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Comparison of Bioethanol Preparation from Triticale Straw Using the Ionic Liquid and Sulfate Methods

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  • Małgorzata Smuga-Kogut

    (Department of Agrobiotechnology, Faculty of Mechanical Engineering, Koszalin University of Technology, Raclawicka 15-17, 75-620 Koszalin, Poland)

  • Bartosz Walendzik

    (Faculty of Civil Engineering, Environmental and Geodetic Sciences, Koszalin University of Technology Koszalin, Sniadeckich 2, 75-453 Koszalin, Poland)

  • Daria Szymanowska-Powalowska

    (Department of Biotechnology and Food Microbiology, Poznan University of Life Sciences, Wojska Polskiego 48, 60-627 Poznan, Poland)

  • Joanna Kobus-Cisowska

    (Department of Gastronomical Sciences and Functional Foods, Poznan University of Life Sciences, Wojska Polskiego, 60-637 Poznan, Poland)

  • Janusz Wojdalski

    (Department of Production Management and Engineering, Faculty of Production Engineering, Warsaw University of Life Sciences, Nowoursynowska 166, 02-787 Warsaw, Poland)

  • Mateusz Wieczorek

    (Department of Pharmacognosy, Poznan University of Medical Sciences, Swiecickiego 4, 60-781 Poznań, Poland)

  • Judyta Cielecka-Piontek

    (Department of Pharmacognosy, Poznan University of Medical Sciences, Swiecickiego 4, 60-781 Poznań, Poland)

Abstract

Triticale straw constitutes a potential raw material for biofuel production found in Poland in considerable quantities. Thus far, production of bioethanol has been based on food raw materials such as cereal seeds, sugar beets or potatoes, and the biofuel production methods developed for these lignocellulose raw materials can threaten the environment and are inefficient. Therefore, this study aimed to compare of methods for pretreatment of triticale straw using 1-ethyl-3-methylimidazolium acetate and the sulfate method in the aspect of ethanol production intended for fuel. Based on the conducted experiments it has been determined that the use of 1-ethyl-3-methylimidazolium acetate for the pretreatment of triticale straw resulted in an increase of reducing sugars after enzymatic hydrolysis and ethyl alcohol after alcoholic fermentation. Furthermore, the study compared the efficiency of enzymatic hydrolysis of triticale straw without pretreatment, after processing with ionic liquid, recycled ionic liquid and using sulfate method, allowing a comparison of these methods. The more favorable method of lignocellulose material purification was the use of ionic liquid, due to the lower amount of toxic byproducts formed during the process, and the efficiency test results of bioethanol production using pretreatment with ionic liquid and sulfate method were similar. Ionic liquid recycling after pretreatment of rye straw using lyophilization allowed us to reuse this solvent to purify rye straw, yet the efficiency of this method remained at a low level. As a result of the conducted study it was determined that the use of ionic liquid-1-ethyl-3-methylimidazolium acetate enhanced the yield of bioethanol from triticale straw from 1.60 g/dm 3 after processing without pre-treatment to 10.64 g/dm 3 after pre-treatment.

Suggested Citation

  • Małgorzata Smuga-Kogut & Bartosz Walendzik & Daria Szymanowska-Powalowska & Joanna Kobus-Cisowska & Janusz Wojdalski & Mateusz Wieczorek & Judyta Cielecka-Piontek, 2019. "Comparison of Bioethanol Preparation from Triticale Straw Using the Ionic Liquid and Sulfate Methods," Energies, MDPI, vol. 12(6), pages 1-13, March.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:6:p:1155-:d:216958
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    References listed on IDEAS

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    1. Naik, S.N. & Goud, Vaibhav V. & Rout, Prasant K. & Dalai, Ajay K., 2010. "Production of first and second generation biofuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 578-597, February.
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    1. Kłosowski, Grzegorz & Mikulski, Dawid, 2023. "Changes in various lignocellulose biomasses structure after microwave-assisted hydrotropic pretreatment," Renewable Energy, Elsevier, vol. 219(P1).
    2. Krzysztof Dutkowski & Marcin Kruzel & Bartosz Zajączkowski, 2020. "Determining the Heat of Fusion and Specific Heat of Microencapsulated Phase Change Material Slurry by Thermal Delay Method," Energies, MDPI, vol. 14(1), pages 1-14, December.
    3. Rezania, Shahabaldin & Oryani, Bahareh & Cho, Jinwoo & Talaiekhozani, Amirreza & Sabbagh, Farzaneh & Hashemi, Beshare & Rupani, Parveen Fatemeh & Mohammadi, Ali Akbar, 2020. "Different pretreatment technologies of lignocellulosic biomass for bioethanol production: An overview," Energy, Elsevier, vol. 199(C).

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