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Effect of novel Ni2P-loaded catalysts on algal pyrolysis bio-oil

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  • Li, Fanghua
  • Sweeney, Daniel J.
  • Dai, Yanjun
  • Wang, Chi-Hwa

Abstract

This study focused on conversion of algal biomass to bio-oil through in-situ catalytic fast pyrolysis. In particular, novel Ni2P-loaded and unmodified (zeolite, activated carbon and chicken manure biochar) catalysts were evaluated to determine their effect on in-situ upgrading of algal pyrolysis products. Among the catalysts evaluated, Ni2P-loaded zeolite achieved the highest bio-oil hydrocarbon (34.97 %) and calorific value (32.66 MJ/kg), and the lowest O/C (0.075) and N/C (0.074) ratios. There was a 137 % increase of the aliphatic hydrocarbon fraction and a 72 % increase of the biochar specific surface area (SSA) with the loading of Ni2P to zeolite. Additionally, unfavourable major oxygen- and nitrogen-containing compound, phytol and tetradecanamide, decreased seven- and six-fold, respectively, compared to the non-catalytic baseline case. Ni2P-loaded biochar achieved a reduction in the bio-oil acidity from a pH of 4.52–6.78 and a 41 % decrease of the carboxylic acids content. Biochar produced from the zeolite formulations exhibited especially favourable sorbent quality with SSA greater than 500 m2/g. According to the proposed catalytic mechanism, the generation of n-heptadecane and hexadecanamide may be due to the decomposition of phytol and tetradecanamide, and the catalytic activity was correlated to the pore size of the catalyst (22.22 Å). Direct addition reactions were the dominant pathway in the formation of liquid hydrocarbons. These results suggest that it is feasible to develop an in-situ multi-catalyst system to achieve high-quality bio-oil production. Thus, the development of novel Ni2P-loaded catalysts addressed a promising approach for biomass conversion into hydrocarbon-rich products with low risk to the environment.

Suggested Citation

  • Li, Fanghua & Sweeney, Daniel J. & Dai, Yanjun & Wang, Chi-Hwa, 2021. "Effect of novel Ni2P-loaded catalysts on algal pyrolysis bio-oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    • Handle: RePEc:eee:rensus:v:151:y:2021:i:c:s1364032121008522
    DOI: 10.1016/j.rser.2021.111575
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    1. Aysu, Tevfik & Abd Rahman, Nur Adilah & Sanna, Aimaro, 2016. "Catalytic pyrolysis of Tetraselmis and Isochrysis microalgae by nickel ceria based catalysts for hydrocarbon production," Energy, Elsevier, vol. 103(C), pages 205-214.
    2. Hansen, Samuel & Mirkouei, Amin & Diaz, Luis A., 2020. "A comprehensive state-of-technology review for upgrading bio-oil to renewable or blended hydrocarbon fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    3. Srivatsa, Srikanth Chakravartula & Li, Fanghua & Bhattacharya, Sankar, 2019. "Optimization of reaction parameters for bio-oil production by catalytic pyrolysis of microalga Tetraselmis suecica: Influence of Ni-loading on the bio-oil composition," Renewable Energy, Elsevier, vol. 142(C), pages 426-436.
    4. Brennan, Liam & Owende, Philip, 2010. "Biofuels from microalgae--A review of technologies for production, processing, and extractions of biofuels and co-products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 557-577, February.
    5. Inayat, Muddasser & Sulaiman, Shaharin A. & Kurnia, Jundika Candra & Shahbaz, Muhammad, 2019. "Effect of various blended fuels on syngas quality and performance in catalytic co-gasification: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 252-267.
    6. Azizi, Kolsoom & Keshavarz Moraveji, Mostafa & Abedini Najafabadi, Hamed, 2018. "A review on bio-fuel production from microalgal biomass by using pyrolysis method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3046-3059.
    7. Bhoi, P.R. & Ouedraogo, A.S. & Soloiu, V. & Quirino, R., 2020. "Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    8. Cuevas-Castillo, Gabriela A. & Navarro-Pineda, Freddy S. & Baz Rodríguez, Sergio A. & Sacramento Rivero, Julio C., 2020. "Advances on the processing of microalgal biomass for energy-driven biorefineries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 125(C).
    9. Enamala, Manoj Kumar & Enamala, Swapnika & Chavali, Murthy & Donepudi, Jagadish & Yadavalli, Rajasri & Kolapalli, Bhulakshmi & Aradhyula, Tirumala Vasu & Velpuri, Jeevitha & Kuppam, Chandrasekhar, 2018. "Production of biofuels from microalgae - A review on cultivation, harvesting, lipid extraction, and numerous applications of microalgae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 49-68.
    10. Rizwan, Muhammad & Mujtaba, Ghulam & Memon, Sheraz Ahmed & Lee, Kisay & Rashid, Naim, 2018. "Exploring the potential of microalgae for new biotechnology applications and beyond: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 92(C), pages 394-404.
    11. Li, Fanghua & Srivatsa, Srikanth Chakravartula & Bhattacharya, Sankar, 2019. "A review on catalytic pyrolysis of microalgae to high-quality bio-oil with low oxygeneous and nitrogenous compounds," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 481-497.
    12. Theodore Dickerson & Juan Soria, 2013. "Catalytic Fast Pyrolysis: A Review," Energies, MDPI, vol. 6(1), pages 1-25, January.
    13. Saber, Mohammad & Nakhshiniev, Bakhtiyor & Yoshikawa, Kunio, 2016. "A review of production and upgrading of algal bio-oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 918-930.
    14. Dissanayake, Pavani Dulanja & Choi, Seung Wan & Igalavithana, Avanthi Deshani & Yang, Xiao & Tsang, Daniel C.W. & Wang, Chi-Hwa & Kua, Harn Wei & Lee, Ki Bong & Ok, Yong Sik, 2020. "Sustainable gasification biochar as a high efficiency adsorbent for CO2 capture: A facile method to designer biochar fabrication," Renewable and Sustainable Energy Reviews, Elsevier, vol. 124(C).
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