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Logical-Information Model of Energy-Saving Production of Organic Sulfur Compounds from Low-Molecular Sulfur Waste Fuel Oil

Author

Listed:
  • Valery Meshalkin

    (International Institute of Logistics Resource Saving and Technological Innovators (SFC), Russian University of Chemical Technology Named after D.I. Mendeleev, 105005 Moscow, Russia)

  • Elena Shinkar

    (Chemistry Department, Astrakhan State Technical University, 414056 Astrakhan, Russia)

  • Nadezhda Berberova

    (Chemistry Department, Astrakhan State Technical University, 414056 Astrakhan, Russia)

  • Nadezhda Pivovarova

    (Chemistry Department, Astrakhan State Technical University, 414056 Astrakhan, Russia)

  • Foat Ismagilov

    (Chemistry Department, Astrakhan State Technical University, 414056 Astrakhan, Russia)

  • Andrey Okhlobystin

    (Chemistry Department, Astrakhan State Technical University, 414056 Astrakhan, Russia)

Abstract

A logical-informational model of energy resource-efficient chemical technology for the utilization of hydrogen sulfide and low molecular alkanethiols, which are toxic and difficult to remove sulfur components of residual fuel (fuel oil), is proposed. Based on the IDEF1 methodology and existing knowledge about the technological processes of the demercaptanization of various hydrocarbon raw materials (oils, gas condensates), a scheme for the production of organic sulfur compounds from sulfur waste extracted from fuel oil has been modeled. For a sufficiently complete removal of hydrogen sulfide and low molecular weight alkanethiols, energy- and resource-saving stages of the technological process have been developed, which are implemented by ultrasonic and/or magnetic treatment of fuel oil. It is proposed to use the combined action of two alternative methods of processing fuel oil to increase the efficiency of cleaning fuel oil from sulfur components. For the first time, an approach has been developed to utilize unwanted sulfuric impurities contained in fuel oil by involving electric and microwave synthesis in green technological processes, to obtain practically useful organic sulfur compounds with biological activity. It is shown that the use of one-electron oxidant thiols and hydrogen sulfide in organic media leads to the synthesis of organic disulfides and elemental sulfur. Indirect (with the use of mediators) electrosynthesis contributes to the cyclic conduct of the technological process, an increase in efficiency and a decrease in energy consumption compared to the direct (on electrodes) initiation of sulfur components.

Suggested Citation

  • Valery Meshalkin & Elena Shinkar & Nadezhda Berberova & Nadezhda Pivovarova & Foat Ismagilov & Andrey Okhlobystin, 2020. "Logical-Information Model of Energy-Saving Production of Organic Sulfur Compounds from Low-Molecular Sulfur Waste Fuel Oil," Energies, MDPI, vol. 13(20), pages 1-22, October.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:20:p:5286-:d:426499
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    References listed on IDEAS

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    1. Popp, David C., 2001. "The effect of new technology on energy consumption," Resource and Energy Economics, Elsevier, vol. 23(3), pages 215-239, July.
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