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Different Mechanism Effect between Gas-Solid and Liquid-Solid Interface on the Three-Phase Coexistence Hydrate System Dissociation in Seawater: A Molecular Dynamics Simulation Study

Author

Listed:
  • Zhixue Sun

    (School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China)

  • Haoxuan Wang

    (School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China)

  • Jun Yao

    (School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China)

  • Chengwei Yang

    (Exploration & Development Research Institute, Petro China Changqing Oilfield Company, Xi’an 136201, China)

  • Jianlong Kou

    (School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China)

  • Kelvin Bongole

    (School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China)

  • Ying Xin

    (School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China)

  • Weina Li

    (School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China)

  • Xuchen Zhu

    (School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China)

Abstract

Almost 98% of methane hydrate is stored in the seawater environment, the study of microscopic mechanism for methane hydrate dissociation on the sea floor is of great significance to the development of hydrate production, involving a three-phase coexistence system of seawater (3.5% NaCl) + hydrate + methane gas. The molecular dynamics method is used to simulate the hydrate dissociation process. The dissociation of hydrate system depends on diffusion of methane molecules from partially open cages and a layer by layer breakdown of the closed cages. The presence of liquid or gas phases adjacent to the hydrate has an effect on the rate of hydrate dissociation. At the beginning of dissociation process, hydrate layers that are in contact with liquid phase dissociated faster than layers adjacent to the gas phase. As the dissociation continues, the thickness of water film near the hydrate-liquid interface became larger than the hydrate-gas interface giving more resistance to the hydrate dissociation. Dissociation rate of hydrate layers adjacent to gas phase gradually exceeds the dissociation rate of layers adjacent to the liquid phase. The difficulty of methane diffusion in the hydrate-liquid side also brings about change in dissociation rate.

Suggested Citation

  • Zhixue Sun & Haoxuan Wang & Jun Yao & Chengwei Yang & Jianlong Kou & Kelvin Bongole & Ying Xin & Weina Li & Xuchen Zhu, 2017. "Different Mechanism Effect between Gas-Solid and Liquid-Solid Interface on the Three-Phase Coexistence Hydrate System Dissociation in Seawater: A Molecular Dynamics Simulation Study," Energies, MDPI, vol. 11(1), pages 1-16, December.
  • Handle: RePEc:gam:jeners:v:11:y:2017:i:1:p:6-:d:123782
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    References listed on IDEAS

    as
    1. Zhixue Sun & Ying Xin & Qiang Sun & Ruolong Ma & Jianguang Zhang & Shuhuan Lv & Mingyu Cai & Haoxuan Wang, 2016. "Numerical Simulation of the Depressurization Process of a Natural Gas Hydrate Reservoir: An Attempt at Optimization of Field Operational Factors with Multiple Wells in a Real 3D Geological Model," Energies, MDPI, vol. 9(9), pages 1-20, September.
    2. Niall J. English & John S. Tse, 2010. "Perspectives on Hydrate Thermal Conductivity," Energies, MDPI, vol. 3(12), pages 1-9, December.
    3. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
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