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Non-Stoichiometric Redox Thermochemical Energy Storage Analysis for High Temperature Applications

Author

Listed:
  • Timo Roeder

    (Deutsches Zentrum für Luft-und Raumfahrt (German Aerospace Center)—DLR, Institute of Future Fuels, Linder Höhe, 51147 Cologne, Germany
    Faculty of Mechanical Engineering, RWTH Aachen University, 52074 Aachen, Germany)

  • Kai Risthaus

    (Deutsches Zentrum für Luft-und Raumfahrt (German Aerospace Center)—DLR, Institute of Future Fuels, Linder Höhe, 51147 Cologne, Germany)

  • Nathalie Monnerie

    (Deutsches Zentrum für Luft-und Raumfahrt (German Aerospace Center)—DLR, Institute of Future Fuels, Linder Höhe, 51147 Cologne, Germany)

  • Christian Sattler

    (Deutsches Zentrum für Luft-und Raumfahrt (German Aerospace Center)—DLR, Institute of Future Fuels, Linder Höhe, 51147 Cologne, Germany
    Faculty of Mechanical Engineering, RWTH Aachen University, 52074 Aachen, Germany)

Abstract

Concentrated solar power is capable of providing high-temperature process streams to different applications. One promising application is the high-temperature electrolysis process demanding steam and air above 800 °C. To overcome the intermittence of solar energy, energy storage is required. Currently, thermal energy at such temperatures can be stored predominately as sensible heat in packed beds. However, such storage suffers from a loss of usable storage capacity after several cycles. To improve such storage, a one-dimensional packed bed thermal energy storage model using air as a heat transfer medium is set up and used to investigate and quantify the benefit of the incorporation of different thermochemical materials from the class of perovskites. Perovskites undergo a non-stoichiometric reaction extension which offers the utilization of thermochemical heat over a larger temperature range. Three different perovskites were considered: SrFeO 3 , CaMnO 3 and Ca 0.8 Sr 0.2 MnO 3 . In total, 15 vol% of sensible energy storage has been replaced by one perovskite and different positions of the reactive material are analyzed. The effect of reactive heat on storage performance and thermal degradation over 15 consecutive charging and discharging cycles is studied. Based on the selected variation and reactive material, storage capacity and useful energy capacity are increased. The partial replacement close to the cold inlet/outlet of the storage system can increase the overall storage capacity by 10.42%. To fully utilize the advantages of thermochemical material, suitable operation conditions and a fitting placement of the material are vital.

Suggested Citation

  • Timo Roeder & Kai Risthaus & Nathalie Monnerie & Christian Sattler, 2022. "Non-Stoichiometric Redox Thermochemical Energy Storage Analysis for High Temperature Applications," Energies, MDPI, vol. 15(16), pages 1-21, August.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:16:p:5982-:d:891565
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    References listed on IDEAS

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    1. Mario Cascetta & Fabio Serra & Simone Arena & Efisio Casti & Giorgio Cau & Pierpaolo Puddu, 2016. "Experimental and Numerical Research Activity on a Packed Bed TES System," Energies, MDPI, vol. 9(9), pages 1-13, September.
    2. Galione, P.A. & Pérez-Segarra, C.D. & Rodríguez, I. & Oliva, A. & Rigola, J., 2015. "Multi-layered solid-PCM thermocline thermal storage concept for CSP plants. Numerical analysis and perspectives," Applied Energy, Elsevier, vol. 142(C), pages 337-351.
    3. Lin, Meng & Reinhold, Jan & Monnerie, Nathalie & Haussener, Sophia, 2018. "Modeling and design guidelines for direct steam generation solar receivers," Applied Energy, Elsevier, vol. 216(C), pages 761-776.
    4. Andreas Rosenstiel & Nathalie Monnerie & Jürgen Dersch & Martin Roeb & Robert Pitz-Paal & Christian Sattler, 2021. "Electrochemical Hydrogen Production Powered by PV/CSP Hybrid Power Plants: A Modelling Approach for Cost Optimal System Design," Energies, MDPI, vol. 14(12), pages 1-22, June.
    5. Tescari, Stefania & Neumann, Nicole Carina & Sundarraj, Pradeepkumar & Moumin, Gkiokchan & Rincon Duarte, Juan Pablo & Linder, Marc & Roeb, Martin, 2022. "Storing solar energy in continuously moving redox particles – Experimental analysis of charging and discharging reactors," Applied Energy, Elsevier, vol. 308(C).
    6. Albrecht, Kevin J. & Jackson, Gregory S. & Braun, Robert J., 2016. "Thermodynamically consistent modeling of redox-stable perovskite oxides for thermochemical energy conversion and storage," Applied Energy, Elsevier, vol. 165(C), pages 285-296.
    7. Sanz-Bermejo, Javier & Muñoz-Antón, Javier & Gonzalez-Aguilar, José & Romero, Manuel, 2014. "Optimal integration of a solid-oxide electrolyser cell into a direct steam generation solar tower plant for zero-emission hydrogen production," Applied Energy, Elsevier, vol. 131(C), pages 238-247.
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