IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i7p1720-d341430.html
   My bibliography  Save this article

Investigation of NiFe-Based Catalysts for Oxygen Evolution in Anion-Exchange Membrane Electrolysis

Author

Listed:
  • Sabrina Campagna Zignani

    (Institute for Advanced Energy Technologies “Nicola Giordano” (ITAE) of the Italian National Research Council (CNR), 98126 Messina, Italy)

  • Massimiliano Lo Faro

    (Institute for Advanced Energy Technologies “Nicola Giordano” (ITAE) of the Italian National Research Council (CNR), 98126 Messina, Italy)

  • Stefano Trocino

    (Institute for Advanced Energy Technologies “Nicola Giordano” (ITAE) of the Italian National Research Council (CNR), 98126 Messina, Italy)

  • Antonino Salvatore Aricò

    (Institute for Advanced Energy Technologies “Nicola Giordano” (ITAE) of the Italian National Research Council (CNR), 98126 Messina, Italy)

Abstract

NiFe electrodes are developed for the oxygen evolution reaction (OER) in an alkaline electrolyser based on an anion exchange membrane (AEM) separator and fed with diluted KOH solution as supporting electrolyte. This study reports on the electrochemical behaviour of two different NiFe-oxide compositions (i.e., Ni 1 Fe 1 -oxide and Ni 1 Fe 2 -oxide) prepared by the oxalate method. These catalysts are assessed for single-cell operation in an MEA including a Sustainion™ anion-exchange membrane. The electrochemical polarization shows a current density of 650 mA cm −2 at 2 V and 50 °C for the Ni 1 Fe 1 anode composition. A durability test of 500 h is carried out using potential cycling as an accelerated stress-test. This shows a decrease in current density of 150 mA cm −2 mainly during the first 400 h. The performance achieved for the anion-exchange membrane electrolyser single-cell based on the NiFeO x catalyst appears promising. However, further improvements are required to enhance the stability under these operating conditions.

