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Optimization, kinetics and thermodynamic studies on oil extraction from Daturametel Linn oil seed for biodiesel production

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  • Mathiarasi, Ramasamy
  • Partha, Nagarajan

Abstract

In this research, Daturametel Linn seed oil was investigated for the first time as a promising non-conventional feedstock for preparation of biodiesel fuel. The maximum extraction of oil was observed to be 38.57 (wt) % and the activation energy Ea (25.8 kJ mol−1) was calculated. Further the thermodynamic properties for oil extraction were determined as activation enthalpy = 25.051 kJ mol−1, activation entropy = −241.25 J mol−1, and the Gibb's energy = 105.39 kJ mol−1. This present study also reports the new single-step ultrasound production of biodiesel from high fatty acid D.metel Linn oil using sulfuryl chloride as catalysts in which 95.50% yield was achieved with 2 h. Different reaction parameters for oil extraction and biodiesel production were optimized. This analysis confirms that Daturametel Linn biodiesel is appropriate alternative to petroleum diesel with recommended fuel properties as per specified standards.

Suggested Citation

  • Mathiarasi, Ramasamy & Partha, Nagarajan, 2016. "Optimization, kinetics and thermodynamic studies on oil extraction from Daturametel Linn oil seed for biodiesel production," Renewable Energy, Elsevier, vol. 96(PA), pages 583-590.
    • Handle: RePEc:eee:renene:v:96:y:2016:i:pa:p:583-590
    DOI: 10.1016/j.renene.2016.04.078
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    1. Siddiquee, Muhammad N. & Rohani, Sohrab, 2011. "Lipid extraction and biodiesel production from municipal sewage sludges: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1067-1072, February.
    2. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
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    2. Pascoal, C.V.P. & Oliveira, A.L.L. & Figueiredo, D.D. & Assunção, J.C.C., 2020. "Optimization and kinetic study of ultrasonic-mediated in situ transesterification for biodiesel production from the almonds of Syagrus cearensis," Renewable Energy, Elsevier, vol. 147(P1), pages 1815-1824.
    3. Rodrigues, Jailson Silva & do Valle, Camila Peixoto & Uchoa, Antonia Flávia Justino & Ramos, Denise Moreira & da Ponte, Flávio Albuquerque Ferreira & Rios, Maria Alexsandra de Sousa & de Queiroz Malve, 2020. "Comparative study of synthetic and natural antioxidants on the oxidative stability of biodiesel from Tilapia oil," Renewable Energy, Elsevier, vol. 156(C), pages 1100-1106.
    4. Murillo, Gabriel & Ali, Sameh S. & Sun, Jianzhong & Yan, Yunjun & Bartocci, Pietro & El-Zawawy, Nessma & Azab, Maha & He, Yaojia & Fantozzi, Francesco, 2019. "Ultrasonic emulsification assisted immobilized Burkholderia cepacia lipase catalyzed transesterification of soybean oil for biodiesel production in a novel reactor design," Renewable Energy, Elsevier, vol. 135(C), pages 1025-1034.
    5. Mueanmas, Chokchai & Nikhom, Ruamporn & Petchkaew, Anida & Iewkittayakorn, Jutarut & Prasertsit, Kulchanart, 2019. "Extraction and esterification of waste coffee grounds oil as non-edible feedstock for biodiesel production," Renewable Energy, Elsevier, vol. 133(C), pages 1414-1425.

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