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Natural Gas Conversion and Liquid/Solid Organic Waste Gasification by Ultra-Superheated Steam

Author

Listed:
  • Sergey M. Frolov

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, Department of Combustion and Explosion, 119991 Moscow, Russia)

  • Viktor A. Smetanyuk

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, Department of Combustion and Explosion, 119991 Moscow, Russia)

  • Ilias A. Sadykov

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, Department of Combustion and Explosion, 119991 Moscow, Russia)

  • Anton S. Silantiev

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, Department of Combustion and Explosion, 119991 Moscow, Russia)

  • Igor O. Shamshin

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, Department of Combustion and Explosion, 119991 Moscow, Russia)

  • Viktor S. Aksenov

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, Department of Combustion and Explosion, 119991 Moscow, Russia)

  • Konstantin A. Avdeev

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, Department of Combustion and Explosion, 119991 Moscow, Russia)

  • Fedor S. Frolov

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, Department of Combustion and Explosion, 119991 Moscow, Russia)

Abstract

The technology of a pulsed detonation gun for gasification of organic waste with ultra-superheated steam has been experimentally demonstrated for the first time. Experiments were performed on natural gas conversion as well as on the gasification of liquid (waste machine oil) and solid (wood sawdust) waste by hot detonation products of natural gas–oxygen mixture at a frequency of detonation pulses f = 1 Hz. Periodic release of detonation products to a 100 L flow reactor provided a time-averaged mean temperature and pressure in the reactor at about 1200 K and 0.1 MPa. It is shown that the technology of a pulsed detonation gun can provide complete (100%) natural gas conversion to syngas containing H 2 and CO with a H 2 /CO ratio of 1.25. During the gasification of liquid and solid wastes, the total volume fraction of combustible gases (H 2 , CO, and CH 4 ) in the product syngas was 80 and 65% with H 2 /CO ratios of 0.8 and 0.5, respectively. Comparison of the experiments on natural gas conversion and liquid/solid organic waste gasification under the same conditions at f = 1 Hz showed that the composition of the product syngas in terms of H 2 and CO content almost did not depend on the type of used feedstock. The estimated ideal energy gain defined as the ratio of the total energy of product syngas to the energy spent in its production from dry wood sawdust is about 4.6, i.e., the pulsed detonation technology of biomass gasification is economically very attractive.

Suggested Citation

  • Sergey M. Frolov & Viktor A. Smetanyuk & Ilias A. Sadykov & Anton S. Silantiev & Igor O. Shamshin & Viktor S. Aksenov & Konstantin A. Avdeev & Fedor S. Frolov, 2022. "Natural Gas Conversion and Liquid/Solid Organic Waste Gasification by Ultra-Superheated Steam," Energies, MDPI, vol. 15(10), pages 1-19, May.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:10:p:3616-:d:816046
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    References listed on IDEAS

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    1. Sérgio Ferreira & Eliseu Monteiro & Paulo Brito & Cândida Vilarinho, 2019. "A Holistic Review on Biomass Gasification Modified Equilibrium Models," Energies, MDPI, vol. 12(1), pages 1-31, January.
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    Cited by:

    1. Sergey M. Frolov & Anton S. Silantiev & Ilias A. Sadykov & Viktor A. Smetanyuk & Fedor S. Frolov & Jaroslav K. Hasiak & Alexey B. Vorob’ev & Alexey V. Inozemtsev & Jaroslav O. Inozemtsev, 2023. "Gasification of Waste Machine Oil by the Ultra-Superheated Mixture of Steam and Carbon Dioxide," Waste, MDPI, vol. 1(2), pages 1-17, June.
    2. Sergey M. Frolov, 2022. "Organic Waste Gasification by Ultra-Superheated Steam," Energies, MDPI, vol. 16(1), pages 1-11, December.

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