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Investigation of Novel Composite Materials for Thermochemical Heat Storage Systems

Author

Listed:
  • Salih Cem Akcaoglu

    (Department of Chemistry, University of Otago, Dunedin 9016, New Zealand)

  • Zhifa Sun

    (Department of Physics, University of Otago, Dunedin 9016, New Zealand)

  • Stephen Carl Moratti

    (Department of Chemistry, University of Otago, Dunedin 9016, New Zealand)

  • Georgios Martinopoulos

    (School of Science and Technology, International Hellenic University, 57001 Thessaloniki, Greece)

Abstract

Increasing energy prices make space heating more expensive every year in The Organisation for Economic Co-operation and Development (OECD) member countries. Thermochemical heat storage systems (THSS) can be used to reduce residential energy consumption for space heating and to control humidity. Utilizing compressed thermochemical pellets as heat storage materials is a way to increase volumetric energy storage capacity and to improve the performance of the THSS. In this work, expanded natural graphite (ENG), activated carbon (AC), strontium bromide, and magnesium sulphate were mixed in different mass ratios and compressed under applied pressures in a range of 0.77 to 5.2 kN⋅mm −2 to form composite pellets with a diameter of 12 and 25 mm, respectively, and a thickness from 1.5 to 25 mm. These pellets were characterized using thermogravimetric analysis and differential scanning calorimetry. Cyclic tests of hydration at 20 °C and dehydration at 85 °C were conducted to investigate changes in the surface morphology and the heat and mass transfer characteristics of the composite pellets. The permeability and thermal conductivity of the composite pellets were also measured. It was found that the structural stability of the pellets was enhanced by increasing the compression pressure. Utilizing AC and ENG in the composite mixture enhanced the porosity, thermal conductivity, and the permeability of the pellets.

Suggested Citation

  • Salih Cem Akcaoglu & Zhifa Sun & Stephen Carl Moratti & Georgios Martinopoulos, 2020. "Investigation of Novel Composite Materials for Thermochemical Heat Storage Systems," Energies, MDPI, vol. 13(5), pages 1-31, February.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:5:p:1042-:d:325440
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    1. Donkers, P.A.J. & Sögütoglu, L.C. & Huinink, H.P. & Fischer, H.R. & Adan, O.C.G., 2017. "A review of salt hydrates for seasonal heat storage in domestic applications," Applied Energy, Elsevier, vol. 199(C), pages 45-68.
    2. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    3. Finck, Christian & Li, Rongling & Kramer, Rick & Zeiler, Wim, 2018. "Quantifying demand flexibility of power-to-heat and thermal energy storage in the control of building heating systems," Applied Energy, Elsevier, vol. 209(C), pages 409-425.
    4. Scapino, Luca & Zondag, Herbert A. & Van Bael, Johan & Diriken, Jan & Rindt, Camilo C.M., 2017. "Sorption heat storage for long-term low-temperature applications: A review on the advancements at material and prototype scale," Applied Energy, Elsevier, vol. 190(C), pages 920-948.
    5. Harkouss, Fatima & Fardoun, Farouk & Biwole, Pascal Henry, 2019. "Optimal design of renewable energy solution sets for net zero energy buildings," Energy, Elsevier, vol. 179(C), pages 1155-1175.
    6. N’Tsoukpoe, Kokouvi Edem & Schmidt, Thomas & Rammelberg, Holger Urs & Watts, Beatriz Amanda & Ruck, Wolfgang K.L., 2014. "A systematic multi-step screening of numerous salt hydrates for low temperature thermochemical energy storage," Applied Energy, Elsevier, vol. 124(C), pages 1-16.
    7. Yate Ding & S.B. Riffat, 2012. "Thermochemical energy storage technologies for building applications: a state-of-the-art review," International Journal of Low-Carbon Technologies, Oxford University Press, vol. 8(2), pages 106-116, January.
    8. Abedin, Ali Haji & Rosen, Marc A., 2012. "Closed and open thermochemical energy storage: Energy- and exergy-based comparisons," Energy, Elsevier, vol. 41(1), pages 83-92.
    9. Aydin, Devrim & Casey, Sean P. & Riffat, Saffa, 2015. "The latest advancements on thermochemical heat storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 356-367.
    10. Michel, Benoit & Mazet, Nathalie & Mauran, Sylvain & Stitou, Driss & Xu, Jing, 2012. "Thermochemical process for seasonal storage of solar energy: Characterization and modeling of a high density reactive bed," Energy, Elsevier, vol. 47(1), pages 553-563.
    11. Martinopoulos, G. & Tsalikis, G., 2018. "Diffusion and adoption of solar energy conversion systems – The case of Greece," Energy, Elsevier, vol. 144(C), pages 800-807.
    12. Korhammer, Kathrin & Druske, Mona-Maria & Fopah-Lele, Armand & Rammelberg, Holger Urs & Wegscheider, Nina & Opel, Oliver & Osterland, Thomas & Ruck, Wolfgang, 2016. "Sorption and thermal characterization of composite materials based on chlorides for thermal energy storage," Applied Energy, Elsevier, vol. 162(C), pages 1462-1472.
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    1. Mukherjee, Ankit & Pujari, Ankush Shankar & Shinde, Shraddha Nitin & Kashyap, Uddip & Kumar, Lalit & Subramaniam, Chandramouli & Saha, Sandip K., 2022. "Performance assessment of open thermochemical energy storage system for seasonal space heating in highly humid environment," Renewable Energy, Elsevier, vol. 201(P1), pages 204-223.
    2. Bruno Rafael de Almeida Moreira & Ronaldo da Silva Viana & Victor Hugo Cruz & Paulo Renato Matos Lopes & Celso Tadao Miasaki & Anderson Chagas Magalhães & Paulo Alexandre Monteiro de Figueiredo & Luca, 2020. "Anti-Thermal Shock Binding of Liquid-State Food Waste to Non-Wood Pellets," Energies, MDPI, vol. 13(12), pages 1-26, June.

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