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Modeling of Laboratory Steam Methane Reforming and CO 2 Methanation Reactors

Author

Listed:
  • Paola Costamagna

    (Department of Chemistry and Industrial Chemistry, University of Genova, via Dodecaneso 31, I-16146 Genova, Italy)

  • Federico Pugliese

    (Department of Civil, Chemical and Environmental Engineering, Chemical Engineering Pole, University of Genova, via Opera Pia 15, I-16145 Genova, Italy)

  • Tullio Cavattoni

    (INSTM, UdR Genova, via Dodecaneso 31, I-16146 Genova, Italy)

  • Guido Busca

    (Department of Civil, Chemical and Environmental Engineering, Chemical Engineering Pole, University of Genova, via Opera Pia 15, I-16145 Genova, Italy
    INSTM, UdR Genova, via Dodecaneso 31, I-16146 Genova, Italy)

  • Gabriella Garbarino

    (Department of Civil, Chemical and Environmental Engineering, Chemical Engineering Pole, University of Genova, via Opera Pia 15, I-16145 Genova, Italy
    INSTM, UdR Genova, via Dodecaneso 31, I-16146 Genova, Italy)

Abstract

To support the interpretation of the experimental results obtained from two laboratory-scale reactors, one working in the steam methane reforming (SMR) mode, and the other in the CO 2 hydrogenation (MCO2) mode, a steady-state pseudo-homogeneous 1D non-isothermal packed-bed reactor model is developed, embedding the classical Xu and Froment local kinetics. The laboratory reactors are operated with three different catalysts, two commercial and one homemade. The simulation model makes it possible to identify and account for thermal effects occurring inside the catalytic zone of the reactor and along the exit line. The model is intended to guide the development of small size SMR and MCO2 reactors in the context of Power-to-X (P2X) studies.

Suggested Citation

  • Paola Costamagna & Federico Pugliese & Tullio Cavattoni & Guido Busca & Gabriella Garbarino, 2020. "Modeling of Laboratory Steam Methane Reforming and CO 2 Methanation Reactors," Energies, MDPI, vol. 13(10), pages 1-19, May.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:10:p:2624-:d:361477
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    References listed on IDEAS

    as
    1. Chen, Bin & Hajimolana, Yashar S. & Venkataraman, Vikrant & Ni, Meng & Aravind, P.V., 2019. "Integration of reversible solid oxide cells with methane synthesis (ReSOC-MS) in grid stabilization: A dynamic investigation," Applied Energy, Elsevier, vol. 250(C), pages 558-567.
    2. Unknown, 2005. "Forward," 2005 Conference: Slovenia in the EU - Challenges for Agriculture, Food Science and Rural Affairs, November 10-11, 2005, Moravske Toplice, Slovenia 183804, Slovenian Association of Agricultural Economists (DAES).
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    Cited by:

    1. Gabriella Garbarino & Giovanni Pampararo & Thanh Khoa Phung & Paola Riani & Guido Busca, 2020. "Heterogeneous Catalysis in (Bio)Ethanol Conversion to Chemicals and Fuels: Thermodynamics, Catalysis, Reaction Paths, Mechanisms and Product Selectivities," Energies, MDPI, vol. 13(14), pages 1-19, July.
    2. Cerqueira, Pedro & Soria, M.A. & Madeira, Luis M., 2023. "Valorization of olive mill wastewater via autothermal reforming for hydrogen production," Renewable Energy, Elsevier, vol. 219(P2).

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