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Recent Insights into Low-Surface-Area Catalysts for Hydrogen Production from Ammonia

Author

Listed:
  • Marina Pinzón

    (Department of Chemical Engineering, Faculty of Chemical Sciences and Technologies, University of Castilla-La Mancha, Avenida Camilo José Cela 12, 13071 Ciudad Real, Spain)

  • Paula Sánchez

    (Department of Chemical Engineering, Faculty of Chemical Sciences and Technologies, University of Castilla-La Mancha, Avenida Camilo José Cela 12, 13071 Ciudad Real, Spain)

  • Ana Raquel de la Osa

    (Department of Chemical Engineering, Faculty of Chemical Sciences and Technologies, University of Castilla-La Mancha, Avenida Camilo José Cela 12, 13071 Ciudad Real, Spain)

  • Amaya Romero

    (Department of Chemical Engineering, Higher Technical School of Agronomical Engineers, University of Castilla-La Mancha, Ronda de Calatrava 7, 13071 Ciudad Real, Spain)

  • Antonio de Lucas-Consuegra

    (Department of Chemical Engineering, Faculty of Chemical Sciences and Technologies, University of Castilla-La Mancha, Avenida Camilo José Cela 12, 13071 Ciudad Real, Spain)

Abstract

A potential method of storing and transporting hydrogen safely in a cost-effective and practical way involves the utilization of molecules that contain hydrogen in their structure such as ammonia. Because of its high hydrogen content and carbon-free molecular structure, as well as the maturity of related technology (easy liquefaction), ammonia has gained attention as a “hydrogen carrier” for the generation of energy. Unfortunately, hydrogen production from ammonia requires an efficient catalyst to achieve high conversion at low reaction temperatures. Recently, very attractive results have been obtained with low-surface-area materials. This review paper is focused on summarizing and comparing recent advances in novel, economic and active catalysts for this reaction, paying particular attention to materials with low surface area such as silicon carbide (SiC) and perovskites (ABO 3 structure). The effects of the supports, the active phase and the addition of promoters in such low-porosity materials have been analyzed in detail. Advances in adequate catalytic systems (including support and active metal) benefit the perspective of ammonia as a hydrogen carrier for the decarbonization of the energy sector and accelerate the “hydrogen economy”.

Suggested Citation

  • Marina Pinzón & Paula Sánchez & Ana Raquel de la Osa & Amaya Romero & Antonio de Lucas-Consuegra, 2022. "Recent Insights into Low-Surface-Area Catalysts for Hydrogen Production from Ammonia," Energies, MDPI, vol. 15(21), pages 1-25, November.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:21:p:8143-:d:959744
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    References listed on IDEAS

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    1. Ewelina Pawelczyk & Natalia Łukasik & Izabela Wysocka & Andrzej Rogala & Jacek Gębicki, 2022. "Recent Progress on Hydrogen Storage and Production Using Chemical Hydrogen Carriers," Energies, MDPI, vol. 15(14), pages 1-34, July.
    2. Hosseini, Seyed Ehsan & Wahid, Mazlan Abdul, 2016. "Hydrogen production from renewable and sustainable energy resources: Promising green energy carrier for clean development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 850-866.
    3. Cesaro, Zac & Ives, Matthew & Nayak-Luke, Richard & Mason, Mike & Bañares-Alcántara, René, 2021. "Ammonia to power: Forecasting the levelized cost of electricity from green ammonia in large-scale power plants," Applied Energy, Elsevier, vol. 282(PA).
    4. Muhammad Aziz & Agung Tri Wijayanta & Asep Bayu Dani Nandiyanto, 2020. "Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization," Energies, MDPI, vol. 13(12), pages 1-25, June.
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