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An Aqueous CaCl 2 Solution in the Condenser/Evaporator Instead of Pure Water: Application for the New Adsorptive Cycle “Heat from Cold”

Author

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  • Ilya Girnik

    (Boreskov Institute of Catalysis, Novosiborsk 630055, Russia
    Department of Natural Sciences, Novosibirsk State University, Novosiborsk 630055, Russia)

  • Yuri Aristov

    (Boreskov Institute of Catalysis, Novosiborsk 630055, Russia
    Department of Natural Sciences, Novosibirsk State University, Novosiborsk 630055, Russia)

Abstract

This paper addresses the analysis of the applicability of water as a working fluid for the new adsorptive heat transformation (AHT) cycle "Heat from Cold" (HeCol). The cycle proposed for cold countries operates at the ambient temperature below 0 °C. In this work, an aqueous solution of calcium chloride is proposed instead of liquid water to prevent the ice formation in the evaporator and condenser. The proposed water-based cycle is compared with the common methanol-based HeCol one in terms of the specific useful heat generated per cycle. The effect of the CaCl 2 solution on the cycle boundary pressures and its useful heat is studied both theoretically and experimentally. This approach can be extended to other adsorptive heat transformation cycles working at an evaporator or condenser temperature below 0 °C.

Suggested Citation

  • Ilya Girnik & Yuri Aristov, 2020. "An Aqueous CaCl 2 Solution in the Condenser/Evaporator Instead of Pure Water: Application for the New Adsorptive Cycle “Heat from Cold”," Energies, MDPI, vol. 13(11), pages 1-11, June.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:11:p:2904-:d:368006
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    References listed on IDEAS

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    1. Palomba, Valeria & Sapienza, Alessio & Aristov, Yuri, 2019. "Dynamics and useful heat of the discharge stage of adsorptive cycles for long term thermal storage," Applied Energy, Elsevier, vol. 248(C), pages 299-309.
    2. Gordeeva, Larisa G. & Aristov, Yuriy I., 2011. "Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization," Energy, Elsevier, vol. 36(2), pages 1273-1279.
    3. Sapienza, Alessio & Velte, Andreas & Girnik, Ilya & Frazzica, Andrea & Füldner, Gerrit & Schnabel, Lena & Aristov, Yuri, 2017. "“Water - Silica Siogel” working pair for adsorption chillers: Adsorption equilibrium and dynamics," Renewable Energy, Elsevier, vol. 110(C), pages 40-46.
    4. Shkatulov, Alexandr & Gordeeva, Larisa G. & Girnik, Ilya S. & Huinink, Henk & Aristov, Yuri I., 2020. "Novel adsorption method for moisture and heat recuperation in ventilation: Composites “LiCl/matrix” tailored for cold climate," Energy, Elsevier, vol. 201(C).
    5. Kyle R. Gluesenkamp & Andrea Frazzica & Andreas Velte & Steven Metcalf & Zhiyao Yang & Mina Rouhani & Corey Blackman & Ming Qu & Eric Laurenz & Angeles Rivero-Pacho & Sam Hinmers & Robert Critoph & Ma, 2020. "Experimentally Measured Thermal Masses of Adsorption Heat Exchangers," Energies, MDPI, vol. 13(5), pages 1-21, March.
    6. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.
    7. Mikhail Tokarev, 2019. "A Double-Bed Adsorptive Heat Transformer for Upgrading Ambient Heat: Design and First Tests," Energies, MDPI, vol. 12(21), pages 1-14, October.
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