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Aging Behavior of Lithium Titanate Battery under High-Rate Discharging Cycle

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  • Chu Wang

    (Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China
    University of Chinese Academy of Sciences, Beijing 100039, China)

  • Zehui Liu

    (Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China
    University of Chinese Academy of Sciences, Beijing 100039, China)

  • Yaohong Sun

    (Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China
    Key Laboratory of Power Electronics and Electric Drive, Beijing 100190, China)

  • Yinghui Gao

    (Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China)

  • Ping Yan

    (Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China
    University of Chinese Academy of Sciences, Beijing 100039, China)

Abstract

The high-rate discharging performance of a lithium titanate battery is one of its main properties. In conditions that require ultra-high-rate discharging, a lithium titanate battery can be discharged continuously at a current of 50 C (50 times of its maximum capacity) or higher. In this paper, we take cylindrical steel shell lithium titanate cells as the research object and perform aging cycles at 66 C on these cells. The ultra-high-rate discharging cycles cause a rapid high-power capacity fading while the available capacity at normal current rate is not affected. The capacity at 66 C decreases to 80% of initial value in 10 cycles. This paper also analyzes the aging process of a lithium titanate battery at high-rate discharging with incremental capacity (IC) analysis, and presents the aging behavior of lithium titanate battery qualitatively, which is inconsistent with existing research. We attribute the aging mechanism of ultra-high-rate discharging cycles to the decrease of ionic mobility and increase of polarization resistance. Mechanical damage is observed in the CT scan of an aged cell, which we presume to be the result of rapid strain of cathode material.

Suggested Citation

  • Chu Wang & Zehui Liu & Yaohong Sun & Yinghui Gao & Ping Yan, 2021. "Aging Behavior of Lithium Titanate Battery under High-Rate Discharging Cycle," Energies, MDPI, vol. 14(17), pages 1-14, September.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:17:p:5482-:d:627965
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    References listed on IDEAS

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    1. Chu Wang & Yaohong Sun & Yinghui Gao & Ping Yan, 2023. "The Incremental Capacity Curves and Frequency Response Characteristic Evolution of Lithium Titanate Battery during Ultra-High-Rate Discharging Cycles," Energies, MDPI, vol. 16(8), pages 1-14, April.

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