IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i16p5062-d616324.html
   My bibliography  Save this article

Influence of Oxygen Ion Migration from Substrates on Photochemical Degradation of CH 3 NH 3 PbI 3 Hybrid Perovskite

Author

Listed:
  • Ivan S. Zhidkov

    (Institute of Physics and Technology, Ural Federal University, Mira St. 19, 620002 Yekaterinburg, Russia
    M. N. Mikheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences, S. Kovalevskoi St. 18, 620108 Yekaterinburg, Russia)

  • Azat F. Akbulatov

    (Institute for Problems of Chemical Physics, The Russian Academy of Sciences (IPCP RAS), Semenov Prospect 1, 141432 Chernogolovka, Russia)

  • Liana N. Inasaridze

    (Institute for Problems of Chemical Physics, The Russian Academy of Sciences (IPCP RAS), Semenov Prospect 1, 141432 Chernogolovka, Russia)

  • Andrey I. Kukharenko

    (Institute of Physics and Technology, Ural Federal University, Mira St. 19, 620002 Yekaterinburg, Russia)

  • Lyubov A. Frolova

    (Institute for Problems of Chemical Physics, The Russian Academy of Sciences (IPCP RAS), Semenov Prospect 1, 141432 Chernogolovka, Russia)

  • Seif O. Cholakh

    (Institute of Physics and Technology, Ural Federal University, Mira St. 19, 620002 Yekaterinburg, Russia)

  • Chu-Chen Chueh

    (Advanced Research Center for Green Materials Science and Technology, Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan)

  • Pavel A. Troshin

    (Institute for Problems of Chemical Physics, The Russian Academy of Sciences (IPCP RAS), Semenov Prospect 1, 141432 Chernogolovka, Russia)

  • Ernst Z. Kurmaev

    (Institute of Physics and Technology, Ural Federal University, Mira St. 19, 620002 Yekaterinburg, Russia
    M. N. Mikheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences, S. Kovalevskoi St. 18, 620108 Yekaterinburg, Russia)

Abstract

Measurements of XPS survey, core levels (N 1s, O 1s, Pb 4f, I 3d), and valence band (VB) spectra of CH 3 NH 3 PbI 3 (MAPbI 3 ) hybrid perovskite prepared on different substrates (glass, indium tin oxide (ITO), and TiO 2 ) aged under different light-soaking conditions at room temperature are presented. The results reveal that the photochemical stability of MAPbI 3 depends on the type of substrate and gradually decreases when glass is replaced by ITO and TiO 2 . Also, the degradation upon exposure to visible light is accompanied by the formation of MAI, PbI 2 , and Pb 0 products as shown by XPS core levels spectra. According to XPS O 1s and VB spectra measurements, this degradation process is superimposed on the partial oxidation of lead atoms in ITO/MAPbI 3 and TiO 2 /MAPbI 3 , for which Pb–O bonds are formed due to the diffusion of the oxygen ions from the substrates. This unexpected interaction leads to additional photochemical degradation.

Suggested Citation

  • Ivan S. Zhidkov & Azat F. Akbulatov & Liana N. Inasaridze & Andrey I. Kukharenko & Lyubov A. Frolova & Seif O. Cholakh & Chu-Chen Chueh & Pavel A. Troshin & Ernst Z. Kurmaev, 2021. "Influence of Oxygen Ion Migration from Substrates on Photochemical Degradation of CH 3 NH 3 PbI 3 Hybrid Perovskite," Energies, MDPI, vol. 14(16), pages 1-9, August.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:16:p:5062-:d:616324
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/16/5062/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/16/5062/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Hernan Sanchez Casalongue & Sarp Kaya & Venkatasubramanian Viswanathan & Daniel J. Miller & Daniel Friebel & Heine A. Hansen & Jens K. Nørskov & Anders Nilsson & Hirohito Ogasawara, 2013. "Direct observation of the oxygenated species during oxygen reduction on a platinum fuel cell cathode," Nature Communications, Nature, vol. 4(1), pages 1-6, December.
    2. Alessandra Alberti & Corrado Bongiorno & Emanuele Smecca & Ioannis Deretzis & Antonino La Magna & Corrado Spinella, 2019. "Pb clustering and PbI2 nanofragmentation during methylammonium lead iodide perovskite degradation," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Weilun Li & Mengmeng Hao & Ardeshir Baktash & Lianzhou Wang & Joanne Etheridge, 2023. "The role of ion migration, octahedral tilt, and the A-site cation on the instability of Cs1-xFAxPbI3," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Panpan Xu & Xingyu Guo & Binglei Jiao & Jinxing Chen & Minghao Zhang & Haodong Liu & Xiaolu Yu & Maura Appleberry & Zhenzhen Yang & Hongpeng Gao & Fan Yang & Xuefei Weng & Yanbin Shen & Jing Gu & Ying, 2024. "Proton-exchange induced reactivity in layered oxides for lithium-ion batteries," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    3. Jingxian Zhong & Dawei Zhou & Qi Bai & Chao Liu & Xinlian Fan & Hehe Zhang & Congzhou Li & Ran Jiang & Peiyi Zhao & Jiaxiao Yuan & Xiaojiao Li & Guixiang Zhan & Hongyu Yang & Jing Liu & Xuefen Song & , 2024. "Growth of millimeter-sized 2D metal iodide crystals induced by ion-specific preference at water-air interfaces," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Salvatore Valastro & Emanuele Smecca & Salvatore Sanzaro & Filippo Giannazzo & Ioannis Deretzis & Antonino La Magna & Youhei Numata & Ajay Kumar Jena & Tsutomu Miyasaka & Antonio Gagliano & Alessandra, 2020. "Improved Electrical and Structural Stability in HTL-Free Perovskite Solar Cells by Vacuum Curing Treatment," Energies, MDPI, vol. 13(15), pages 1-11, August.
    5. Benedikt Axel Brandes & Yogeshwaran Krishnan & Fabian Luca Buchauer & Heine Anton Hansen & Johan Hjelm, 2024. "Unifying the ORR and OER with surface oxygen and extracting their intrinsic activities on platinum," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:16:p:5062-:d:616324. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.