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Synergetic Approach for Superior Thermoelectric Performance in PbTe-PbSe-PbS Quaternary Alloys and Composites

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  • Dianta Ginting

    (Department of Applied Physics and Institute of Natural Sciences, Kyung Hee University, Yong-In, Gyong-gi 17104, Korea
    Department of Mechanical Engineering, Universitas Mercu Buana, Meruya Selatan, Kota Jakarta Barat 11650, Indonesia)

  • Chan-Chieh Lin

    (Department of Applied Physics and Institute of Natural Sciences, Kyung Hee University, Yong-In, Gyong-gi 17104, Korea)

  • Jong-Soo Rhyee

    (Department of Applied Physics and Institute of Natural Sciences, Kyung Hee University, Yong-In, Gyong-gi 17104, Korea)

Abstract

Thermoelectric power generation is an energy conversion technology from heat to electric energy, which can be applied to waste heat power conversion. Among thermoelectric materials (TE), PbTe-PbSe-PbS quaternary alloys and composites are promising candidates for thermoelectric power generation applications in the mid-temperature operating range from 500 to ~850 K. Besides, the thermoelectric performance of quaternary alloys and composites is not fully optimized regarding its composition and synthesis process. In the quaternary system, PbTe-PbSe-PbS, it was found that PbS will form nanoprecipitation in the matrix of quaternary alloy for a small content of PbS (≤0.07), which reduces the lattice thermal conductivity. The power factor of PbTe-PbSe-PbS quaternary alloys can be significantly enhanced by using a band convergence in PbTe 1−x Se x . The band structure modifications, with the result of simultaneous PbS nanoprecipitation, give rise to a high Z T value of 2.3 at 800 K for (PbTe) 0.95−x (PbSe) x (PbS) 0.05 . The chemical potential tuning by effective K-doping ( x = 0.02) and PbS substitution reveals a high power factor and low thermal conductivity, resulting in a comparatively high Z T value of 1.72 at 800 K. The combination of a high Seebeck coefficient and low thermal conductivity results in a very high Z T value of 1.52 at 700 K as n-type materials for low Cl-doped ( x = 0.0005) (PbTe 0.93−x Se 0.07 Cl x ) 0.93 (PbS) 0.07 composites. Therefore, this review presents the simultaneous emergence of effective chemical potential tuning, band convergence, and nanoprecipitation, giving rise to a significant enhancement of the thermoelectric performance of both p - and n -type PbTe-PbSe-PbS quaternary alloy and composite TE materials.

Suggested Citation

  • Dianta Ginting & Chan-Chieh Lin & Jong-Soo Rhyee, 2019. "Synergetic Approach for Superior Thermoelectric Performance in PbTe-PbSe-PbS Quaternary Alloys and Composites," Energies, MDPI, vol. 13(1), pages 1-29, December.
    • Handle: RePEc:gam:jeners:v:13:y:2019:i:1:p:72-:d:300791
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    References listed on IDEAS

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    1. Yanzhong Pei & Xiaoya Shi & Aaron LaLonde & Heng Wang & Lidong Chen & G. Jeffrey Snyder, 2011. "Convergence of electronic bands for high performance bulk thermoelectrics," Nature, Nature, vol. 473(7345), pages 66-69, May.
    2. Kanishka Biswas & Jiaqing He & Ivan D. Blum & Chun-I Wu & Timothy P. Hogan & David N. Seidman & Vinayak P. Dravid & Mercouri G. Kanatzidis, 2012. "High-performance bulk thermoelectrics with all-scale hierarchical architectures," Nature, Nature, vol. 489(7416), pages 414-418, September.
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