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Design of Nanomaterials for Hydrogen Storage

Author

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  • Luca Pasquini

    (Department of Physics and Astronomy, Alma Mater Studiorum—Università di Bologna, viale Berti-Pichat 6/2, 40127 Bologna, Italy)

Abstract

The interaction of hydrogen with solids and the mechanisms of hydride formation experience significant changes in nanomaterials due to a number of structural features. This review aims at illustrating the design principles that have recently inspired the development of new nanomaterials for hydrogen storage. After a general discussion about the influence of nanomaterials’ microstructure on their hydrogen sorption properties, several scientific cases and hot topics are illustrated surveying various classes of materials. These include bulk-like nanomaterials processed by mechanochemical routes, thin films and multilayers, nano-objects with composite architectures such as core–shell or composite nanoparticles, and nanoparticles on porous or graphene-like supports. Finally, selected examples of recent in situ studies of metal–hydride transformation mechanisms using microscopy and spectroscopy techniques are highlighted.

Suggested Citation

  • Luca Pasquini, 2020. "Design of Nanomaterials for Hydrogen Storage," Energies, MDPI, vol. 13(13), pages 1-28, July.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:13:p:3503-:d:381266
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    References listed on IDEAS

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    1. Brian C. H. Steele & Angelika Heinzel, 2001. "Materials for fuel-cell technologies," Nature, Nature, vol. 414(6861), pages 345-352, November.
    2. Tarun C. Narayan & Fariah Hayee & Andrea Baldi & Ai Leen Koh & Robert Sinclair & Jennifer A. Dionne, 2017. "Direct visualization of hydrogen absorption dynamics in individual palladium nanoparticles," Nature Communications, Nature, vol. 8(1), pages 1-8, April.
    3. Peter Ngene & Alessandro Longo & Lennard Mooij & Wim Bras & Bernard Dam, 2017. "Metal-hydrogen systems with an exceptionally large and tunable thermodynamic destabilization," Nature Communications, Nature, vol. 8(1), pages 1-8, December.
    4. Cermak, Jiri & Kral, Lubomir & Roupcova, Pavla, 2020. "Significantly decreased stability of MgH2 in the Mg-In-C alloy system: Long-period-stacking-ordering as a new way how to improve performance of hydrogen storage alloys?," Renewable Energy, Elsevier, vol. 150(C), pages 204-212.
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    Cited by:

    1. Ádám Révész, 2023. "Improved Hydrogen Storage Performance of Novel Metal Hydrides and Their Composites," Energies, MDPI, vol. 16(8), pages 1-3, April.
    2. Ádám Révész & Marcell Gajdics, 2021. "High-Pressure Torsion of Non-Equilibrium Hydrogen Storage Materials: A Review," Energies, MDPI, vol. 14(4), pages 1-22, February.
    3. Marcin Kremieniewski, 2020. "Influence of Graphene Oxide on Rheological Parameters of Cement Slurries," Energies, MDPI, vol. 13(20), pages 1-15, October.

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