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Progress on the pre-treatment of lignocellulosic biomass employing ionic liquids

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  • Halder, Pobitra
  • Kundu, Sazal
  • Patel, Savankumar
  • Setiawan, Adi
  • Atkin, Rob
  • Parthasarthy, Rajarathinam
  • Paz-Ferreiro, Jorge
  • Surapaneni, Aravind
  • Shah, Kalpit

Abstract

The effective pre-treatment methods are required for the destruction of the complex biomass structure to economically produce high grade fuels and valuable platform chemicals. Ionic liquids have high potential for energy efficient biomass pre-treatment due to their low vapour pressure, emission profile, recyclability and tuneable properties; some ionic liquids can even be prepared from renewable biomass feedstocks. However, a number of issues currently impede the large scale uptake of ionic liquids including their cost of production, detailed understanding the macro, micro and molecular level deconstruction mechanisms which inhibits process optimisation and modelling, and the need for techno-economic astable sessment on large scale trials. So far, laboratory to bench scale IL pre-treatments of various lignocellulosic biomasses were studied by changing various process parameters where the aims were to investigate the biomass dissolution mechanism and understand the pre-treatment performance of ILs. This review outlines current research gaps and potential applications for ionic liquids in the destruction of biomass into its components followed by separation of lignin, hemicellulose and cellulose rich fractions.

Suggested Citation

  • Halder, Pobitra & Kundu, Sazal & Patel, Savankumar & Setiawan, Adi & Atkin, Rob & Parthasarthy, Rajarathinam & Paz-Ferreiro, Jorge & Surapaneni, Aravind & Shah, Kalpit, 2019. "Progress on the pre-treatment of lignocellulosic biomass employing ionic liquids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 268-292.
    • Handle: RePEc:eee:rensus:v:105:y:2019:i:c:p:268-292
    DOI: 10.1016/j.rser.2019.01.052
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    2. Oliva, A. & Tan, L.C. & Papirio, S. & Esposito, G. & Lens, P.N.L., 2021. "Effect of methanol-organosolv pretreatment on anaerobic digestion of lignocellulosic materials," Renewable Energy, Elsevier, vol. 169(C), pages 1000-1012.
    3. Wu, Bo & Wang, Yan-Wei & Dai, Yong-Hua & Song, Chao & Zhu, Qi-Li & Qin, Han & Tan, Fu-Rong & Chen, Han-Cheng & Dai, Li-Chun & Hu, Guo-Quan & He, Ming-Xiong, 2021. "Current status and future prospective of bio-ethanol industry in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
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    5. Wang, Youmei & Liu, Peng & Zhang, Guifen & Yang, Qiaomei & Lu, Jun & Xia, Tao & Peng, Liangcai & Wang, Yanting, 2021. "Cascading of engineered bioenergy plants and fungi sustainable for low-cost bioethanol and high-value biomaterials under green-like biomass processing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).

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