IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v173y2023ics1364032122009315.html
   My bibliography  Save this article

Schroeder's paradox in proton exchange membrane fuel cells: A review

Author

Listed:
  • Chen, Lei
  • Chen, Yanyu
  • Tao, Wen-Quan

Abstract

Schroeder's paradox discovered by Schroeder in 1905 refers to the phenomenon that polymers have different maximum water uptake in the liquid and saturated vapor phases. For more than a hundred years, people have often debated whether this phenomenon conforms to thermodynamics. As proton exchange membrane fuel cell (PEMFC) gradually becomes a promising renewable energy utilization device, its impact on the physical properties of the proton exchange membrane has been studied widely. This paper reviews the theory and experiments on Schroeder's paradox over more than 100 years, especially the exploration of perfluorosulfonic acid membranes and PEMFCs in recent decades. Since membrane water content determines the operational performance of the PEMFC, this paper discusses and analyzes the effect of Schroeder's paradox on the PEMFC performance, including mechanical properties, electrical conductivity, and water transport mechanism. The effect of this phenomenon on the non-equilibrium operation of PEMFC has been highlighted, such as cold start-up, because of the different properties of membranes in contact with liquid water and air. This review gives an introduction to critical aspects of Schroeder's paradox to serve governments and organizations to promote the application of PEMFC in different regions.

