopy on the Performance Degradation of LiFePO 4 /Graphite Lithium-Ion Battery Due to Charge-Discharge Cycling under Different C-Rates," Energies, MDPI, vol. 12(23), pages 1-14, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chen, Jianguo & Han, Xuebing & Sun, Tao & Zheng, Yuejiu, 2024. "Analysis and prediction of battery aging modes based on transfer learning," Applied Energy, Elsevier, vol. 356(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mohammed, Abubakar Gambo & Elfeky, Karem Elsayed & Wang, Qiuwang, 2022. "Recent advancement and enhanced battery performance using phase change materials based hybrid battery thermal management for electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    2. Farmann, Alexander & Waag, Wladislaw & Sauer, Dirk Uwe, 2016. "Application-specific electrical characterization of high power batteries with lithium titanate anodes for electric vehicles," Energy, Elsevier, vol. 112(C), pages 294-306.
    3. Yashraj Tripathy & Andrew McGordon & Anup Barai, 2020. "Improving Accessible Capacity Tracking at Low Ambient Temperatures for Range Estimation of Battery Electric Vehicles," Energies, MDPI, vol. 13(8), pages 1-18, April.
    4. Hao Sun & Bo Jiang & Heze You & Bojian Yang & Xueyuan Wang & Xuezhe Wei & Haifeng Dai, 2021. "Quantitative Analysis of Degradation Modes of Lithium-Ion Battery under Different Operating Conditions," Energies, MDPI, vol. 14(2), pages 1-19, January.
    5. Yun Bao & Yuansheng Chen, 2021. "Lithium-Ion Battery Real-Time Diagnosis with Direct Current Impedance Spectroscopy," Energies, MDPI, vol. 14(15), pages 1-16, July.
    6. Thanh-Tung Nguyen & Abdul Basit Khan & Younghwi Ko & Woojin Choi, 2020. "An Accurate State of Charge Estimation Method for Lithium Iron Phosphate Battery Using a Combination of an Unscented Kalman Filter and a Particle Filter," Energies, MDPI, vol. 13(17), pages 1-15, September.
    7. Qiaohua Fang & Xuezhe Wei & Haifeng Dai, 2019. "A Remaining Discharge Energy Prediction Method for Lithium-Ion Battery Pack Considering SOC and Parameter Inconsistency," Energies, MDPI, vol. 12(6), pages 1-24, March.
    8. Yu, Quanqing & Dai, Lei & Xiong, Rui & Chen, Zeyu & Zhang, Xin & Shen, Weixiang, 2022. "Current sensor fault diagnosis method based on an improved equivalent circuit battery model," Applied Energy, Elsevier, vol. 310(C).
    9. Huang, Deyang & Chen, Ziqiang & Zhou, Shiyao, 2021. "Model prediction-based battery-powered heating method for series-connected lithium-ion battery pack working at extremely cold temperatures," Energy, Elsevier, vol. 216(C).
    10. Thomas F. Landinger & Guenter Schwarzberger & Guenter Hofer & Matthias Rose & Andreas Jossen, 2021. "Power Line Communications for Automotive High Voltage Battery Systems: Channel Modeling and Coexistence Study with Battery Monitoring," Energies, MDPI, vol. 14(7), pages 1-26, March.
    11. Tao, Laifa & Cheng, Yujie & Lu, Chen & Su, Yuzhuan & Chong, Jin & Jin, Haizu & Lin, Yongshou & Noktehdan, Azadeh, 2017. "Lithium-ion battery capacity fading dynamics modelling for formulation optimization: A stochastic approach to accelerate the design process," Applied Energy, Elsevier, vol. 202(C), pages 138-152.
    12. Yingjie Chen & Geng Yang & Xu Liu & Zhichao He, 2019. "A Time-Efficient and Accurate Open Circuit Voltage Estimation Method for Lithium-Ion Batteries," Energies, MDPI, vol. 12(9), pages 1-20, May.
    13. Liao, Xiaolin & Sun, Peiyi & Xu, Mengqing & Xing, Lidan & Liao, Youhao & Zhang, Liping & Yu, Le & Fan, Weizhen & Li, Weishan, 2016. "Application of tris(trimethylsilyl)borate to suppress self-discharge of layered nickel cobalt manganese oxide for high energy battery," Applied Energy, Elsevier, vol. 175(C), pages 505-511.
    14. Lyons, P.F. & Wade, N.S. & Jiang, T. & Taylor, P.C. & Hashiesh, F. & Michel, M. & Miller, D., 2015. "Design and analysis of electrical energy storage demonstration projects on UK distribution networks," Applied Energy, Elsevier, vol. 137(C), pages 677-691.
    15. Fabio Massimo Gatta & Alberto Geri & Regina Lamedica & Stefano Lauria & Marco Maccioni & Francesco Palone & Massimo Rebolini & Alessandro Ruvio, 2016. "Application of a LiFePO 4 Battery Energy Storage System to Primary Frequency Control: Simulations and Experimental Results," Energies, MDPI, vol. 9(11), pages 1-16, October.
    16. Liang Zhang & Shunli Wang & Daniel-Ioan Stroe & Chuanyun Zou & Carlos Fernandez & Chunmei Yu, 2020. "An Accurate Time Constant Parameter Determination Method for the Varying Condition Equivalent Circuit Model of Lithium Batteries," Energies, MDPI, vol. 13(8), pages 1-12, April.
    17. Abdel-Monem, Mohamed & Trad, Khiem & Omar, Noshin & Hegazy, Omar & Van den Bossche, Peter & Van Mierlo, Joeri, 2017. "Influence analysis of static and dynamic fast-charging current profiles on ageing performance of commercial lithium-ion batteries," Energy, Elsevier, vol. 120(C), pages 179-191.
    18. Carla Menale & Stefano Constà & Vincenzo Sglavo & Livia Della Seta & Roberto Bubbico, 2022. "Experimental Investigation of Overdischarge Effects on Commercial Li-Ion Cells," Energies, MDPI, vol. 15(22), pages 1-16, November.
    19. Yang, Ruixin & Xiong, Rui & He, Hongwen & Mu, Hao & Wang, Chun, 2017. "A novel method on estimating the degradation and state of charge of lithium-ion batteries used for electrical vehicles," Applied Energy, Elsevier, vol. 207(C), pages 336-345.
    20. Theodoros Kalogiannis & Md Sazzad Hosen & Mohsen Akbarzadeh Sokkeh & Shovon Goutam & Joris Jaguemont & Lu Jin & Geng Qiao & Maitane Berecibar & Joeri Van Mierlo, 2019. "Comparative Study on Parameter Identification Methods for Dual-Polarization Lithium-Ion Equivalent Circuit Model," Energies, MDPI, vol. 12(21), pages 1-35, October.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:8:p:2862-:d:793554. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.