IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2019i1p72-d300791.html
   My bibliography  Save this article

Synergetic Approach for Superior Thermoelectric Performance in PbTe-PbSe-PbS Quaternary Alloys and Composites

Author

Listed:
  • Dianta Ginting

    (Department of Applied Physics and Institute of Natural Sciences, Kyung Hee University, Yong-In, Gyong-gi 17104, Korea
    Department of Mechanical Engineering, Universitas Mercu Buana, Meruya Selatan, Kota Jakarta Barat 11650, Indonesia)

  • Chan-Chieh Lin

    (Department of Applied Physics and Institute of Natural Sciences, Kyung Hee University, Yong-In, Gyong-gi 17104, Korea)

  • Jong-Soo Rhyee

    (Department of Applied Physics and Institute of Natural Sciences, Kyung Hee University, Yong-In, Gyong-gi 17104, Korea)

Abstract

Thermoelectric power generation is an energy conversion technology from heat to electric energy, which can be applied to waste heat power conversion. Among thermoelectric materials (TE), PbTe-PbSe-PbS quaternary alloys and composites are promising candidates for thermoelectric power generation applications in the mid-temperature operating range from 500 to ~850 K. Besides, the thermoelectric performance of quaternary alloys and composites is not fully optimized regarding its composition and synthesis process. In the quaternary system, PbTe-PbSe-PbS, it was found that PbS will form nanoprecipitation in the matrix of quaternary alloy for a small content of PbS (≤0.07), which reduces the lattice thermal conductivity. The power factor of PbTe-PbSe-PbS quaternary alloys can be significantly enhanced by using a band convergence in PbTe 1−x Se x . The band structure modifications, with the result of simultaneous PbS nanoprecipitation, give rise to a high Z T value of 2.3 at 800 K for (PbTe) 0.95−x (PbSe) x (PbS) 0.05 . The chemical potential tuning by effective K-doping ( x = 0.02) and PbS substitution reveals a high power factor and low thermal conductivity, resulting in a comparatively high Z T value of 1.72 at 800 K. The combination of a high Seebeck coefficient and low thermal conductivity results in a very high Z T value of 1.52 at 700 K as n-type materials for low Cl-doped ( x = 0.0005) (PbTe 0.93−x Se 0.07 Cl x ) 0.93 (PbS) 0.07 composites. Therefore, this review presents the simultaneous emergence of effective chemical potential tuning, band convergence, and nanoprecipitation, giving rise to a significant enhancement of the thermoelectric performance of both p - and n -type PbTe-PbSe-PbS quaternary alloy and composite TE materials.