Suggested Citation

  • Chen, Lei & Chen, Yanyu & Tao, Wen-Quan, 2023. "Schroeder's paradox in proton exchange membrane fuel cells: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    • Handle: RePEc:eee:rensus:v:173:y:2023:i:c:s1364032122009315
    DOI: 10.1016/j.rser.2022.113050
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032122009315
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2022.113050?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Maestre, V.M. & Ortiz, A. & Ortiz, I., 2021. "Challenges and prospects of renewable hydrogen-based strategies for full decarbonization of stationary power applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    2. He, Pu & Mu, Yu-Tong & Park, Jae Wan & Tao, Wen-Quan, 2020. "Modeling of the effects of cathode catalyst layer design parameters on performance of polymer electrolyte membrane fuel cell," Applied Energy, Elsevier, vol. 277(C).
    3. Zhihao Shang & Ryszard Wycisk & Peter Pintauro, 2021. "Electrospun Composite Proton-Exchange and Anion-Exchange Membranes for Fuel Cells," Energies, MDPI, vol. 14(20), pages 1-21, October.
    4. Hu, Junming & Li, Jianqiu & Xu, Liangfei & Huang, Fusen & Ouyang, Minggao, 2016. "Analytical calculation and evaluation of water transport through a proton exchange membrane fuel cell based on a one-dimensional model," Energy, Elsevier, vol. 111(C), pages 869-883.
    5. Li, Tianya & Wang, Kejian & Wang, Jihao & Liu, Yueqi & Han, Yufen & Xu, Zhiyang & Lin, Guangyi & Liu, Yong, 2021. "Optimization of GDL to improve water transferability," Renewable Energy, Elsevier, vol. 179(C), pages 2086-2093.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Liu, Huize & Hu, Zunyan & Li, Jianqiu & Xu, Liangfei & Shao, Yangbin & Ouyang, Minggao, 2023. "Investigation on the optimal GDL thickness design for PEMFCs considering channel/rib geometry matching and operating conditions," Energy, Elsevier, vol. 282(C).
    2. Bai, Fan & Quan, Hong-Bing & Yin, Ren-Jie & Zhang, Zhuo & Jin, Shu-Qi & He, Pu & Mu, Yu-Tong & Gong, Xiao-Ming & Tao, Wen-Quan, 2022. "Three-dimensional multi-field digital twin technology for proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 324(C).
    3. Zhang, Rui & Cao, Xuewen & Zhang, Xingwang & Yang, Jian & Bian, Jiang, 2024. "Co-benefits of the liquid hydrogen economy and LNG economy: Advances in LNG integrating LH2 production processes," Energy, Elsevier, vol. 301(C).
    4. Ahmed Mohmed Dafalla & Lin Wei & Bereket Tsegai Habte & Jian Guo & Fangming Jiang, 2022. "Membrane Electrode Assembly Degradation Modeling of Proton Exchange Membrane Fuel Cells: A Review," Energies, MDPI, vol. 15(23), pages 1-26, December.
    5. Yu, Rui Jiao & Guo, Hang & Ye, Fang & Chen, Hao, 2022. "Multi-parameter optimization of stepwise distribution of parameters of gas diffusion layer and catalyst layer for PEMFC peak power density," Applied Energy, Elsevier, vol. 324(C).
    6. Xu, Liangfei & Fang, Chuan & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2018. "Nonlinear dynamic mechanism modeling of a polymer electrolyte membrane fuel cell with dead-ended anode considering mass transport and actuator properties," Applied Energy, Elsevier, vol. 230(C), pages 106-121.
    7. Teng Teng & Xin Zhang & Qicheng Xue & Baodi Zhang, 2024. "Research of Proton Exchange Membrane Fuel Cell Modeling on Concentration Polarization under Variable-Temperature Operating Conditions," Energies, MDPI, vol. 17(3), pages 1-17, February.
    8. Zhang, Qinguo & Tong, Zheming & Tong, Shuiguang & Cheng, Zhewu, 2021. "Self-humidifying effect of air self-circulation system for proton exchange membrane fuel cell engines," Renewable Energy, Elsevier, vol. 164(C), pages 1143-1155.
    9. Teixeira, Fátima C. & Teixeira, António P.S. & Rangel, C.M., 2022. "New proton conductive membranes of indazole- and condensed pyrazolebisphosphonic acid-Nafion membranes for PEMFC," Renewable Energy, Elsevier, vol. 196(C), pages 1187-1196.
    10. Nikolas Schöne & Boris Heinz, 2023. "Semi-Systematic Literature Review on the Contribution of Hydrogen to Universal Access to Energy in the Rationale of Sustainable Development Goal Target 7.1," Energies, MDPI, vol. 16(4), pages 1-42, February.
    11. Saeidfar, Asal & Yesilyurt, Serhat, 2023. "Numerical investigation of the effects of catalyst layer composition and channel to rib width ratios for low platinum loaded PEMFCs," Applied Energy, Elsevier, vol. 339(C).
    12. Ahmad Baroutaji & Arun Arjunan & John Robinson & Tabbi Wilberforce & Mohammad Ali Abdelkareem & Abdul Ghani Olabi, 2021. "PEMFC Poly-Generation Systems: Developments, Merits, and Challenges," Sustainability, MDPI, vol. 13(21), pages 1-31, October.
    13. Siwen Gu & Jiaan Wang & Xinmin You & Yu Zhuang, 2023. "Investigating the Parameter-Driven Cathode Gas Diffusion of PEMFCs with a Piecewise Linearization Model," Energies, MDPI, vol. 16(9), pages 1-12, April.
    14. Li, Xiang & Tang, Fumin & Wang, Qianqian & Li, Bing & Dai, Haifeng & Chang, Guofeng & Zhang, Cunman & Ming, Pingwen, 2023. "Effect of cathode catalyst layer on proton exchange membrane fuel cell performance: Considering the spatially variable distribution," Renewable Energy, Elsevier, vol. 212(C), pages 644-654.
    15. Ming Peng & Enci Dong & Li Chen & Yu Wang & Wen-Quan Tao, 2022. "Effects of Cathode Gas Diffusion Layer Configuration on the Performance of Open Cathode Air-Cooled Polymer Electrolyte Membrane Fuel Cell," Energies, MDPI, vol. 15(17), pages 1-21, August.
    16. Dapeng Gong & Sichuan Xu & Yuan Gao, 2023. "Investigation of Water and Heat Transfer Mechanism in PEMFCs Based on a Two-Phase Non-Isothermal Model," Energies, MDPI, vol. 16(2), pages 1-20, January.
    17. Li, Hui & Eghbalian, Nasrin, 2021. "Numerical studies of effect of integrated through-plane array flow field on novel PEFC performance using BWO algorithm under uncertainties," Energy, Elsevier, vol. 231(C).
    18. Bhandari, Ramchandra, 2022. "Green hydrogen production potential in West Africa – Case of Niger," Renewable Energy, Elsevier, vol. 196(C), pages 800-811.
    19. Uchman, Wojciech & Kotowicz, Janusz & Sekret, Robert, 2022. "Investigation on green hydrogen generation devices dedicated for integrated renewable energy farm: Solar and wind," Applied Energy, Elsevier, vol. 328(C).
    20. Abdollahipour, Armin & Sayyaadi, Hoseyn, 2022. "A novel electrochemical refrigeration system based on the combined proton exchange membrane fuel cell-electrolyzer," Applied Energy, Elsevier, vol. 316(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:173:y:2023:i:c:s1364032122009315. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.