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Heat Transfer at the Interface of Graphene Nanoribbons with Different Relative Orientations and Gaps

Author

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  • Shahin Mohammad Nejad

    (Department of Energy, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy
    Department of Mechanical Engineering, Eindhoven University of Technology, Postbus 513, 5600 MB Eindhoven, The Netherlands)

  • Masoud Bozorg Bigdeli

    (Department of Mechanical Engineering, University of Alberta, Edmonton, AB T6G 2G8, Canada)

  • Rajat Srivastava

    (Department of Energy, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy)

  • Matteo Fasano

    (Department of Energy, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy)

Abstract

Because of their high thermal conductivity, graphene nanoribbons (GNRs) can be employed as fillers to enhance the thermal transfer properties of composite materials, such as polymer-based ones. However, when the filler loading is higher than the geometric percolation threshold, the interfacial thermal resistance between adjacent GNRs may significantly limit the overall thermal transfer through a network of fillers. In this article, reverse non-equilibrium molecular dynamics is used to investigate the impact of the relative orientation (i.e., horizontal and vertical overlap, interplanar spacing and angular displacement) of couples of GNRs on their interfacial thermal resistance. Based on the simulation results, we propose an empirical correlation between the thermal resistance at the interface of adjacent GNRs and their main geometrical parameters, namely the normalized projected overlap and average interplanar spacing. The reported correlation can be beneficial for speeding up bottom-up approaches to the multiscale analysis of the thermal properties of composite materials, particularly when thermally conductive fillers create percolating pathways.

Suggested Citation

  • Shahin Mohammad Nejad & Masoud Bozorg Bigdeli & Rajat Srivastava & Matteo Fasano, 2019. "Heat Transfer at the Interface of Graphene Nanoribbons with Different Relative Orientations and Gaps," Energies, MDPI, vol. 12(5), pages 1-11, February.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:5:p:796-:d:209516
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    References listed on IDEAS

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    1. Timon Rabczuk & Mohammad Reza Azadi Kakavand & Raahul Palanivel Uma & Ali Hossein Nezhad Shirazi & Meysam Makaremi, 2018. "Thermal Conductance along Hexagonal Boron Nitride and Graphene Grain Boundaries," Energies, MDPI, vol. 11(6), pages 1-14, June.
    2. Fasano, Matteo & Bozorg Bigdeli, Masoud & Vaziri Sereshk, Mohammad Rasool & Chiavazzo, Eliodoro & Asinari, Pietro, 2015. "Thermal transmittance of carbon nanotube networks: Guidelines for novel thermal storage systems and polymeric material of thermal interest," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1028-1036.
    3. James Annett & Graham L. W. Cross, 2016. "Self-assembly of graphene ribbons by spontaneous self-tearing and peeling from a substrate," Nature, Nature, vol. 535(7611), pages 271-275, July.
    4. Serrano, Elena & Rus, Guillermo & García-Martínez, Javier, 2009. "Nanotechnology for sustainable energy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2373-2384, December.
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