Suggested Citation

  • Dianta Ginting & Chan-Chieh Lin & Jong-Soo Rhyee, 2019. "Synergetic Approach for Superior Thermoelectric Performance in PbTe-PbSe-PbS Quaternary Alloys and Composites," Energies, MDPI, vol. 13(1), pages 1-29, December.
    • Handle: RePEc:gam:jeners:v:13:y:2019:i:1:p:72-:d:300791
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/1/72/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/13/1/72/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Kanishka Biswas & Jiaqing He & Ivan D. Blum & Chun-I Wu & Timothy P. Hogan & David N. Seidman & Vinayak P. Dravid & Mercouri G. Kanatzidis, 2012. "High-performance bulk thermoelectrics with all-scale hierarchical architectures," Nature, Nature, vol. 489(7416), pages 414-418, September.
    2. Yanzhong Pei & Xiaoya Shi & Aaron LaLonde & Heng Wang & Lidong Chen & G. Jeffrey Snyder, 2011. "Convergence of electronic bands for high performance bulk thermoelectrics," Nature, Nature, vol. 473(7345), pages 66-69, May.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jing-Wei Li & Zhijia Han & Jincheng Yu & Hua-Lu Zhuang & Haihua Hu & Bin Su & Hezhang Li & Yilin Jiang & Lu Chen & Weishu Liu & Qiang Zheng & Jing-Feng Li, 2023. "Wide-temperature-range thermoelectric n-type Mg3(Sb,Bi)2 with high average and peak zT values," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Zihang Liu & Weihong Gao & Hironori Oshima & Kazuo Nagase & Chul-Ho Lee & Takao Mori, 2022. "Maximizing the performance of n-type Mg3Bi2 based materials for room-temperature power generation and thermoelectric cooling," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Yingcai Zhu & Dongyang Wang & Tao Hong & Lei Hu & Toshiaki Ina & Shaoping Zhan & Bingchao Qin & Haonan Shi & Lizhong Su & Xiang Gao & Li-Dong Zhao, 2022. "Multiple valence bands convergence and strong phonon scattering lead to high thermoelectric performance in p-type PbSe," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Yilin Jiang & Jinfeng Dong & Hua-Lu Zhuang & Jincheng Yu & Bin Su & Hezhang Li & Jun Pei & Fu-Hua Sun & Min Zhou & Haihua Hu & Jing-Wei Li & Zhanran Han & Bo-Ping Zhang & Takao Mori & Jing-Feng Li, 2022. "Evolution of defect structures leading to high ZT in GeTe-based thermoelectric materials," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Yong Yu & Xiao Xu & Yan Wang & Baohai Jia & Shan Huang & Xiaobin Qiang & Bin Zhu & Peijian Lin & Binbin Jiang & Shixuan Liu & Xia Qi & Kefan Pan & Di Wu & Haizhou Lu & Michel Bosman & Stephen J. Penny, 2022. "Tunable quantum gaps to decouple carrier and phonon transport leading to high-performance thermoelectrics," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    6. Decheng An & Senhao Zhang & Xin Zhai & Wutao Yang & Riga Wu & Huaide Zhang & Wenhao Fan & Wenxian Wang & Shaoping Chen & Oana Cojocaru-Mirédin & Xian-Ming Zhang & Matthias Wuttig & Yuan Yu, 2024. "Metavalently bonded tellurides: the essence of improved thermoelectric performance in elemental Te," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    7. Zhifang Zhou & Yi Huang & Bin Wei & Yueyang Yang & Dehong Yu & Yunpeng Zheng & Dongsheng He & Wenyu Zhang & Mingchu Zou & Jin-Le Lan & Jiaqing He & Ce-Wen Nan & Yuan-Hua Lin, 2023. "Compositing effects for high thermoelectric performance of Cu2Se-based materials," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Song Lv & Zuoqin Qian & Dengyun Hu & Xiaoyuan Li & Wei He, 2020. "A Comprehensive Review of Strategies and Approaches for Enhancing the Performance of Thermoelectric Module," Energies, MDPI, vol. 13(12), pages 1-24, June.
    9. Eom, Yoomin & Wijethunge, Dimuthu & Park, Hwanjoo & Park, Sang Hyun & Kim, Woochul, 2017. "Flexible thermoelectric power generation system based on rigid inorganic bulk materials," Applied Energy, Elsevier, vol. 206(C), pages 649-656.
    10. Bingchao Qin & Dongyang Wang & Tao Hong & Yuping Wang & Dongrui Liu & Ziyuan Wang & Xiang Gao & Zhen-Hua Ge & Li-Dong Zhao, 2023. "High thermoelectric efficiency realized in SnSe crystals via structural modulation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    11. Nie, Xianhua & Xue, Juan & Zhao, Li & Deng, Shuai & Xiong, Hanping, 2024. "New insight of thermodynamic cycle in thermoelectric power generation analyses: Literature review and perspectives," Energy, Elsevier, vol. 292(C).
    12. Ni, Dan & Song, Haijun & Chen, Yuanxun & Cai, Kefeng, 2019. "Free-standing highly conducting PEDOT films for flexible thermoelectric generator," Energy, Elsevier, vol. 170(C), pages 53-61.
    13. Ming Liu & Muchun Guo & Haiyan Lyu & Yingda Lai & Yuke Zhu & Fengkai Guo & Yueyang Yang & Kuai Yu & Xingyan Dong & Zihang Liu & Wei Cai & Matthias Wuttig & Yuan Yu & Jiehe Sui, 2024. "Doping strategy in metavalently bonded materials for advancing thermoelectric performance," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    14. Hangtian Zhu & Wenjie Li & Amin Nozariasbmarz & Na Liu & Yu Zhang & Shashank Priya & Bed Poudel, 2023. "Half-Heusler alloys as emerging high power density thermoelectric cooling materials," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    15. Pascal Boulet & Marie-Christine Record, 2020. "Theoretical Investigations of the BaRh 2 Ge 4 X 6 (X = S, Se, Te) Compounds," Energies, MDPI, vol. 13(23), pages 1-21, December.
    16. Romo-De-La-Cruz, Cesar-Octavio & Chen, Yun & Liang, Liang & Paredes-Navia, Sergio A. & Wong-Ng, Winnie K. & Song, Xueyan, 2023. "Entering new era of thermoelectric oxide ceramics with high power factor through designing grain boundaries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    17. Zhi Li & Wenhao Li & Zhen Chen, 2017. "Performance Analysis of Thermoelectric Based Automotive Waste Heat Recovery System with Nanofluid Coolant," Energies, MDPI, vol. 10(10), pages 1-15, September.
    18. Jiawei Zhang & Nikolaj Roth & Kasper Tolborg & Seiya Takahashi & Lirong Song & Martin Bondesgaard & Eiji Nishibori & Bo B. Iversen, 2021. "Direct observation of one-dimensional disordered diffusion channel in a chain-like thermoelectric with ultralow thermal conductivity," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    19. Zakariya M. Dalala & Osama Saadeh & Mathhar Bdour & Zaka Ullah Zahid, 2018. "A New Maximum Power Point Tracking (MPPT) Algorithm for Thermoelectric Generators with Reduced Voltage Sensors Count Control †," Energies, MDPI, vol. 11(7), pages 1-16, July.
    20. Yihua Zhang & Guyang Peng & Shuankui Li & Haijun Wu & Kaidong Chen & Jiandong Wang & Zhihao Zhao & Tu Lyu & Yuan Yu & Chaohua Zhang & Yang Zhang & Chuansheng Ma & Shengwu Guo & Xiangdong Ding & Jun Su, 2024. "Phase interface engineering enables state-of-the-art half-Heusler thermoelectrics," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2019:i:1:p:72-:d:300791. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.