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High-concentration operation of a passive air-breathing direct methanol fuel cell integrated with a porous methanol barrier

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  • Yuan, Wei
  • Tang, Yong
  • Yang, Xiaojun

Abstract

To realize high-concentration operation of a passive air-breathing direct methanol fuel cell (PAB-DMFC) is a critical issue that should be addressed before it is used for practical applications. This work reports the feasibility of using a porous metal fiber sintered felt (PMFSF) as the anodic methanol barrier to control methanol crossover (MCO) in order to feed the fuel cell with a higher concentration of methanol fuel. The effectiveness of this method is successfully validated. The optimization criterion of using this material is to maintain a balance between reactant and product management. Results demonstrate that a medium value of PMFSF thickness, i.e. 2mm yields a higher performance. The PMFSF porosity has two-fold effect on the cell performance, which interacts with the current collector setup including the opening pattern and ratio. The related mechanisms concerning such effects on mass transfer process are explained in detail. In addition, the dynamic characteristics of this PMFSF-based PAB-DMFC are also evaluated in this study.

Suggested Citation

  • Yuan, Wei & Tang, Yong & Yang, Xiaojun, 2013. "High-concentration operation of a passive air-breathing direct methanol fuel cell integrated with a porous methanol barrier," Renewable Energy, Elsevier, vol. 50(C), pages 741-746.
    • Handle: RePEc:eee:renene:v:50:y:2013:i:c:p:741-746
    DOI: 10.1016/j.renene.2012.08.039
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    References listed on IDEAS

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    1. Achmad, F. & Kamarudin, S.K. & Daud, W.R.W. & Majlan, E.H., 2011. "Passive direct methanol fuel cells for portable electronic devices," Applied Energy, Elsevier, vol. 88(5), pages 1681-1689, May.
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    Cited by:

    1. Zainoodin, A.M. & Kamarudin, S.K. & Masdar, M.S. & Daud, W.R.W. & Mohamad, A.B. & Sahari, J., 2014. "High power direct methanol fuel cell with a porous carbon nanofiber anode layer," Applied Energy, Elsevier, vol. 113(C), pages 946-954.
    2. Munjewar, Seema S. & Thombre, Shashikant B. & Mallick, Ranjan K., 2017. "Approaches to overcome the barrier issues of passive direct methanol fuel cell – Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1087-1104.
    3. Zhang, Yufeng & Xue, Rui & Zhang, Xuelin & Song, Jiaying & Liu, Xiaowei, 2015. "rGO deposited in stainless steel fiber felt as mass transfer barrier layer for μ-DMFC," Energy, Elsevier, vol. 91(C), pages 1081-1086.
    4. Mallick, Ranjan K. & Thombre, Shashikant B. & Shrivastava, Naveen K., 2016. "Vapor feed direct methanol fuel cells (DMFCs): A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 51-74.

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