Suggested Citation

  • Sabrina Campagna Zignani & Massimiliano Lo Faro & Stefano Trocino & Antonino Salvatore Aricò, 2020. "Investigation of NiFe-Based Catalysts for Oxygen Evolution in Anion-Exchange Membrane Electrolysis," Energies, MDPI, vol. 13(7), pages 1-14, April.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:7:p:1720-:d:341430
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/7/1720/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/13/7/1720/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Vincent, Immanuel & Bessarabov, Dmitri, 2018. "Low cost hydrogen production by anion exchange membrane electrolysis: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1690-1704.
    2. Massari, Stefania & Ruberti, Marcello, 2013. "Rare earth elements as critical raw materials: Focus on international markets and future strategies," Resources Policy, Elsevier, vol. 38(1), pages 36-43.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ana L. Santos & Maria-João Cebola & Diogo M. F. Santos, 2021. "Towards the Hydrogen Economy—A Review of the Parameters That Influence the Efficiency of Alkaline Water Electrolyzers," Energies, MDPI, vol. 14(11), pages 1-35, May.
    2. Sumit Sood & Om Prakash & Mahdi Boukerdja & Jean-Yves Dieulot & Belkacem Ould-Bouamama & Mathieu Bressel & Anne-Lise Gehin, 2020. "Generic Dynamical Model of PEM Electrolyser under Intermittent Sources," Energies, MDPI, vol. 13(24), pages 1-34, December.
    3. Negar Shaya & Simon Glöser-Chahoud, 2024. "A Review of Life Cycle Assessment (LCA) Studies for Hydrogen Production Technologies through Water Electrolysis: Recent Advances," Energies, MDPI, vol. 17(16), pages 1-21, August.
    4. Machacek, Erika & Fold, Niels, 2014. "Alternative value chains for rare earths: The Anglo-deposit developers," Resources Policy, Elsevier, vol. 42(C), pages 53-64.
    5. Yang, Xiaoming & Islam, Md. Monirul & Mentel, Grzegorz & Ahmad, Ashfaq & Vasa, László, 2024. "Synergistic dynamics unveiled: Interplay between rare earth prices, clean energy innovations, and tech companies' market resilience amidst the Covid-19 pandemic and Russia-Ukraine conflict," Resources Policy, Elsevier, vol. 89(C).
    6. Li, Zheng-Zheng & Meng, Qin & Zhang, Linling & Lobont, Oana-Ramona & Shen, Yijuan, 2023. "How do rare earth prices respond to economic and geopolitical factors?," Resources Policy, Elsevier, vol. 85(PA).
    7. Wübbeke, Jost, 2013. "Rare earth elements in China: Policies and narratives of reinventing an industry," Resources Policy, Elsevier, vol. 38(3), pages 384-394.
    8. Ge, Jianping & Lei, Yalin, 2018. "Resource tax on rare earths in China: Policy evolution and market responses," Resources Policy, Elsevier, vol. 59(C), pages 291-297.
    9. ZHANG, Lu & GUO, Qing & ZHANG, Junbiao & HUANG, Yong & XIONG, Tao, 2015. "Did China׳s rare earth export policies work? — Empirical evidence from USA and Japan," Resources Policy, Elsevier, vol. 43(C), pages 82-90.
    10. Daniela S. Falcão, 2023. "Green Hydrogen Production by Anion Exchange Membrane Water Electrolysis: Status and Future Perspectives," Energies, MDPI, vol. 16(2), pages 1-8, January.
    11. Thibeault, Al & Ryder, Michael & Tomomewo, Olusegun & Mann, Michael, 2023. "A review of competitive advantage theory applied to the global rare earth industry transition," Resources Policy, Elsevier, vol. 85(PA).
    12. Wang, Xingxing & Li, Huajiao & Yao, Huajun & Zhu, Depeng & Liu, Nairong, 2018. "Simulation analysis of the spread of a supply crisis based on the global natural graphite trade network," Resources Policy, Elsevier, vol. 59(C), pages 200-209.
    13. Tomer Fishman & Rupert J. Myers & Orlando Rios & T.E. Graedel, 2018. "Implications of Emerging Vehicle Technologies on Rare Earth Supply and Demand in the United States," Resources, MDPI, vol. 7(1), pages 1-15, January.
    14. An, Qi & Jin, Zhijiang & Li, Nan & Wang, Hongchao & Schmierer, Joel & Wei, Cundi & Hu, Hongyu & Gao, Qian & Woodall, Jerry M., 2022. "Study on the liquid phase-derived activation mechanism in Al-rich alloy hydrolysis reaction for hydrogen production," Energy, Elsevier, vol. 247(C).
    15. Schlinkert, Dominik & van den Boogaart, Karl Gerald, 2015. "The development of the market for rare earth elements: Insights from economic theory," Resources Policy, Elsevier, vol. 46(P2), pages 272-280.
    16. Lucia BALDI & Massimo PERI & Daniela VANDONE, 2013. "Clean Energy Industries and Rare Earth Materials: Economic and Financial Issues," Departmental Working Papers 2013-07, Department of Economics, Management and Quantitative Methods at Università degli Studi di Milano.
    17. Riddle, Matthew & Macal, Charles M. & Conzelmann, Guenter & Combs, Todd E. & Bauer, Diana & Fields, Fletcher, 2015. "Global critical materials markets: An agent-based modeling approach," Resources Policy, Elsevier, vol. 45(C), pages 307-321.
    18. Charlier, Christophe & Guillou, Sarah, 2014. "Distortion effects of export quota policy: an analysis of the China-Raw Materials dispute," China Economic Review, Elsevier, vol. 31(C), pages 320-338.
    19. Ahmad Baroutaji & Arun Arjunan & John Robinson & Tabbi Wilberforce & Mohammad Ali Abdelkareem & Abdul Ghani Olabi, 2021. "PEMFC Poly-Generation Systems: Developments, Merits, and Challenges," Sustainability, MDPI, vol. 13(21), pages 1-31, October.
    20. Shuai, Jing & Peng, Xinjie & Zhao, Yujia & Wang, Yilan & Xu, Wei & Cheng, Jinhua & Lu, Yang & Wang, Jingjin, 2022. "A dynamic evaluation on the international competitiveness of China's rare earth products: An industrial chain and tech-innovation perspective," Resources Policy, Elsevier, vol. 75(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:7:p:1720-:d:341430. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.